Temperature effect on the extraction of carboxylic acids by amine-based extractants

Industrial and Engineering Chemistry Research

Volumn 43, Issue 23, 2004, Pages 7608-7617

  Canari, Riki ^a   Eyal, Aharon M ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; AMINES; CARBOXYLIC ACIDS; CONCENTRATION (PROCESS); EXTRACTION; HYDROPHILICITY; NEGATIVE IONS; PH EFFECTS; SUBSTITUTION REACTIONS;

BACK EXTRACTION; EXTRACTANTS; ION-PAIR INTERACTIONS; LIPOPHILIC AMINES;

THERMAL EFFECTS;

2 OXOGLUTARIC ACID; ACETIC ACID; BUTYRIC ACID; CARBOXYLIC ACID DERIVATIVE; CITRIC ACID; GLUCONIC ACID; GLUTARIC ACID; ISOBUTYRIC ACID; LACTIC ACID; MALEIC ACID; MALIC ACID; MALONIC ACID; OXALIC ACID; PROPIONIC ACID; SUCCINIC ACID;

EXTRACTION PROCESS;

ALKALINITY; CHEMICAL STRUCTURE; CONFERENCE PAPER; EXTRACTION; MOLECULAR INTERACTION; PH; PKA; TEMPERATURE DEPENDENCE;

EID: 8344221260     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie034127j     Document Type: Conference Paper

References (31)

1. Yu-Ming, J.; Dao-chen, L.; Yuan-Fu, S. Study on Extraction of Citric Acid. In Proceedings of International Solvent Extraction Conference; Library of Congress Cataloging in Publication Data: Denver, CO, 1983; pp 517-518.
2. Baniel, A. M.; Blumberg, R.; Hajdu, K. Recovery of Acids from Aqueous Solutions. British Patent No. 1,426,018, 1973.
3. Baniel, A. M.; Blumberg, R.; Hajdu, K. Recovery of Acids from Aqueous Solutions. U.S. Patent No. 4,275,234, June 23, 1981.
4. Wennersten, R. A New Method for the Purification of Citric Acid by Liquid-Liquid Extraction. Proceedings of International Solvent Extraction Conference (ISEC); Liege University Press: Liege, Belgium, 1980; Vol. 2, p 63.
5. Wennersten, R. The Extraction of Citric Acid from Fermentation Broth Using a Solution of Tertiary Amine. J. Chem. Technol. Biotechnol. 1983, 33B, 85-94.
6. Tamada, J. A. Extraction of Carboxylic Acids by Amine Extractants. Ph.D. Dissertation, Lawrence Berkeley Laboratory, University of California, Berkeley, CA, 1989.
7. Tamada, J. A.; King, C. J. Extraction of Carboxylic Acids by Amine Extractants. 3. Effect of Temperature, Water Coextraction and Process Considerations. Ind. Eng. Chem. Res. 1990, 26, 1933-1938.
8. Eyal, A.; Kazan, B.; Bloch, R. Recovery and Concentration of Strong Mineral Acids from Dilute Solutions Through LLX III. A "Temperature Swing" Based Process. Solvent Extr. Ion Exch. 1991, 9 (2), 223-236.
9. Sadaka, M. G.; Garcia, A. A. The Effect of Temperature on Forward/Bach Extraction Using an Amine Extractant for the Recovery of Cyclic Hydroxy Carboxylic Acids. Sep. Sci. Technol. 1998, 33 (11), 1667-1680.
10. Eyal, A. M.; Kazan, B. Process and Compositions for the Recovery of Ascorbic Acid, U.S. Patent No. 6,037,480, March 14, 2000.
11. Eyal, A. M.; Vitner, A.; Reuveni, T.; Kazan, B. Process for the Production of Erythorbic Acid, U.S. Patent No. 6,172,242, January 9, 2001.
12. a, Amine Basicity and Diluent Properties. Ind. Eng. Chem. Res. 1995, 34, 1789.
13. Canari, R.; Eyal, A. M. The Extraction of Carboxylic Acid by Amine-Based Extractants - Apparent Extractant Basicity According to the pH Half-Neutralization. Ind. Eng. Chem. Res. 2003, 42, 1285.
14. Grinstead, R. R. Base Strengths of Amine in Liquid-Liquid Extraction Systems. In Proceedings of International Solvent Extraction Conference (ISEC); Dyrssen, D., Liljenzin, J. O., Rydberg, J., Eds.; North-Holland, Amsterdam, 1966; p 427.
15. Canari, R.; Eyal, A. M. The Effect of pH on Dicarboxylic Acids Extraction by Amine-Based Extractants. Ind. Eng. Chem. Res. 2003, 42, 1293.
16. Canari, R.; Eyal, A. M. Selectivity in Mono-Carboxylic Acids Extraction from Their Mixture Solutions Using an Amine Based Extractant - The pH Effect. Ind. Eng. Chem. Res. 2003, 42, 1301.
17. Canari, R.; Eyal, A. M. Selectivity in Extraction of Lactic, Malic, Glutaric and Maleic Acid from Their Binary Solutions Using an Amine-Based Extractant-The pH Effect. Ind. Eng. Chem. Res. 2003, 42, 1308.
18. Canari, R.; Eyal, A. M. Acids Extraction by Amine-Based Extractants: An Analysis of the Effect of Anion Concentration in the Aqueous Phase Using the Donnan Model. Ind. Eng. Chem. Res. 2003, 42, 1315.
19. Lide, D. R., Ed. Handbook of Chemistry and Physics, 73rd ed.; CRC Press: Boca Raton, FL, 1992-1993; pp 8-41.
20. Serjeant, E. P.; Dempsey, B. Ionisation Constants of Organic Acids in Aqueous Solution. In IUPAC Series. Pergamon Press: New York, 1979; pp 45, 177.
21. Maskill, H. Temperature Dependence of Chemical Equilibria. In The Physical Basis of Organic Chemistry; Oxford University Press: New York, 1985; pp 142-143.
22. Bender, P.; Biermann, W. J. Heat of Neutralization Studies at High Acid-Base Concentrations. I. Sodium Hydroxide-Hydrochloric Acid. J. Am. Chem. Soc. 1952, 74, 322-325.
23. Bizek, V.; Horacek, J.; Rericha, R.; Kousova, M. Amine Extraction of Citric Acid with 1-Octanol/n-Heptane Solutions of Trialkylamine. Ind. Eng. Chem. Res. 1992, 31, 1554-1562.
24. a Prediction of Organic Acids and Bases; Dempsey, B., Serjeant, E. P., Eds.; Chapman and Hall: New York, 1981; pp 7-8.
25. Apelblat, A.; Manzurola, E. Solubility of Oxalic, Malonic, Succinic, Adipic, Maleic, Malic, Citric, and Tartaric Acids in Water from 278.15 to 338.15 K. J. Chem. Thermodynam. 1987, 19, 317-320.
26. Kertes, A. S.; King, C. J. Extraction Chemistry of Fermentation Product Carboxylic Acids. Biotechnol. Bioeng. 1986, 28, 269-282.
27. Grinstead, R. R.; Davis, J. C. Base Strengths of Amine-Amine Hydrochloride Systems in Toluene. J. Phys. Chem. 1968, 72 (5), 1630.
28. Perrin, D. D. The Effect of Temperature on pK Values of Organic Bases. Aust. J. Chem. 1964, 17, 484-488.
29. Barton, A. F. M. Handbook of Solubility Parameters and Other Cohesion Parameters, Second Edition; CRC Press: Boca Raton, FL, 1991; pp 123-141.
30. Weiss, D. E.; Bolto, B. A.; McNeill, R.; Macpherson, A. S.; Siudak, R.; Swinton, E. A.; Willis, D. An Ion-Exchange Process with Thermal Regeneration II. Properties of Weakly Basic Resins. Aust. J. Chem. 1966, 19, 561-587.
31. Bolto, B. A.; Weiss, D. E. The Thermal Regeneration of Ion-Exchange Resins. In Ion Exchange and Solvent Extraction. A Series of Advances; Marinsky, J. A., Marcus, Y., Eds.; Marcel Dekker: New York, 1977; Vol. 7, pp 221-286.