Characterization of depolymerized residues from extremely low acid hydrolysis (ELA) of sugarcane bagasse cellulose: Effects of degree of polymerization, crystallinity and crystallite size on thermal decomposition

Industrial Crops and Products

Volumn 36, Issue 1, 2012, Pages 560-571

  Gurgel, Leandro Vinícius Alves ^a   Marabezi, Karen ^a   Ramos, Luiz Antonio ^a   Curvelo, Antonio Aprigio da Silva ^a,b  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

^b BRAZILIAN CENTER FOR RESEARCH IN ENERGY AND MATERIALS CNPEM   (Brazil)

Author keywords

Acid hydrolysis; ELA; Microcrystalline cellulose; Sugarcane bagasse; Thermal decomposition

Indexed keywords

ACID HYDROLYSIS; ELA; MICROCRYSTALLINE CELLULOSE; SUGARCANE BAGASSE; THERMAL DECOMPOSITIONS;

ACTIVATION ENERGY; BAGASSE; CHEMICAL ANALYSIS; CRYSTALLITE SIZE; HYDROLYSIS; PARTICLE SIZE ANALYSIS; PYROLYSIS;

CELLULOSE;

CELLULOSE; CRYSTALLINITY; HYDROLYSIS; POLYMERIZATION; REACTION KINETICS; SCANNING ELECTRON MICROSCOPY; SUGAR CANE; THERMAL DECOMPOSITION;

ACIDOLYSIS; BAGASSE; CELLULOSE; CHEMICAL ANALYSIS; DEGREE OF POLYMERIZATION; HYDROLYSIS; MICROCRYSTALLINE CELLULOSE; PARTICLE SIZE; PYROLYSIS; SUGAR CANE;

EID: 83255163137     PISSN: 09266690     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.indcrop.2011.11.009     Document Type: Article

References (33)

1. Bouchard J., et al. Characterization of depolymerized cellulosic residues. 1. Residues obtained by acid-hydrolysis processes. Wood Sci. Technol. 1989, 23(4):343-355.
2. Bouchard J., et al. Characterization of depolymerized cellulosic residues. 2. Residues derived from ethylene-glycol solvolysis of cellulose. Wood Sci. Technol. 1990, 24(2):159-169.
3. Bradbury A.G.W., et al. Kinetic-model for pyrolysis of cellulose. J. Appl. Polym. Sci. 1979, 23(11):3271-3280.
4. Broido A., Nelson M.A. Char yield on pyrolysis of cellulose. Combust. Flame 1975, 24(2):263-268.
5. Calahorra M.E., et al. Thermogravimetric analysis of cellulose - effect of the molecular-weight on thermal-decomposition. J. Appl. Polym. Sci. 1989, 37(12):3305-3314.
6. CONAB. 2010. Companhia Nacional de Abastecimento. Avaliação da safra agrícola brasileira de cana-de-açúcar, safra 2010, segundo levantamento, Setembro. (in Portuguese).
7. Das K., et al. A study of the mechanical, thermal and morphological properties of microcrystalline cellulose particles prepared from cotton slivers using different acid concentrations. Cellulose 2009, 16(5):783-793.
8. Das K., et al. Study of the properties of microcrystalline cellulose particles from different renewable resources by XRD, FTIR, nanoindentation, TGA and SEM. J. Polym. Environ. 2010, 18(3):355-363.
9. Doyle C.D. Kinetic analysis of thermogravimetric data. J. Appl. Polym. Sci. 1961, 5(15):285-292.
10. El-Sakhawy M., Hassan M.L. Physical and mechanical properties of microcrystalline cellulose prepared from agricultural residues. Carbohydr. Polym. 2007, 67(1):1-10.
11. Flynn J.H., Wall L.A. A quick direct method for determination of activation energy from thermogravimetric data. J. Polym. Sci. Polym. Lett. 1966, 4(5PB):323-328.
12. Friedman H.L. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to phenolic plastic. J. Polym. Sci. Polym. Sym. (6pc) 1964, 183-195.
13. Jiang G.Z., et al. A systematic study of the kinetics of lignin pyrolysis. Thermochim. Acta 2010, 498(1-2):61-66.
14. Kim J.S., et al. Cellulose hydrolysis under extremely low sulfuric acid and high-temperature conditions. Appl. Biochem. Biotechnol. 2001, 91-3:331-340.
15. Kim U.J., et al. Thermal decomposition of native cellulose: influence on crystallite size. Polym. Degradr. Stabil. 2010, 95(5):778-781.
16. Kissinger H.E. Reaction kinetics in differential thermal analysis. Anal. Chem. 1957, 29(11):1702-1706.
17. Nelson M.L., Conrad C.M. Improvements in the acid-hydrolysis method of determining the crystallinity of cellulose. Text. Res. J. 1948, 18(3):149-164.
18. Ozawa T. A new method of analyzing thermogravimetric data. Bull. Chem. Soc. Jpn. 1965, 38(11):1881-1886.
19. Poletto M., et al. Crystalline properties and decomposition kinetics of cellulose fibers in wood pulp obtained by two pulping processes. Polym. Degradr. Stabil. 2011, 96(4):679-685.
20. Ramajo-Escalera B., et al. Model-free kinetics applied to sugarcane bagasse combustion. Thermochim. Acta 2006, 448(2):111-116.
21. Segal L., et al. An empirical method for estimating the degree of crystallinity of native cellulose using the X-ray diffractometer. Text. Res. J. 1959, 29:786-794.
22. Shafizadeh F. Pyrolytic reactions and products of biomass. Fundamentals of Thermochemical Biomass Conversion 1985, 183-214. Elsevier, London. R.P. Overend, T.A. Milne, L.K. Mudge (Eds.).
23. Sharples A. The hydrolysis of cellulose and its relation to structure. Trans. Faraday Soc. 1957, 53(7):1003-1013.
24. Shen D.K., Gu S. The mechanism for thermal decomposition of cellulose and its main products. Bioresour. Technol. 2009, 100(24):6496-6504.
25. Tang L.G., et al. Evaluation of microcrystalline cellulose. I. Changes in ultrastructural characteristics during preliminary acid hydrolysis. J. Appl. Polym. Sci. 1996, 59(3):483-488.
26. TAPPI TAPPI Test Methods, T222 om-02. Acid-insoluble Lignin in Wood and Pulp 2002, TAPPI Press, Atlanta.
27. TAPPI TAPPI Test Methods, T211 om-93, Ash in Wood, Pulp, Paper and Paperboard: Combustion at 525°C 1993, TAPPI Press, Atlanta.
28. TAPPI TAPPI Test Methods, T249 cm-00, Carbohydrate Composition of Extractive-free Wood and Wood Pulp by Gas-liquid Chromatography 2000, TAPPI Press, Atlanta.
29. TAPPI TAPPI Test Methods, T204 cm-97, Solvent Extractives of Wood and Pulp 1997, TAPPI Press, Atlanta.
30. Wang S., et al. Mechanism study on cellulose pyrolysis using thermogravimetric analysis coupled with infrared spectroscopy. Front. Energy Power Eng. Chin. 2007, 1(4):413-419.
31. Xiang Q. Conversion of Lignocellulosic Substrate into Chemicals: Kinetic Study of Dilute Acid Hydrolysis and Lignin Utilization, Ph.D. Thesis 2002, University of Auburn, Alabama.
32. Xiang Q., et al. A comprehensive kinetic model for dilute-acid hydrolysis of cellulose. Appl. Biochem. Biotechnol. 2003, 105:337-352.
33. Xiang Q., et al. Heterogeneous aspects of acid hydrolysis of alpha-cellulose. Appl. Biochem. Biotechnol. 2003, 105:505-514.