Morphologically controlled synthesis of copper oxides and their catalytic applications in the synthesis of propargylamine and oxidative degradation of methylene blue

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 392, Issue 1, 2011, Pages 271-282

  Srivastava, Rajendra ^a   Anu Prathap, M U ^a   Kore, Rajkumar ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY ROPAR   (India)

Author keywords

Copper oxide; Methylene blue degradation; Morphologically controlled synthesis; Propargylamine; Structure directing agents

Indexed keywords

CATALYST ACTIVITY; CATALYTIC OXIDATION; CHEMICAL BONDS; COPPER; DEGRADATION; HYDROGEN; HYDROGEN PEROXIDE; METHANOL; NONIONIC SURFACTANTS; POLYMERS; SCANNING ELECTRON MICROSCOPY; SORPTION; SURFACE STRUCTURE; SYNTHESIS (CHEMICAL); TRANSMISSION ELECTRON MICROSCOPY; ULTRAVIOLET VISIBLE SPECTROSCOPY; X RAY DIFFRACTION;

CATALYTIC APPLICATIONS; CONTROLLED SYNTHESIS; FORMATION MECHANISM; FOURIER TRANSFORM INFRARED; HYDROTHERMAL TIME; HYDROTHERMAL TREATMENTS; METAL OXIDES; METHYLENE BLUE; NITROGEN SORPTION; NONIONIC; OXIDATIVE DEGRADATION; POLYMERIC SURFACTANT; PROPARGYLAMINE; SEM AND TEM; STRUCTURE DIRECTING AGENTS; SURFACE AREA; THREE-COMPONENT COUPLING REACTION; UV VISIBLE SPECTROSCOPY; XRD;

COPPER OXIDES;

ALCOHOL; AMINE; COPPER OXIDE; HYDROGEN PEROXIDE; METAL OXIDE; METHANOL; METHYLENE BLUE; NITROGEN; NONIONIC SURFACTANT; POLYMER; PROPARGYLAMINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; FOURIER TRANSFORMATION; HYDROTHERMAL VENT; MORPHOLOGY; OXIDATION; PRIORITY JOURNAL; REACTION ANALYSIS; SCANNING ELECTRON MICROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 82855172053     PISSN: 09277757     EISSN: 18734359     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2011.10.004     Document Type: Article

References (50)

1. Mann S. Self-assembly and transformation of hybrid nano-objects and nanostructures under equilibrium and non-equilibrium conditions. Nat. Mater. 2009, 8:781-792.
2. Zhang Q., Liu S.-J., Yu S.-H. Recent advances in oriented attachment growth and synthesis of functional materials: concept evidence mechanism and future. J. Mater. Chem. 2009, 19:191-207.
3. Lou X.W., Archer L.A., Yang Z. Hollow micro-/nanostructures synthesis and applications. Adv. Mater. 2008, 20:3987-4019.
4. Whitesides G.M., Grzybowski B. Self-assembly at all scales. Science 2002, 295:2418-2421.
5. Colfen H., Antonietti M. Mesocrystals inorganic superstructures made by highly parallel crystallization and controlled alignment. Angew. Chem. Int. Ed. 2005, 44:5576-5591.
6. Tang Z., Kotov N.A., Giersig M. Spontaneous organization of single CdTe nanoparticles into luminescent nanowires. Science 2002, 297:237-240.
7. Privman V., Goia D.V., Park J., Matijevic E.J. Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors. J. Colloid Interface Sci. 1999, 213:36-45.
8. Libert S., Gorshkov V., Privman V., Goia D., Matijevic E. Formation of monodispersed cadmium sulfide particles by aggregation of nanosize precursors. Adv. Colloid Interface Sci. 2003, 100-102:169-183.
9. van Bommel K.J.C., Friggeri A., Shinkai S. Organic templates for the generation of inorganic materials. Angew. Chem. Int. Ed. 2003, 42:980-999.
10. Li M., Schnablegger H., Mann S. Coupled synthesis and self-assembly of nanoparticles to give structures with controlled organization. Nature 1999, 402:393-395.
11. Yu S.-H., Cölfen H.J. Bio-inspired crystal morphogenesis by hydrophilic polymers. Mater. Chem. 2004, 14:2124-2147.
12. Pacholski C., Kornowski A., Weller H. Self-assembly of ZnO from nanodots to nanorods. Angew. Chem. Int. Ed. 2002, 41:1188-1191.
13. Penn R.L., Banfield J.F. Imperfect oriented attachment dislocation generation in defect free nanocrystals. Science 1998, 281:969-971.
14. Tosheva L., Valtchev V.P. Nanozeolites synthesis crystallization mechanism and applications. Chem. Mater. 2005, 17:2494-2513.
15. Stein A. Advances in microporous and mesoporous solids highlights of recent progress. Adv. Mater. 2003, 15:763-775.
16. Taguchi A., Schüth F. Ordered mesoporous materials in catalysis. Micropor. Mesopor. Mater. 2005, 77:1-45.
17. Schüth F. Non-siliceous mesostructured and mesoporous materials. Chem. Mater. 2001, 13:3184-3195.
18. Scott B.J., Wirnsberger G., Stucky G.D. Mesoporous and mesostructured materials for optical applications. Chem. Mater. 2001, 13:3140-3150.
19. Sanchez C., Lebeau B., Chaput F., Boilot J.P. Optical properties of functional hybrid organic-inorganic nanocomposites. Adv. Mater. 2003, 15:1969-1994.
20. 2 microstructure and its application in water purification. J. Colloid Interface Sci. 2010, 348:600-607.
21. Anu Prathap M.U., Srivastava R. Synthesis of nanoporous metal oxides through the self-assembly of phloroglucinol-formaldehyde resol and tri-block copolymer. J. Colloid Interface Sci. 2011, 358:399-408.
22. Li J.Y., Xiong S.L., Xi B.J., Li X.G., Qian Y.T. Synthesis of CuO perpendicularly cross-bedded microstructure via a precursor-based route. Cryst. Growth Des. 2009, 9:4108-4115.
23. Vaseem M., Umar A., Hahn Y.B., Kim D.H., Lee K.S., Jang J.S., Lee J.S. Flower-shaped CuO nanostructures structural photocatalytic and XANES studies. Catal. Commun. 2008, 10:11-16.
24. Zhang X.J., Wang G.F., Liu X.W., Wu J.J., Li M., Gu J., Liu H., Fang B. Different CuO nanostructures synthesis characterization and applications for glucose sensors. J. Phys. Chem. C 2008, 112:16845-16849.
25. 2S detection by vertically aligned CuO nanowire array sensors. Phys. Chem. C 2008, 112:16017-16021.
26. 3Cl plates as precursor. Mater. Chem. Phys. 2008, 112:442-447.
27. Liu B., Zeng H.C. Mesoscale organization of CuO nanoribbons formation of Dandelions. J. Am. Chem. Soc. 2004, 126:8124-8125.
28. Song R.Q., Cölfen H. Additive controlled crystallization. CrystEngComm 2011, 13:1249-1276.
29. Meldrum F.C., Colfen H. Controlling mineral morphologies and structures in biological and synthetic systems. Chem. Rev. 2008, 108:4332-4432.
30. 2O, and CuO nanotubes and nanorods. Chem. Commun. 2003, 188:4-1885.
31. Chang Y., Zeng H.C. Controlled synthesis and self-assembly of single-crystalline CuO nanorods and nanoribbons. Cryst. Growth Des. 2004, 4:397-402.
32. Xu Y.Y., Chen D.R., Jiao X.L. Fabrication of CuO pricky microspheres with tunable size by a simple solution route. J. Phys. Chem. B 2005, 109:13561-13566.
33. Wang W., Zhan Y., Wang G. One-step solid-state reaction to the synthesis of copper oxide nanorods in the presence of a suitable surfactant. Chem. Commun. 2001, 8:727-728.
34. 2 nanowires CuO nanowires and CuO nanobelts. Chem. Phys. Lett. 2004, 393:64-69.
35. Hong Z.S., Cao Y., Deng J.F. A convenient alcohothermal approach for low temperature synthesis of CuO nanoparticles. Mater. Lett. 2002, 52:34-38.
36. Park S.H., Kim H.J. Unidirectionally aligned copper hydroxide crystalline nanorods from two-dimensional copper hydroxy nitrate. J. Am. Chem. Soc. 2004, 126:14368-14369.
37. Vaseem M., Umar A., Kim S.H., Hahn Y.B. Low-temperature synthesis of flower-shaped CuO nanostructures by solution process: formation mechanism and structural properties. J. Phys. Chem. C 2008, 112:5729-5735.
38. Liu X.M., Zhang X.G., Fu S.Y. Preparation of urchinlike NiO nanostructures and their electrochemical capacitive behaviors. Mater. Res. Bull. 2006, 41:620-627.
39. Nyquist R.A., Kagel R.O. Infrared Spectra of Inorganic Compounds 1971, Academic Press, Inc., New York, London, p. 220.
40. Xiao H.M., Fu S.Y., Zhu L.P., Li Y.Q., Yang G. Controlled synthesis and characterization of CuO nanostructures through a facile hydrothermal route in the presence of sodium citrate. Eur. J. Inorg. Chem. 2007, 14:1966-1971.
41. 2-x nanoparticles. J. Appl. Phys. 2000, 87:1318-1321.
42. Zhao D., HuO Q., Feng J., Chemelka B.F., Stucky G.D. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered hydrothermally stable mesoporous silica structures. J. Am. Chem. Soc. 1998, 120:6024-6036.
43. Li C.J. The development of catalytic nucleophilic additions of terminal alkynes in water. Acc. Chem. Res. 2010, 43:581-590.
44. Patil M.K., Keller M., Reddy B.M., Pale P., Sommer J. Copper zeolites as a green catalysts for multi component reactions of aldehydes, terminal alkynes and amines: an efficient and green synthesis of propargylamines. Eur. J. Org. Chem. 2008, 26:4440-4445.
45. 3) bond cleavage in generation of iminium intermediates. J. Am. Chem. Soc. 2010, 32:5332-5333.
46. Nakamura S., Ohara M., Nakamura Y., Shibata N., Toru T. Copper catalyzed enantioselective three-component synthesis of optically active propargylamines from aldehydes, amines, and aliphatic alkynes. Chem. Eur. J. 2010, 16:2360-2362.
47. Choudary B.M., Mannepalli C.S., Kantam L., Sreedhar B. Hydroxyapatite supported copper catalyst for effective three-component coupling. Tetrahedron Lett. 2004, 45:7319-7321.
48. Eshghi H., Zohuri G.H., Damavandi S. One-pot multicomponent route to propargylamines using ferric hydrogensulfate. Eur. J. Chem. 2011, 2:100-103.
49. 2 hollow octahedral. Solid State Sci. 2009, 11:1265-1269.
50. 2 nanorods and their rapid and efficient catalytic oxidation of methylene blue dye. Catal. Commun. 2006, 7:408-412.