Mechanism of hydrogen transfer in arsane generation by aqueous tetrahydridoborate: Interference effects of AuIII and other noble metals

Spectrochimica Acta - Part B Atomic Spectroscopy

Volumn 66, Issue 9-10, 2011, Pages 740-747

  Pagliano, Enea ^a   Onor, Massimo ^b   Meija, Juris ^c   Mester, Zoltan ^c   Sturgeon, Ralph E ^c   D'Ulivo, Alessandro ^b  

^a SCUOLA NORMALE SUPERIORE   (Italy)

^b CNR   (Italy)

^c NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

Hydride generation; Mechanistic interference; Noble metal; Reaction mechanism; Tetrahydridoborate

Indexed keywords

BATCH EXPERIMENTS; CONTINUOUS FLOWS; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; GENERATION SYSTEMS; H/D EXCHANGE; HYDRIDE GENERATIONS; HYDROGEN TRANSFER; INTERFERENCE EFFECTS; INTERMEDIATE SPECIE; ISOTOPIC COMPOSITION; METAL CONCENTRATIONS; REACTION MECHANISM; REACTION YIELDS; TETRAHYDRIDOBORATE; TRACE LEVEL;

ARSENIC; ATOMIC ABSORPTION SPECTROMETRY; GAS CHROMATOGRAPHY; HYDRIDES; HYDROGEN; INERT GASES; ISOTOPES; MASS SPECTROMETRY; METAL IONS; METALS; PLATINUM; PRECIOUS METALS; REACTION INTERMEDIATES;

PALLADIUM;

EID: 82755197137     PISSN: 05848547     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.sab.2011.09.009     Document Type: Article

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