Oxidation of toluene on γ-Al2O3 supported copper-manganese catalysts

Environmental Engineering Science

Volumn 28, Issue 12, 2011, Pages 827-833

  Kim, Hye Jin ^a   Choi, Sung Woo ^b   Lee, Chang Seop ^b   Wielage, Bernhard ^c   Bae, Sunyoung ^d   Obare, Sherine O ^e   Inyang, Hilary I ^f  

^a UNIVERSITY OF NORTH CAROLINA AT CHARLOTTE   (United States)

^b Keimyung University   (South Korea)

^c CHEMNITZ UNIVERSITY OF TECHNOLOGY   (Germany)

^d Seoul Women University   (South Korea)

^e WESTERN MICHIGAN UNIVERSITY   (United States)

^f University of North Carolina at Charlotte   (United States)

Author keywords

Copper manganese catalysts; Cu1.5Mn1.5O4; Temperature programmed reduction; Toluene oxidation; XRD

Indexed keywords

ACTIVE SITE; BRUNAUER-EMMETT-TELLER SURFACE AREAS; FIXED-BED FLOW REACTORS; HIGH ACTIVITY; HIGH OXIDATION STATE; MN CATALYST; OXIDATION LEVEL; OXIDATION OF TOLUENES; OXIDE CATALYSTS; REDOX ACTIVITY; REDOX PEAKS; TEMPERATURE PROGRAMMED OXIDATION; TEMPERATURE RANGE; TEMPERATURE-PROGRAMMED REDUCTION; TOLUENE OXIDATION; WEIGHT RATIOS; XRD;

BINDING ENERGY; CATALYTIC OXIDATION; COPPER; INCINERATION; MANGANESE; MANGANESE COMPOUNDS; OXIDATION; PHOTONS; SCANNING ELECTRON MICROSCOPY; TOLUENE; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYST ACTIVITY;

ALUMINUM OXIDE; COPPER; MANGANESE; TOLUENE;

ARTICLE; CATALYSIS; CATALYST; OXIDATION; OXIDATION REDUCTION REACTION; OXYGEN CONSUMPTION; SCANNING ELECTRON MICROSCOPY; TEMPERATURE SENSITIVITY; THERMAL CONDUCTIVITY; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 82555195644     PISSN: 10928758     EISSN: 15579018     Source Type: Journal    
DOI: 10.1089/ees.2010.0116     Document Type: Article

References (27)

1. Alonso, L., Palacios, J.M., Garcia, E., and Moliner, R. (2000). Characterization of Mn and Cu oxides as regenerable sorbents for hot coal gas desulfurization. Fuel Process. Technol. 62, 31.
2. Alvarez-Galvan, M.C., Pawelec, B., O'Shea, V.A.P., Fierro, J.L.G., and Arias, P.L. (2004). Formaldehyde/methanol combustion on alumina-supported manganese-palladium oxide catalyst. Appl. Catal. B Environ. 51, 83.
3. 2(cubic) catalysts. Catal. Commun. 5, 115.
4. Cooper, C.D., and Alley, F.C. (2002). Air Pollution Control, 3rd edition. Long Grove, IL: Waveland Press.
5. Dow, W.P., Wang, Y.P., and Huang, T.J. (2000). TPR and XRD studies of yttria-doped ceria/γ-alumina-supported copper oxide catalyst. Appl. Catal. A Gen. 190, 25.
6. 3 catalysts: oxidation of mixture. Appl. Catal. B Environ. 50, 161.
7. Hu, J., Chu, W., and Shi, L. (2008). Effects of carrier and Mn loading on supported manganese oxide catalysts for catalytic combustion of methane. Nat. Gas Chem. 17, 159.
8. Jeon, H.J. and Seo, G. (2002). Introduction of Catalysis, 4th edition. Seoul: Hanlimwon Publishers.
9. Kim, H.J., Choi, S.W., and Inyang, H.I. (2008). Catalytic oxidation of toluene in contaminant emission control systems using Mn-Ce/c-Al2O3. Environ. Tech. 29, 559.
10. Kim, S.C. (2002). The catalytic oxidation of aromatic hydrocarbons over supported metal oxide. J. Hazard. Mater. B91, 285.
11. Labaki, M., Siffert, S., Lamonier, J.F., Zhilinskaya, E.A., and Aboukais, A. (2003). Total oxidation of propene and toluene in the presence of zirconia doped by copper and yttrium: role of anionic vacancies. Appl. Catal. B Environ. 43, 261.
12. Lee, J.D., Park, N.K., Ryu, S.O., Kim, K.S., and Lee, T.J. (2004). Self-oscillatory behavior in toluene oxidation on zeolite-NaX. Appl. Catal. A Gen. 275, 79.
13. Li, W.B., Chu, W.B., Zhuang, M., and Hua, J. (2004). Catalytic oxidation of toluene on Mn-containing mixed oxides prepared in reverse microemulsions. Catal. Today 93, 205.
14. Li, W.B., Zhuang, M., and Wang, J.X. (2008). Catalytic combustion of toluene on Cu-Mn/MCM-41 catalysts: influence of calcinations temperature and operation conditions on the catalytic activity. Catal. Today 137, 340.
15. Li, W.B., Zhuang, M., Xiao, T.C., and Green, M.L.H. (2006). MCM-41 supported Cu-Mn catalysts for catalytic oxidation of toluene at low. J. Phys. Chem. B 110, 21568.
16. 3 catalysts prepared in the presence of polyvinyl pyrrolidone. J. Hazard. Mater. 176, 1106.
17. Mirzaei, A.A., Shaterian, H.R., Habibi, M., Hutchings, G.J., and Taylor, S.H. (2003). Characterization of copper-manganese oxide catalysts: effect of precipitate ageing upon the structure and morphology of precursors and catalysts. Appl. Catal. A Gen. 253, 499.
18. Morales, M.R., Barbero, B.P., and Cadus, L.E. (2006). Total oxidation of ethanol and propane over Mn-Cu mixed oxide catalysts. Appl. Catal. B Environ. 67, 229.
19. 2 for ethanol total oxidation. Fuel 88, 2122.
20. Niemantsverdriet, J.W. (2000). Spectroscopy in Catalysis. Germany: Wiley-VCH Verlag GmbH.
21. Okumura, K., Tanaka, H., and Niwa, M. (1999). Influence of acid-base property of support on the toluene combustion activity of palladium. Catal. Lett. 58, 43.
22. Papavasiliou, J., Avgouropoulos, G., and Ioannides, T. (2005). Steam reforming of methanol over copper-manganese spinel oxide catalysts. Catal. Commun. 6, 497.
23. Patterson, M.J., Angove, D.E., and Cant, N.W. (2001). The effect of metal order on the oxidation of a hydrocarbon mixture over alumina-supported combined platinum/rhodium catalysts. Appl. Catal. B Environ. 35, 53.
24. Rodrigues, A.C.C. (2007) Metallic mixed oxides (Pt, Mn or Cr) as catalysts for the gas-phase toluene oxidation. Catal. Commun. 8, 1227.
25. Scire, S., Minico, S., Crisafulli, C., Satrkano, C., and Pistone, A. (2003). Catalytic combustion of volatile organic compounds on gold/cerium oxide catalysts. Appl. Catal. B Environ. 40, 43.
26. 2 mixed oxide catalysts for complete oxidation of formaldehyde: effect of preparation method and calcinations temperature. Appl. Catal. B Environ. 62, 265.
27. 3-supported transition-metal oxide catalysts for catalytic incineration of toluene. Chemosphere 55, 11.