Single atom hot-spots at Au-Pd nanoalloys for electrocatalytic H 2O 2 production

Journal of the American Chemical Society

Volumn 133, Issue 48, 2011, Pages 19432-19441

  Jirkovský, Jakub S ^a,e   Panas, Itai ^b   Ahlberg, Elisabet ^c   Halasa, Matej ^d   Romani, Simon ^a   Schiffrin, David J ^a  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

^b CHALMERS UNIVERSITY OF TECHNOLOGY   (Sweden)

^c UNIVERSITY OF GOTHENBURG   (Sweden)

^d SOLVAY S A   (Belgium)

^e ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AU NANOPARTICLE; AU SURFACES; DFT MODELING; ELECTROCATALYTIC; HOTSPOTS; NANO-ALLOYS; NOVEL STRATEGIES; OXYGEN REDUCTION REACTION; PD ATOMS; POLYMER ELECTROLYTE FUEL CELLS; PRODUCTION COST; PROTON EXCHANGE MEMBRANES; SINGLE ATOMS; STICKING PROBABILITY; VULCAN XC72;

ATOMS; ELECTROLYTIC REDUCTION; GOLD; NANOPARTICLES; PLATINUM; RHODIUM; SYNTHESIS (CHEMICAL); TRANSITION METALS;

PALLADIUM;

ALLOY; ELECTROLYTE; GOLD NANOALLOY; GOLD NANOPARTICLE; HYDROGEN PEROXIDE; OXYGEN; PALLADIUM; PALLADIUM NANOALLOY; PLATINUM; POLYMER; RHODIUM; TRANSITION ELEMENT; UNCLASSIFIED DRUG; WATER;

ARTICLE; ATOM; CONCENTRATION RESPONSE; CYCLIC POTENTIOMETRY; DECOMPOSITION; DENSITY FUNCTIONAL THEORY; ELECTROCHEMICAL ANALYSIS; ELECTROCHEMISTRY; ENERGY; MOLECULAR MODEL; MOLECULAR STABILITY; NANOCATALYSIS; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; REDUCTION; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

ALLOYS; CATALYSIS; ELECTROCHEMICAL TECHNIQUES; GOLD; HYDROGEN PEROXIDE; NANOPARTICLES; OXIDATION-REDUCTION; PALLADIUM;

EID: 82555194625     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja206477z     Document Type: Article

References (52)

1. Hess, W. T. In Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 13, 4 th ed.; Kroschwitz, J. I., Howe-Grant, M., Eds.; Wiley: New York, 1995; p 961.
2. HPPO technology; http://www.basf.com; http://www.dow.com.
3. Edwards, J. K.; Solsona, B.; Ntainjua, E.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Science 2009, 323, 1037-1041
4. Stamenkovic, V. R.; Fowler, B.; Mun, B. S.; Wang, G.; Ross, P. N.; Lucas, C. A.; Markovic, N. M. Science 2007, 315, 493-497
5. Yamanaka, I.; Onizawa, T.; Takenaka, S.; Otsuka, K. Angew. Chem., Int. Ed. 2003, 42, 3653-3655
6. Vielstich, W.; Lamm, A.; Gasteiger, H. A. Handbook of Fuel Cells, Fundamentals, Technology and Applications; Wiley: New York, 2003.
7. Hoogers, G. Catalysts for the Proton Exchange Membrane Fuel Cell; CRC: Boca Raton, FL, 2003.
8. Gasteiger, H. A.; Markovic, N. M. Science 2009, 324, 48-49
9. Jirkovsky, J. S.; Busch, M.; Ahlberg, E.; Panas, I.; Krtil, P. J. Am. Chem. Soc. 2011, 133, 5882-5892
10. Edwards, J. K.; Hutchings, G. J. Angew. Chem., Int. Ed. 2008, 47, 9192-9198
11. Tammeveski, K.; Kontturi, K.; Nichols, R. J.; Potter, R. J.; Schiffrin, D. J. J. Electroanal. Chem. 2001, 515, 101-112
12. Wass, R. T. J.; Ahlberg, E.; Panas, I.; Schiffrin, D. J. Phys. Chem. Chem. Phys. 2006, 8, 4189-4199
13. Adzic, R. In Electrocatalysis; Lipkowski, J.; Ross, P. N., Eds.; Wiley: New York, 1998; Vol. 197.
14. Kim, J.; Gewirth, A. A. J. Phys. Chem. B 2006, 110, 2565-2571
15. Markovic, N. M.; Gasteiger, H. A.; Ross, P. N. J. Phys. Chem. 1995, 99, 3411-3415
16. Li, X.; Gewirth, A. A. J. Am. Chem. Soc. 2004, 127, 5252-5260
17. Durand, R. R.; Anson, F. C. J. Electroanal. Chem. 1982, 134, 273-289
18. Jirkovsky, J. S.; Halasa, M.; Schiffrin, D. J. Phys. Chem. Chem. Phys. 2010, 12, 8042-8052
19. Lueckoff, U. D; Paucksch, H.; Luft, G. Ger. Offen. 1992, DE 4127918, A1 19920910.
20. Edwards, J. K.; Thomas, A.; Carley, A. F.; Herzing, A. A.; Kiely, C. J.; Hutchings, G. J. Green Chem. 2008, 10, 388-394
21. Stamenkovic, V. R.; Mun, B. S.; Mayrhofer, K. J. J.; Ross, P. N.; Markovic, N. M.; Rossmeisl, J.; Greeley, J.; Nørskov, J. K. Angew. Chem., Int. Ed. 2006, 45, 2897-2901
22. Stamenkovic, V. R.; Mun, B. S.; Arenz, M.; Mayrhofer, K. J. J.; Lucas, C. A.; Wang, G.; Ross, P. N.; Markovic, N. M. Nat. Mater. 2007, 6, 241-247
23. Maroun, F.; Ozanam, F.; Magnussen, O. M.; Behm, R. J. Science 2001, 293, 1811-1814
24. Liu, P.; Norskov, J. K. Phys. Chem. Chem. Phys. 2001, 3, 3814-3818
25. Pluntke, Y.; Kibler, L. A.; Kolb, D. M. Phys. Chem. Chem. Phys. 2008, 10, 3684-3688
26. Schafer, P. J.; Kibler, L. A. Phys. Chem. Chem. Phys. 2010, 12, 15225-15230
27. Al-Odail, F. A.; Anastasopoulos, A.; Hayden, B. E. Phys. Chem. Chem. Phys. 2010, 12, 11398-11406
28. Wang, D.; Villa, A.; Porta, F.; Sua, D.; Prati, L. Chem. Commun. 2006, 1956-1958
29. Ketchie, W. C.; Murayama, M.; Davis, R. J. J. Catal. 2007, 250, 264-273
30. Delley, B. J. Chem. Phys. 1990, 92, 508-517
31. Delley, B. J. Chem. Phys. 2000, 113, 7756-7764
32. Materials Studio Release Notes, Release 5.0, Accelrys Software, Inc.: San Diego, CA, 2009.
33. Perdew, J.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868
34. Delley, B. Phys. Rev. B 2002, 66, 1551251-1551259
35. Chen, M.; Kumar, D.; Yi, C. W.; Goodman, D. W. Science 2005, 310, 291-293
36. Panas, I.; Sieghbahn, P.; Wahlgren, U. J. Chem. Phys. 1989, 90, 6791-6801
37. Xiao, L.; Zhuang, L.; Liu, Y.; Lu, J.; Abruna, H. D. J. Am. Chem. Soc. 2009, 131, 602-608
38. Ham, H. C.; Hwang, G. S.; Han, J.; Nam, S. W.; Lim, T. H. J. Phys Chem. C 2009, 113, 12943-12945
39. Li, J.; Staykov, A.; Ishihara, T.; Yoshizawa, K. J. Phys. Chem. C 2011, 115, 7392-7398
40. Lundin, A.; Panas, I.; Ahlberg, E. J. Phys. Chem. A 2007, 111, 9080-9086
41. Busch, M.; Ahlberg, E.; Panas, I. Phys. Chem. Chem. Phys. 2011, 13, 15062-15068
42. Panas, I.; Schüle, J.; Siegbahn, P. E. M.; Wahlgren, U. Chem. Phys. Lett. 1988, 149, 265-272
43. Ham, H. C.; Hwang, G. S.; Han, J.; Nam, S. W.; Lim, T. H. J. Phys. Chem. C 2010, 114, 14922-14928
44. Ferrer, D.; Blom, D. A.; Allard, L. F.; Mejia, S.; Perez-Tijerinacd, E.; Jose-Yacaman, M. J. Mater. Chem. 2008, 18, 2442-2446
45. Ruban, A. V.; Skriver, H. L.; Nørskov, J. K. Phys. Rev B 1999, 59, 15990-16000
46. Wang, L.-L.; Johnson, D. D. J. Am. Chem. Soc. 2009, 131, 14023-14029
47. Venkatachalam, S; Jakob, T. Phys. Chem. Chem. Phys. 2009, 11, 3263-3270
48. Soto-Verdugo, V.; Metiu, H. Surf. Sci. 2007, 601, 5332-5339
49. Bruckenstein, S.; Shay, M. J. Electroanal. Chem. 1985, 188, 131-136
50. Bjorling, A.; Ahlberg, E.; Feliu, J. M. Electrochem. Commun. 2010, 12, 359-361
51. Bard, A. J.; Faulkner, L. R., Electrochemical Methods-Fundamentals and Application; Wiley: New York, 2001.
52. Panas, I.; Siegbahn, P.; Wahlgren, U. Chem. Phys. 1987, 112, 325-337