Production and characterization of biopolyols and polyurethane foams from crude glycerol based liquefaction of soybean straw

Bioresource Technology

Volumn 103, Issue 1, 2012, Pages 227-233

  Hu, Shengjun ^a   Wan, Caixia ^a   Li, Yebo ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

Biomass; Biopolyols; Crude glycerol; Liquefaction; Polyurethane foams

Indexed keywords

ACID NUMBERS; ALTERNATIVE SOLVENTS; BIO-POLYOLS; BIOMASS LOADING; CRUDE GLYCEROL; HYDROXYL NUMBER; LIGNOCELLULOSIC BIOMASS; LIQUEFACTION PROCESS; MATERIAL PROPERTY; PETROLEUM SOLVENTS; POLYURETHANE FOAM; POLYURETHANE FOAMS; SOYBEAN STRAW;

BIOMASS; COMPRESSIVE STRENGTH; GLYCEROL; MATERIALS PROPERTIES; POLYURETHANES; RIGID FOAMED PLASTICS; SULFURIC ACID;

LIQUEFACTION;

BIOPOLYOL; GLYCEROL; HYDROXYL GROUP; LIGNOCELLULOSE; POLYOL; POLYURETHAN FOAM; SOLVENT; SULFURIC ACID; UNCLASSIFIED DRUG;

BIOMASS; CRUDE OIL; FOAM; LIQUEFACTION; POLYMER; SOLVENT; SOYBEAN; STRAW; VISCOSITY;

ARTICLE; BIOMASS; COMPRESSIVE STRENGTH; DENSITY; LIQUEFACTION; PRIORITY JOURNAL; SOYBEAN; VISCOSITY;

BIOMASS; BIOTECHNOLOGY; GLYCEROL; POLYMERS; POLYURETHANES; SOYBEANS; SULFURIC ACIDS; TEMPERATURE; TIME FACTORS; VISCOSITY; WASTE PRODUCTS;

GLYCINE MAX;

EID: 82455191722     PISSN: 09608524     EISSN: 18732976     Source Type: Journal    
DOI: 10.1016/j.biortech.2011.09.125     Document Type: Article

References (23)

1. Alma M.H., Shiraishi N. Preparation of polyurethane-like foams from NaOH-catalyzed liquefied wood. Holz. Roh. Werkst. 1998, 56(4):245-246.
2. Alma M.H., Basturk M.A., Digrak M. New polyurethane-type rigid foams from liquified wood powders. J. Mater. Sci. Lett. 2003, 22(17):1225-1228.
3. Biswas A.K., Ganguly D. Esterification of fatty acids with glycerol. Nature 1960, 188:56-57.
4. Chen F.G., Lu Z.M. Liquefaction of wheat straw and preparation of rigid polyurethane foam from the liquefaction products. J. Appl. Polym. Sci. 2009, 111(1):508-516.
5. Dobroth Z.T., Hu S.J., Coats E.R., McDonald A.G. Polyhydroxybutyrate synthesis on biodiesel wastewater using mixed microbial consortia. Bioresour. Technol. 2011, 102(3):3352-3359.
6. Dow polyols. <>. Last accessed on 7/28/2011. http://www.dow.com/polyurethane/la/en/apps/building/poly.htm.
7. Hassan E.B.M., Shukry N. Polyhydric alcohol liquefaction of some lignocellulosic agricultural residues. Ind. Crops Prod. 2008, 27(1):33-38.
8. Ionescu M., Petrovic Z.S. High functionality polyether polyols based on polyglycerol. J. Cell. Plast. 2010, 46(3):223-237.
9. Johnson D.T., Taconi K.A. The glycerin glut: options for the value-added conversion of crude glycerol resulting from biodiesel production. Environ. Prog. 2007, 26(4):338-348.
10. Lee S.H., Yoshioka M., Shiraishi N. Liquefaction of corn bran (CB) in the presence of alcohols and preparation of polyurethane foam from its liquefied polyol. J. Appl. Polym. Sci. 2000, 78(2):319-325.
11. Lee S.H., Teramoto Y., Shiraishi N. Biodegradable polyurethane foam from liquefied waste paper and its thermal stability, biodegradability, and genotoxicity. J. Appl. Polym. Sci. 2002, 83(7):1482-1489.
12. Pachauri, N., He, B. 2006. In Presented at 2006 ASABE Annual International Meeting, Paper number: 066223.
13. Petrovic Z.S. Polyurethanes from vegetable oils. Polym. Rev. 2008, 48(1):109-155.
14. Ruppert A.M., Meeldijk J.D., Kuipers B.W.M., Erne B.H., Weckhuysen B.M. Glycerol etherification over highly active CaO-based materials: new mechanistic aspects and related colloidal particle formation. Chem. Eur. J. 2008, 14(7):2016-2024.
15. Thompson J.C., He B.B. Characterization of crude glycerol from biodiesel production from multiple feedstocks. Appl. Eng. Agric. 2006, 22(2):261-265.
16. Wang H., Chen H.Z. A novel method of utilizing the biomass resource. Rapid liquefaction of wheat straw and preparation of biodegradable polyurethane foam (PUF). J. Chin. Inst. Chem. Eng. 2007, 38:95-102.
17. Wang Y., Wu J., Wan Y.L.H., Yu F., Chen P., Lin X., Liu Y., Ruan R. Liquefaction of corn stover using industrial biodiesel glycerol. Int. J. Agric. Biol. Eng. 2009, 2(2):32-40.
18. Yamada T., Ono H. Rapid liquefaction of lignocellulosic waste by using ethylene carbonate. Bioresour. Technol. 1999, 70(1):61-67.
19. Yamada T., Ono H. Characterization of the products resulting from ethylene glycol liquefaction of cellulose. J. Wood. Sci. 2001, 47:458-464.
20. Yan Y.B., Pang H., Yang X.X., Zhang R.L., Liao B. Preparation and characterization of water-blown polyurethane foams from liquefied cornstalk polyol. J. Appl. Polym. Sci. 2008, 110(2):1099-1111.
21. Yao Y., Yoshioka M., Shiraishi N. Combined liquefaction of wood and starch in a polyethylene glycol/glycerin blended solvent. Mokuzai Gakkaishi 1993, 39:930-938.
22. Yao Y.G., Yoshioka M., Shiraishi N. Water-absorbing polyurethane foams from liquefied starch. J. Appl. Polym. Sci. 1996, 60(11):1939-1949.
23. Yu F., Le Z., Chen P., Liu Y., Lin X., Ruan R. Atmospheric pressure liquefaction of dried distillers grains (DDG) and making polyurethane foams from liquefied DDG. Appl. Biochem. Biotechnol. 2008, 148:235-243.