Natrolite is not a "soda-stone" anymore: Structural study of alkali (Li+), alkaline-earth (Ca2+, Sr2+, Ba2+) and heavy metal (Cd2+, Pb2+, Ag +) cation-exchanged natrolites

American Mineralogist

Volumn 96, Issue 11-12, 2011, Pages 1718-1724

  Lee, Yongjae ^a   Seoung, Donghoon ^a   Lee, Yongmoon ^a  

^a Yonsei University   (South Korea)

Author keywords

Crystal chemistry; Ion exchange; Natrolite; Rietveld refinement

Indexed keywords

ALKALINE EARTH METALS; ALKALINITY; CRYSTAL CHEMISTRY; HEAVY METALS; ION EXCHANGE; MOLECULES; POSITIVE IONS; RIETVELD REFINEMENT;

AMBIENT CONDITIONS; CHANNEL OPENING; DISTRIBUTION PATTERNS; LINEAR RELATIONSHIPS; NATROLITE; STRUCTURAL MODELS; STRUCTURAL STUDIES; UNIT-CELL VOLUME;

ZEOLITES;

CATION; CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; HEAVY METAL; ION EXCHANGE; NATROLITE; RIETVELD ANALYSIS; SYMMETRY;

EID: 81855166066     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2011.3853     Document Type: Article

References (21)

1. Alberti, A., Pongiluppi, D., and Vezzalini, G. (1982) The crystal chemistry of natrolite, mesolite and scolecite. Neues Jahrbuch für Mineralogie, 143, 231-248.
2. 2O at 20K. Acta Crystallographica, C40, 1658-1662.
3. Baur, W.H., Kassner, D., Kim, C.-H., and Sieber, N.H. (1990) Flexibility and distortion of the framework of natrolite: Crystal structures of ion-exchanged natrolites. European Journal of Mineralogy, 2, 761-769.
4. Comodi, P., Gatta, G.D., and Zanazzi, P.F. (2002) High-pressure structural behaviour of scolecite. European Journal of Mineralogy, 14, 567-574. (Pubitemid 34604745)
5. Klaproth, M.H. (1803) XV Ges. Naturforsch. Freunde. Berlin N. Schr., 4, 243-248.
6. Kvick, A., Stahl, K., and Smith, J.V. (1985) A neutron diffraction study of the bonding of zeolitic water in scolecite at 20K. Zeitschrift für Kristallographie, 171, 141-154.
7. Larson, A.C. and VonDreele, R.B. (1986) GSAS; General Structure Analysis System, Report LAUR 86-748. Los Alamos National Laboratory, New Mexico.
8. Lee, Y., Hriljac, J.A., Parise, J.B., and Vogt, T. (2005) Pressure-induced stabilization of ordered paranatrolite: A new insight into the paranatrolite controversy. American Mineralogist, 90, 252-257.
9. Lee, Y., Lee, Y., and Seoung, D. (2010) Natrolite may not be a "soda-stone" anymore: Structural study of fully K-, Rb-, and Cs-exchanged natrolite. American Mineralogist, 95, 1636-1641.
10. Lee, Y., Vogt, T., Hriljac, J.A., Parise, J.B., and Artioli, G. (2002) Pressure-induced volume expansion of zeolites in the natrolite family. Journal of the American Chemical Society, 124, 5466-5475. (Pubitemid 34506944)
11. Meier, W.M. (1960) The crystal structure of natrolite. Zeitschrift für Kristallographie, 113, 430-444.
12. Meneghinello, E., Martuccia, A., Albertia, A., and Renzob, F.D. (1999) Structural refinement of a K-rich natrolite: Evidence of a new extraframework cation site Microporous and Mesoporous Materials, 30, 89-94.
13. Rietveld, H.M. (1969) A profile refinement method for nuclear and magnetic structures. Journal of Applied Crystallography, 2, 65-71.
14. Ross, M., Flohr, M.J.K., and Ross, D.R. (1992) Crystalline solution series and order-disorder within the natrolite mineral group. American Mineralogist, 77, 685-703. (Pubitemid 23384348)
15. Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, 32, 751.
16. Shannon, R.D. and Prewitt, C.T. (1969) Effective ionic radii in oxides and fluorides. Acta Crystallographica, B25, 925.
17. Stuckenschmidt, E., Kassner, D., Joswig, W., and Baur, W.H. (1992) Flexibility and distortion of the collapsible framework of NAT topology: The crystal structure of NH4-exchanged natrolite. European Journal of Mineralogy, 4, 1229-1240. (Pubitemid 23387137)
18. Taylor, W.H., Meek, C.A., and Jackson, W.W. (1933) The structures of the fibrous zeolites. Zeitschrift für Kristallographie, 84, 373-398.
19. 3. Journal of Applied Crystallography, 20, 79-83.
20. Toby, B.H. (2001) EXPGUI, a graphical user interface for GSAS. Journal of Applied Crystallography, 34, 210-213. (Pubitemid 32290310)
21. Yamazaki, A., Kamioka, K., Matsumoto, H., and Otsuka, R. (1987) Structure refinement of K-exchanged natrolite by Rietveld method. Memoirs of the School of Science and Engineering, Waseda University, 118, 40-44. (Pubitemid 18611611)