Adducts of Rh2[MTPA]4 with some phosphine chalcogenides: Nature of binding and ligand exchange

Magnetic Resonance in Chemistry

Volumn 42, Issue 7, 2004, Pages 600-604

  Gáti, Tamás ^a   Simon, András ^a   Tóth, Gábor ^a   Magiera, Damian ^b   Moeller, Stefan ^b   Duddeck, Helmut ^b  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

^b LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

1H NMR; 31P NMR; 77Se NMR; Adduct formation; Dirhodium complexes; NMR; Phosphine chalcogenides; Variable temperature NMR

Indexed keywords

CHALCOGENIDES; ELECTROSTATICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; SULFUR COMPOUNDS;

1H NMR; 31P-NMR; 77SE NMR; ADDUCT FORMATION; DIRHODIUM COMPLEX; LIGAND EXCHANGES; OXIDE COMPOUNDS; PHOSPHINE CHALCOGENIDES; PHOSPHINE OXIDE; VARIABLE-TEMPERATURE NMR;

LIGANDS;

CHALCOGEN; OXYGEN; PHOSPHINE DERIVATIVE; PHOSPHORUS; RHODIUM DERIVATIVE; SELENIDE; 3 METHYLTHIOPROPYLAMINE; 3-METHYLTHIOPROPYLAMINE; LIGAND; PROPYLAMINE; RHODIUM;

ADDITION REACTION; ARTICLE; BINDING AFFINITY; CHEMICAL BOND; DEGRADATION KINETICS; ELECTRICITY; IONIC STRENGTH; LIGAND BINDING; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR MECHANICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STATISTICAL SIGNIFICANCE; STRUCTURE ANALYSIS; BINDING SITE; CHEMISTRY; METHODOLOGY; OXIDATION REDUCTION REACTION; TEMPERATURE;

BINDING SITES; CHALCOGENS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION-REDUCTION; PHOSPHINES; PROPYLAMINES; RHODIUM; TEMPERATURE;

EID: 8144223873     PISSN: 07491581     EISSN: None     Source Type: Journal    
DOI: 10.1002/mrc.1388     Document Type: Article

References (19)

1. (a) Boyar EB, Robinson SD. Coord. Chem. Rev. 1983; 50: 109;
2. (b) Cotton FA, Walton RA (2nd edn). Multiple Bonds between Metal Atoms Clarendon Press: Oxford, 1993.
3. (a) Mertis C, Kravaritoy M, Chorianopoulou M, Koinis S, Psaroudakis N. Top. Mol. Organis. Eng. 1994; 11: 321;
4. (b) Doyle MP, McKervey MA, Ye T. Modern Catalytic Methods for Organic Synthesis with Diazo Compounds: from Cyclopropanes to Ylides. Wiley: New York, 1998;
5. (c) Endres A, Maas G. Tetrahedron 2002; 58: 3999, and references cited therein.
6. Clarke MJ, Zhu F, Frasca DR. Chem. Rev. 1999; 99: 2511.
7. (a) Rockitt S, Duddeck H, Omelanczuk J. Chirality 2001; 13: 214;
8. (b) Malik S, Duddeck H, Omelanczuk J, Choudhary MI. Chirality 2002; 14: 407;
9. (c) Magiera D, Moeller S, Drzazga Z, Pakulski Z, Pietrusiewicz KM, Duddeck H. Chirality 2003; 15: 391.
10. Deubel DV. Organometallics 2002; 21: 4303.
11. Wypchlo K, Duddeck H. Tetrahedron: Asymmetry 1994; 5: 27.
12. Meyer C, Duddeck H. Magn. Reson. Chem. 2000; 38: 29.
13. (a) Jackman LM. Cotton FA (eds). Dynamic Nuclear Magnetic Resonance Spectroscopy. Academic Press: New York, 1975;
14. (b) Sandström J. Dynamic NMR Spectroscopy. Academic Press: London, 1982;
15. (c) Oki M. Applications of Dynamic NMR Spectroscopy to Organic Chemistry. Methods in Stereochemical Analysis, vol. 4. VCH: Deerfield Beach, FL, 1985.
16. (a) Duddeck H, Malik S, Gáti T, Tóth G, Choudhary MI. Magn. Reson. Chem. 2002; 40: 153;
17. (b) Rozwadowski Z, Malik S, Tóth G, Gáti T, Duddeck H. Dalton Trans. 2003; 375;
18. (c) Malik S, Moeller S, Tóth C, Gáti T, Choudhary MI, Duddeck H. Magn. Reson. Chem. 2003; 41: 455;
19. (d) Magiera D, Omelanczuk J, Dziuba KPietrusiewicz KM, Duddeck H. Organometallics 2003; 22: 2464.