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Volumn 2, Issue 11, 2011, Pages 2196-2198

Enantioselective carbon-sulfur bond formation: γ additions of aryl thiols to allenoates catalyzed by a chiral phosphepine

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL THIOLS; ARYL ALKYL SULFIDES; ASYMMETRIC ADDITION; CARBON SULFUR BONDS; CATALYTIC CYCLES; CHIRAL PHOSPHINE; ENANTIOSELECTIVE; ENANTIOSELECTIVE ADDITION; MECHANISTIC DATA; OPTIMIZED REACTION CONDITIONS;

EID: 81355139615     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c1sc00414j     Document Type: Article
Times cited : (62)

References (23)
  • 7
    • 0001563584 scopus 로고
    • For a process that produces a stereocenter in the δ position, see
    • B. M. Trost C.-J. Li J. Am. Chem. Soc. 1994 116 10819 10820
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10819-10820
    • Trost, B.M.1    Li, C.-J.2
  • 12
    • 78650575850 scopus 로고    scopus 로고
    • For a seminal investigation of the catalytic asymmetric synthesis of α-thio-substituted carbonyl compounds, see
    • R. Sinisi J. Sun G. C. Fu Proc. Natl. Acad. Sci. U. S. A. 2010 107 20652 20654
    • (2010) Proc. Natl. Acad. Sci. U. S. A. , vol.107 , pp. 20652-20654
    • Sinisi, R.1    Sun, J.2    Fu, G.C.3
  • 18
    • 78649326498 scopus 로고    scopus 로고
    • Royal Society of Chemistry, Cambridge, UK, Diltiazem, nelfinavir and zofenopril are examples of pharmaceuticals that include an aryl alkyl sulfide Allenoates can be synthesized in one step through the treatment of an acid chloride with a commercially available olefinating reagent such as (carbethoxymethylene)triphenylphosphorane
    • H. Pellissier in Chiral Sulfur Ligands: Asymmetric Catalysis, Royal Society of Chemistry, Cambridge, UK, 2009
    • (2009) Chiral Sulfur Ligands: Asymmetric Catalysis
    • Pellissier, H.1
  • 19
    • 81355164772 scopus 로고    scopus 로고
    • Phosphepines were originally developed as chiral ligands for transition metals. For a review, see:, in, ed. A. Börner, Wiley-VCH, New York, 177-206 For the first application of a phosphepine as a chiral nucleophilic catalyst, see
    • Phosphepines were originally developed as chiral ligands for transition metals. For a review, see: S. Gladiali and E. Alberico, in Phosphorus Ligands in Asymmetric Catalysis, vol. 1, ed., A. Börner, Wiley-VCH, New York, 2008, pp. 177-206
    • (2008) Phosphorus Ligands in Asymmetric Catalysis , vol.1
    • Gladiali, S.1    Alberico, E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.