Fabrication and properties of carbon fibers

Materials

Volumn 2, Issue 4, 2009, Pages 2369-2403

  Huang, Xiaosong ^a  

^a GENERAL MOTORS CORPORATION   (United States)

Author keywords

Carbon fiber; Composite; High modulus; High strength; Light weighting

Indexed keywords

DIFFERENT PRECURSORS; HIGH MODULUS; HIGH STRENGTH; LIGHTWEIGHTING; POLYACRYLONITRILE (PAN); PRECURSOR MATERIALS; PROCESSING CONDITION; RESEARCH AND DEVELOPMENT;

COMPOSITE MATERIALS; OPTIMIZATION; RESEARCH;

CARBON FIBERS;

EID: 81255124519     PISSN: None     EISSN: 19961944     Source Type: Journal    
DOI: 10.3390/ma2042369     Document Type: Review

References (158)

1. Fitzer, E.; Edie, D.D.; Johnson, D.J. Carbon fibers-present state and future expectation; Pitch and mesophase fibers; Structure and properties of carbon fibers. In Carbon Fibers Filaments and Composites, 1st ed.; Figueiredo, J.L., Bernardo, C.A., Baker, R.T.K., Huttinger, K.J., Eds.; Springer: New York, NY, USA, 1989; pp. 3-41, 43-72, 119-146.
2. Roberts, T. The Carbon Fiber Industry: Global Strategic Market Evaluation 2006-2010; Materials Technology Publications: Watford, UK, 2006; pp. 10, 93-177, 237.
3. Red, C. Aerospace will continue to lead advanced composites market in 2006. Composites Manuf. 2006, 7, 24-33.
4. Committee on High Performance Synthetic Fibers for Composites, Commission on Engineering and Technical Systems, National Research Council. High-Performance Synthetic Fibers for Composites; National Academy Press: Washington, DC, USA, 1992; pp. 23, 56-64, 86.
5. Chung, D.L. Carbon Fiber Composites; Butterworth-Heinemann: Boston, MA, USA, 1994; pp. 3-65.
6. Donnet, J.B.; Bansal, R.C. Carbon Fibers, 2nd ed.; Marcel Dekker: New York, NY, USA, 1990; pp. 1-145.
7. Friedlander, H.N.; Peebles, L.H.Jr.; Brandrup, J.; Kirby, J.R. On the chromophore of polyacrylonitrile. VI. Mechanism of color formation in polyacrylonitrile. Macromolecules 1968, 1, 79-86.
8. Morley, J.G. High-Performance Fiber Composites; Academic Press: Orlando, FL, USA, 1987; pp. 46-78.
9. Johnson, W.; Watt, W. Structure of high modulus carbon fibres. Nature 1967, 215, 384-386.
10. Wicks, B.J. Microstructural disorder and the mechanical properties of carbon fibers. J. Nucl. Mater. 1975, 56, 287-296.
11. Watt, W.; Johnson, W. The effect of length changes during oxidation of polyacrylonitrile fibers on the Young's modulus of carbon fibers. Appl. Polym. Symp. 1969, 9, 215-227.
12. Fourdeux, A.; Perret, R.; Ruland, W. General structural features of carbon fibers. In Proceedings of the First International Conference on Carbon Fibers, Plastics Institute: London, UK, February 1971; pp. 57-62.
13. Perret, R.; Ruland, W. The microstructure of PAN-base carbon fibres. J. Appl. Crystallogr. 1970, 3, 525-532.
14. Diefendorf, R.J.; Tokarsky, E. High-performance carbon fibers. Polym. Eng. Sci. 1975, 15, 150-159.
15. Edie, D.D. The effect of processing on the structure and properties of carbon fibers. Carbon 1998, 36, 345-362.
16. Guigon, M.; Oberlin, A. Preliminary studies of mesophase-pitch-based carbon fibers: Structure and microtexture. Compos. Sci. Technol. 1986, 25, 231-241.
17. Fitz Gerald, J.D.; Pennock, G.M.; Taylor, G.H. Domain structure in MP (mesophase pitch)-based fibres. Carbon 1991, 29, 139-164.
18. Huang, Y.; Young, R. J. Effect of fiber microstructure upon the modulus of PAN- and pitch-based carbon fibers. Carbon 1995, 33, 97-107.
19. Kobets, L.P.; Deev, I.S. Carbon fibres: Structure and mechanical properties. Compos. Sci. Technol. 1997, 57, 1571-1580.
20. Konkin, A.A.; Watt, W. Properties of carbon fibers and fields of their application. Production of cellulose based carbon fibrous materials. Chemistry and physics of the conversion of polyacrylonitrile fibers into high modulus carbon fibers. In Strong Fibers; Watt, W., Perov, B.V., Eds.; Elsevier Science Publishers: Amsterdam, The Netherlands, 1985; pp. 241-273, 275-325, 327-387.
21. Wolff, E.G. Stiffness-thermal expansion relationships in high modulus carbon fibers. J. Compos. Mater. 1987, 21, 81-97.
22. Lafdi, K.; Wright, M.A. Carbon fibers. In Handbook of Composites, 2nd ed.; Peters, S.T., Ed.; Chapman & Hall: London, UK, 1998; p. 169.
23. Reynolds, W.N.; Sharp, J.V. Crystal shear limit to carbon fiber strength. Carbon 1974, 12, 103-110.
24. Johnson, J.W.; Thorne, D.J. Effect of internal polymer flaws on strength of carbon fibres prepared from an acrylic precursor. Carbon 1969, 7, 659-660.
25. Thorne, D.J. Coating of carbon fiber with carbon. DE 2128526, 1972.
26. Endo, M. Structure of mesophase pitch-based carbon fibres. J. Mater. Sci. 1988, 23, 598-605.
27. Dobb, M.G.; Johnson, D.J.; Park, C.R. Compressional behavior of carbon-fibers. J. Mater. Sci. 1990, 25, 829-834.
28. Hahn, H.T.; Sohi, M.M. Buckling of a fiber bundle embedded in epoxy. Compos. Sci. Technol. 1986, 27, 25-41.
29. Morgon, P. Carbon Fibers and Their Composites; CRC Press: Boca Raton, FL, USA, 2005; pp. 130-162.
30. Peebles, L.H. Carbon Fibers: Structure and Formation; CRC Press: New York, NY, USA, 1995; pp. 12-168.
31. Henrici-Olive, G.; Olive, S. The chemistry of carbon fiber formation from polyacrylonitrile. Adv. Polym. Sci. 1983, 51, 1-60.
32. Masahiro, T.; Takeji, O.; Takashi, F. Preparation of acrylonitrile precursor for carbon fiber. JP 59204914, 1984.
33. Knudsen, J.P. The influence of coagulation variables on the structure and physical properties of an acrylic fiber. Text. Res. J. 1963, 33, 13-20.
34. Daumit, G.P.; Ko, Y.S.; Slater, C.R.; Venner, J.G.; Young, C.C. Formation of melt-spun acrylic fibers possessing a highly uniform internal structure which are particularly suited for thermal conversion to quality carbon fibers. US patent 4935180, 1990.
35. Daumit, G.P.; Ko, Y.S.; Slater, C.R.; Venner, J.G.; Young, C.C.; Zwick, M.M. Formation of melt-spun acrylic fibers which are well suited for thermal conversion to high strength carbon fibers. US patent 4933128, 1990.
36. Daumit, G.P.; Ko, Y.S.; Slater, C.R.; Venner, J.G.; Young, C.C. Formation of melt-spun acrylic fibers which are particularly suited for thermal conversion to high strength carbon fibers. US patent 4921656, 1990.
37. Grove, D.; Desai, P.; Abhiraman, A.S. Exploratory experiments in the conversion of plasticized melt spun PAN-based precursors to carbon fibers. Carbon 1988, 26, 403-411.
38. Mukundan, T.; Bhanu, V.A.; Wiles, K.B.; Johnson, H.; Bortner, M.; Baird, D.G.; Naskar, A.K.; Ogale, A.A.; Edie, D.D.; McGrath, J.E. A photocrosslinkable melt processible acrylonitrile terpolymer as carbon fiber precursor. Polymer 2006, 47, 4163-4171.
39. Rangarajan, P.; Bhanu, V.A.; Godshall, D.; Wilkes, G.L.; McGrath, J.E.; Baird, D.G. Dynamic oscillatory shear properties of potentially melt processible high acrylonitrile terpolymers. Polymer 2002, 43, 2699-2709
40. Paiva, M.C.; Kotasthane, P.; Edie, D.D.; Ogale, A.A. UV stabilization route for melt-processible PAN-based carbon fibers. Carbon 2003, 41, 1399-1409.
41. Imai, K.; Sumoto, M.; Nakamura, H.; Miyahara, N. Process for preparing carbon fibers of high strength. US patent 4902762, 1990.
42. Ohsaki, T.; Imai, K.; Miyahara, N. Process for preparing a carbon fiber of high strength. US Pat. 4925604, 1990.
43. Hirotaka, S.; Hiroaki, K. Manufacturing process of isotactic copolymer for carbon fiber precursor. JP2006016482, 2006.
44. Kuwahara, H.; Suzuki, H.; Matsumura, S. Polymer for carbon fiber precursor. US Pat. 7338997, 2008.
45. Hunter, W.L. Liability of the α-hydrogen in PAN. J. Polym. Sci. B. 1967, 5, 23-26.
46. Warren, C.D.; Paulauskas, F.L.; Baker, F.S.; Eberle, C.C.; Naskar, A. Multi-task research program to develop commodity grade, lower cost carbon fiber. In Proceedings of the SAMPE Fall Technical Conference, Memphis, TN, USA, September 2008.
47. Dasarathy, H.; Schimpf, W.C.; Burleson, T.; Smith, S.B.; Herren, C.W.; Frame, A.C.; Heatherly, P.W. Low cost carbon fiber from chemically modified acrylics. In Proceedings of the International SAMPE Technical Conference, Baltimore, MD, USA, May 2002.
48. Bajaj, P.; Paliwal, D.K.; Gupta, A.K. Influence of metal ions on structure and properties of acrylic fibers. J. Appl. Polym. Sci. 1998, 67, 1647-1659.
49. Shiromoto, K.; Adachi, Y.; Nabae, K. Process for producing carbon fiber. US Pat. 4944932, 1990.
50. Masaki, T.; Komatsubara, T.; Tanaka, Y.; Nakanishi, S.; Nakagawa, M.; Kanamori, J. Finish for carbon fiber precursors. US Pat. 5783305, 1998.
51. Houtz, R.C. Orlan acrylic fibre: Chemistry and properties. J. Text. Res. 1950, 20, 786-801.
52. Schurz, J. Discoloration effects in acrylonitrile polymers. J. Polym. Sci. 1958, 28, 438-439.
53. Standage, A.; Matkowshi, R. Thermal oxidation of polyacrylonitrile. Eur. Polym. J. 1971, 7, 775-783.
54. Goodhew, P.J.; Clarke, A.J.; Bailey, J.E. A review of the fabrication and properties of carbon fibres. Mater. Sci. Eng. 1975, 17, 3-30.
55. Clarke, A.J.; Bailey, J.E. Oxidation of acrylic fibres for carbon fibre formation. Nature 1973, 243, 146-150.
56. Bailey, J.E.; Clarke, A.J. Carbon fibres. Chem. Br. 1970, 6, 484-489.
57. Goodhew, P.J.; Clarke, A.J.; Bailey, J.E. Review of fabrication and properties of carbon-fibers. Mater. Sci. Eng. 1975, 17, 3-30.
58. Henrici-Olive, G.; Olive, S. Molecular interactions and macroscopic properties of polyacrylnitrile and model substances. Adv. Polym. Sci. 1979, 32, 123-152.
59. Ganster, J.; Fink, H.P.; Zenke, I. Chain conformation of polyacrylonitrile: A comparison of model scattering and radial distribution functions with experimental wide-angle X-ray scattering results. Polymer 1991, 32, 1566-1573.
60. Gupta, A.; Harrison, I.R. New aspects in the oxidative stabilization of PAN-based carbon fibers. Carbon 1996, 34, 1427-1445.
61. Fitzer, E.; Muller, D.J. The influence of oxygen on the chemical reactions during stabilization of PAN as carbon fiber precursor. Carbon 1975, 13, 63-69.
62. Fitzer, E.; Frohs, W.; Heine, M. Optimization of stabilization and carbonization treatment of PAN fibres and structural characterization of the resulting carbon fibres. Carbon 1986, 24, 387-395.
63. Yoshinori, N.; Takamaro, K.; Keitarou, F.; Takamaro, K.; Keitaro, F. Process for producing carbon fibers. GB 1500675, 1978.
64. Hamada, M.; Hosako, Y.; Yamada, T.; Shimizu, T. Acrylonitrile-based precursor fiber for the formation of carbon fiber, process for preparing same, and carbon formed from same. US Pat. 6326451, 2001.
65. Potter, W.D.; Scott, G. Initiation of low-temperature degradation of polyacrylonitrile. Nat.-Phys. Sci. 1972, 236, 32.
66. Raskovic, V.; Marinkovic, S. Temperature dependence of processes during oxidation of PAN fibres. Carbon 1975, 13, 535-538.
67. Raskovic, V.; Marinkovic, S. Processes in sulfur dioxide treatment of PAN fibers. Carbon 1978, 16, 351-357.
68. Deurberque, A.; Oberlin, A. Stabilization and carbonization of PAN-based carbon fibers as related to mechanical properties. Carbon 1991, 29, 621-628.
69. Turner, W.N.; Johnson, F.C. Method of manufacturing carbon articles. US Pat. 3767773, 1973.
70. Gump, K.H.; Stuetz, D.E. Stabilization of acrylic fibers and films. US Pat. 4004053, 1977.
71. Kishimoto, S.; Okazaki, S. Process for producing carbon fibers. US Pat. 4009248, 1977.
72. Kishimoto, S.; Okazaki, S. Process for producing carbon fibers having excellent properties. US Pat. 4024227, 1977.
73. Riggs, J.P. Thermally stabilized acrylic fibers produced by sulfation and heating in an oxygencontaining atmosphere. US Pat. 3650668, 1972.
74. Riggs, J.P. Acrylic fiber stabilization catalyzed by Co(II) and Ce(III) cations. US Pat. 3656882, 1972.
75. Riggs, J.P. Process for the stabilization of acrylic fibers. US Pat. 3656883, 1972.
76. Ko, T.H.; Yieting, H.; Lin, C.H. Thermal stabilization of polyacrylonitrile fibers. J. Appl. Polym. Sci. 1988, 35, 631-640.
77. Shiedlin, A.; Marom, G.; Zillkha, A. Catalytic initiation of polyacrylonitrile stabilization. Polymer 1985, 26, 447-451.
78. Mccabe, M.V. Pretreatment of PAN fiber. US Pat. 4661336, 1987.
79. Mladenov, I.; Lyubekeva, M. Polyacrylonitrile fibers treated by hydrazine hydrate as a basis for the production of carbon fibers. J. Polym. Sci. A1 1983, 21, 1223-1226.
80. White, S.M.; Spruiell, J.E.; Paulauskas, F.L. Fundamental studies of stabilization of polyacrylonitrile precursor, Part 1: Effects of thermal and environmental treatments. In Proceedings of the International SAMPE Technical Conference, Long Beach, CA, USA, May 2006.
81. Allen, S.; Cooper, G.A.; Johnson, D.J.; Mayer, R.M. Carbon fibres of high modulus. In Proceeding of the 3rd Conference on Industrial Carbons and Graphite, Society of Chemical Industry, London, UK, April 1970.
82. Paulauskas, F.L.; White, T.L.; Spruiell, J.E. Structure and properties of carbon fibers produced using microwave-assisted plasma technology, Part 2. In Proceedings of the International SAMPE Technical Conference, Long Beach, CA, USA, May 2006.
83. Sung, M.G.; Sassa, K.; Tagawa, T.; Miyata, T.; Ogawa, H.; Doyama, M.; Yamada, S.; Asai, S. Application of a high magnetic field in the carbonizatino process to increase the strength of carbon fibers. Carbon 2002, 40, 2013-2020.
84. Smith, F.A.; Eckle, T.F.; Osterholm, R.J.; Stichel, R.M. Manufacture of coal tar and pitches. In Bituminous Materials; Hoiberg, A.J., Ed.; InterScience Publishers: New York, NY, USA, 1966; Vol. 3, p. 57.
85. Barr, J.B.; Chwastiak, S.; Didchenko, R.; Lewis, I.C.; Lewis, R.T.; Singer, L.S. High modulus carbon fibers from pitch precursors. Appl. Polym. Symp. 1976, 29, 161-173.
86. Otani, S. On the carbon fiber from the molten pyrolysis products. Carbon 1965, 3, 31-38.
87. Otani, S.; Yamada, K.; Koitabashi, T.; Yokoyama, A. On the raw materials of MP carbon fiber. Carbon 1966, 4, 425-432.
88. Singer, L.S. High modulus, high strength carbon fibers produced from mesophase pitch. US Pat. 4005183, 1977.
89. Lewis, I.C. Process for producing carbon fibers from mesophase pitch. US Pat. 4032430, 1977.
90. Chwastiak, S.; Lewis, I.C. Solubility of mesophase pitch. Carbon 1978, 16, 156-157.
91. Fu, T.W.; Katz, M. Process for making mesophase pitch. US Pat. 4999099, 1991.
92. Peter, S.; Beneke, H.; Oeste, F.; Fexer, W.; Jaumann, W.; Meinbreckse, M.; Kempfert, J. A method for the production of a carbon fiber precursor. US Pat. 4756818, 1988.
93. Bolanos, G.; Liu, G.Z.; Hochgeschurtz, T.; Thies, M.C. Producing a carbon fiber precursor by supercritical fluid extraction. Fluid Phase Equilibria 1993, 82, 303-310.
94. Diefendorf, R.J.; Riggs, D.M. Forming optically anisotropic pitches. US Pat. 4208267, 1980.
95. Angier, D.J.; Barnum, H.W. Neomesophase formation. US Pat. 4184942, 1980.
96. Yamada, Y.; Honda H.; Inoue, T., Preparation of carbon fiber. JP 58018421, 1983.
97. Otani, S. Dormant mesophase pitch. JP 57100186, 1982.
98. Kalback, W.; Romine, E.; Bourrat, X. Solvated mesophase pitches. US Pat. 5259947, 1993.
99. Romine, E.; Rodgers, J.; Southard, M.; Nanni, E. Solvating component and solvent system for mesophase pitch. US Pat. 6717021, 2004.
100. Yamada, Y.; Imamura, T.; Shibata, M.; Arita, S.; Honda, H. Method for the preparation of pitches for spinning carbon fibers. US Pat. 4606808, 1986.
101. Seo, I.; Sakaguchi, Y.; Kashiwadate, K. Process for producing carbon fibers and the carbon fibers produced by the process. US Pat. 4863708, 1989.
102. Seo, I.; Oono, T.; Murakami, Y. Catalytic process for producing raw material pitch for carbon materials from naphthalene. US Pat. 5066779, 1991.
103. Mochida, I.; Shimizu, K.; Korai, Y.; Otsuka, H.; Sakai, Y.; Fujiyama, S. Preparation of mesophase pitch from aromatic-hydrocarbons by the aid of HF/BF3. Carbon 1990, 28, 311-319.
104. Korai, Y.; Nakamura, M.; Mochida, I.; Sakai, Y.; Fujiyama, S. Mesophase pitches prepared from methylnaphthalene by the aid of HF/BF3. Carbon 1991, 29, 561-567.
105. Watanabe, F.; Ishida, S.; Korai, Y.; Mochida, I.; Kato, I.; Sakai, Y.; Kamatsu, M. Pitch-based carbon fiber of high compressive strength prepared from synthetic isotropic pitch containing mesophase spheres. Carbon 1999, 37, 961-967.
106. Kofui, Y.; Ishida, S.; Watanabe, F.; Yoon, S.H.; Wang, Y.G.; Mochida, I.; Kato, I.; Nakamura, T.; Sakai, Y.; Komatsu, M. Preparation of carbon fiber from isotropic pitch containing mesophase spheres. Carbon 1997, 35, 1733-1737.
107. Kohn, E.M. Use of hot buoyant liquid to convert pitch to continuous carbon filament. US Pat. 3972968, 1976.
108. Vakili, A.; Yue, Z.R.; Fei, Y.; Cochran, H.; Allen, L.; Duran, M. Pitch based carbon fiber processing and composites. In Proceedings of the International SAMPE Technical Conference, Cincinnati, OH, USA, October 2007.
109. Yue, Z.R.; Matthew, D.P.; Vakili, A. Fabrication of low-cost composites using roving-like mesophase pitch-based carbon fibers, In Proceedings of the 17th International Conference on Composites/Nanocomposites Engineering, Honolulu, HI, USA, July 2009.
110. Sawaki, T.; Sasaki, H.; Nakamura, T.; Sadanobu, J. Process for preparation of high-performance grade carbon fibers. US Pat. 4840762, 1989.
111. Sasaki, H.; Sawaki, T. Method of manufacturing of pitch-base carbon fiber. US Pat. 4948574, 1990.
112. Miyajima, N.; Akatsu, T.; Ikoma, T.; Ito, O.; Rand, B.; Tanabe, Y.; Yasuda, E. A role of chargetransfer complex with iodine in the modification of coal tar pitch. Carbon 2000, 38, 1831-1838.
113. Bright, A.A.; Singer, L.S. Electronic and structural characteristic of carbon-fibers from mesophase pitch. Carbon 1979, 17, 59-69.
114. McHenry, E.R. Process for producing mesophase pitch. US Pat. 4026788, 1977.
115. Guigon, M.; Oberlin, A.; Desarmot, G. Microtexture and structure of some high-modulus PAN-based carbon fibres. Fibre Sci. Technol. 1984, 20, 177-198.
116. Guigon, M.; Oberlin, A.; Desarmot, G. Microtexture and structure of some high tensile strength, PAN-base carbon fibers. Fibre Sci. Technol. 1984, 20, 55-72.
117. Singer, L.S. The mesophase and high modulus carbon fibers from pitch. Carbon 1978, 16, 409-415.
118. Riggs, D.M. Process of spinning pitch-based carbon fibers. US Pat. 4504454, 1985.
119. Otani, S.; Oya, A. Status report on pitch-based carbon fiber in Japan. In Composites '86: Recent Advances in Japan and the United States, Japan Society for Composite Materials; Kawata, K., Umekawa, S., Kobayashi, A. Eds.; Japan Society for Composite Materials: Tokyo, Japan, 1986; pp. 1-10.
120. Peebles, L.H. Carbon Fibers: Formation, Structure, and Properties, 1st ed.; CRS Press: Boca Raton, FL, USA, 1994; p. 3.
121. Tang, M.M.; Bacon, R. Carbonization of cellulose fibers-I. Low temperature pyrolysis. Carbon 1964, 2, 211-214.
122. Bacon, R. Carbon fibers from rayon precursors; In Chemistry and Physics of Carbon; Walker P.L. Jr., Thrower, P.A., Eds.; Marcel Dekker: New York, NY, USA, 1974; Vol. 9, p. 1.
123. Tang, W.K.; Neill, M.K. Effect of flame retardants on pyrolysis and combustion of -cellulose. J. Polym. Sci. C 1964, 6, 65-81.
124. Shindo, A.; Nakanishi, Y.; Sema, I. Carbon fibers from cellulose fibers. Appl. Polym. Symp. 1969, 9, 271-284.
125. Woerner, H.J.; Lukacs, D.J.; Hoffmann, K. Production of Flexible Carbon Fibres. GB 1194176, 1970.
126. Otani, S.; Fukuoka, Y.; Igarashi, B.; Sasaki, K. Method for producing carbonized lignin fiber. US Pat. 3461082, 1969.
127. Sudo, K.; Shimizu, K. A new carbon-fiber from lignin. J. Appl. Polym. Sci. 1992, 44, 127-134.
128. Sudo, K.; Shimizu, K.; Nakashima, N.; Yokoyama, A. A new modification method of exploded lignin for the preparation of a carbon fiber precursor. J. Appl. Polym. Sci. 1993, 48, 1485-1491.
129. Uraki, Y.; Kubo, S.; Nigo, N.; Sano, Y.; Sasaya, T. Preparation of carbon-fibers from Organosolv lignin obtained by aqueous acetic-acid pulping. Holzforschung 1995, 49, 343-350.
130. Kubo, S.; Uraki, Y.; Sano, Y. Preparation of carbon fibers from softwood lignin by atmospheric acetic acid pulping. Carbon 1998, 36, 1119-1124.
131. Kadla, J.F.; Kubo, S.; Venditti, R.A.; Gilbert, R.D.; Compere, A.L.; Griffith, W. Lignin-based carbon fibers for composite fiber application. Carbon 2002, 40, 2913-2920.
132. Kubo, S.; Kadla, J.F. Lignin-based carbon fibers: Effect of synthetic polymer blending on fiber properties. J. Polym. Environ. 2005, 13, 97-105.
133. Braun, J.L.; Holtman, K.M.; Kadla, J.F. Lignin-based carbon fibers: Oxidative thermostabilization of kraft lignin. Carbon 2005, 43, 385-394.
134. Gellerstedt, G.; Pettersson, B. Autooxidation of lignin. Svensk Papperstidn. 1980, 83, 314-318.
135. Fenner, R.A.; Lephardt, J.O. Examination of the thermal-decomposition of kraft pine lignin by Fourier-transform infrared evolved gas-analysis. J. Agric. Food Chem. 1981, 29, 846-849.
136. Schmidt, J.A.; Rye, C.S.; Gurnagul, N. Lignin inhibits autoxidative degradation of cellulose. Polym. Degrad. Stab. 1995, 49, 291-297.
137. Majibur, M.; Khan, R.; Gotoh, Y.; Morikawa, H.; Miura, M.; Fujimori, Y.; Nagura, M. Carbon fiber from natural biopolymer: Bombyxmori silk fibroin with iodine treatment. Carbon 2007, 45, 1035-1042.
138. Bengisu, M.; Yilmaz, E. Oxidation and pyrolysis of chitosan as a route for carbon fiber derivation. Carbohydr. Polym. 2002, 50, 165-175.
139. Prauchner, M.J.; Pasa, V.M.D.; Otani, S.; Otani, C. Biopitch-based general purpose carbon fibers: Processing and properties. Carbon 2005, 43, 591-597.
140. Sliva, D.E.; Selley, W. Continuous method for making spinnable polyacetylene solutions convertible to high strength carbon fiber. US Pat. 3928516, 1975.
141. Krutchen, C.M. Melt extrudable polyacetylene copolymer blends. US Pat. 3852235, 1974.
142. Mavinkurve, A.; Visser, S.; Pennings, A.J. An initial evaluation of poly(vinylacetylene) as a carbon-fiber precursor. Carbon 1995, 33, 757-761.
143. Horikiri, S.; Iseki, J.; Minobe, M. Process for production of carbon fiber. US Pat. 4070446, 1978.
144. Ashitaka, H.; Ishikawa, H.; Ueno, H.; Nagasaka, A. Syndiotactic 1,2-polybutadiene with CO-CS2 catalyst system 1. Preparation, properties, and application of highly crystalline syndiotactic 1,2-polybutadiene. J. Polym. Sci. A1 1983, 21, 1853-1860.
145. Ashitaka, H.; Kusuki, Y.; Yakamoto, S.; Onata, Y.; Nagasaki, A. Preparation of carbon-fibers from syndiotactic 1,2-polybutadiene. J. Appl. Polym. Sci. 1984, 29, 2763-2776.
146. Nagasaka, A.; Ashitaka, H.; Kusuki, Y.; Oda, D.; Yoshinaga, T. Process for producing carbon fiber. US Pat. 4131644, 1978.
147. Newell, J.A.; Edie, D.D. Factors limiting the tensile strength of PBO-based carbon fibers. Carbon 1996, 34, 551-560.
148. Kawamura, K.; Jenkins, G.M. Mechanical properties of glassy carbon fibers derived from phenolic resin. J. Mater. Sci. 1972, 7, 1099-1112.
149. Jenkins, G.M.; Kawamura, K. Phenolic resin fibres. GB 1228910, 1971.
150. Yokota, H.; Kobayashi, A.; Horikawa, J.; Miyashita, A. Process for producing carbon products. GB 1406378, 1975.
151. Santangelo, J.G. Graphitization of fibrous polyamide resinous materials. US Pat. 3547584, 1970.
152. Economy, J.; Lin, R.Y. Adsorption characteristics of activated carbon fibers. Appl. Polym. Symp. 1976, 29, 199-211.
153. Jiang, H.; Desai, P.; Kumar, S.; Abhiraman, A.S. Carbon-fibers from poly(para-phenylene benzobisthiazole) (PBZT) fibers-conversion and morphological aspects. Carbon 1991, 29, 635-644.
154. Murakami, M. Process for producing graphite. US Pat. 4876077, 1989.
155. Ezekiel, H.M.; Spain, R.G. Preparation of graphite fibers from polymeric fibers. J. Polym. Sci. C 1967, 19, 249-265.
156. Shindo, A.; Fujii, R.; Souma, I. Producing method of carbon or carbonaceous material. US Pat. 3427120, 1969.
157. Boncher, E.A.; Cooper, R.N.; Everett, D.H. Preparation and structure of Saran-carbon fibers. Carbon 1970, 8, 597-605.
158. Soehngen, J.W.; Willians, A.G. Carbon fiber production. US Pat. 4020145, 1977.