Kinetics of the reaction of the heaviest hydrogen atom with H2, the 4Heμ + H2 → 4HeμH + H reaction: Experiments, accurate quantal calculations, and variational transition state theory, including kinetic isotope effects for a factor of 36.1 in isotopic mass

Journal of Chemical Physics

Volumn 135, Issue 18, 2011, Pages

  Fleming, Donald G ^a   Arseneau, Donald J ^a   Sukhorukov, Oleksandr ^a,g   Brewer, Jess H ^b   Mielke, Steven L ^c   Truhlar, Donald G ^c   Schatz, George C ^d   Garrett, Bruce C ^e   Peterson, Kirk A ^f  

^a TRIUMF   (Canada)

^b UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^c University of Minnesota   (United States)

^d NORTHWESTERN UNIVERSITY   (United States)

^e PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^f WASHINGTON STATE UNIVERSITY   (United States)

^g UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BORN-OPPENHEIMER DIAGONAL CORRECTIONS; CONFIGURATION-INTERACTION CALCULATIONS; EXPERIMENTAL UNCERTAINTY; EXPERIMENTAL VALUES; HELIUM ATOM; HIGH PRESSURE; HYDROGEN ATOMS; HYPERFINE COUPLING CONSTANTS; ISOTOPIC MASS; KINETIC ISOTOPE EFFECTS; MOLECULAR HYDROGEN; MUON SPIN ROTATION; NEGATIVE MUONS; QUANTUM CALCULATION; QUANTUM MECHANICAL DYNAMICS CALCULATIONS; TEMPERATURE RANGE; VARIATIONAL TRANSITION STATE THEORY;

ATOMS; CARRIER MOBILITY; CHARGED PARTICLES; ELECTRONIC STATES; EXPERIMENTS; HELIUM; HYDROGEN; ISOTOPES; KINETICS; QUANTUM CHEMISTRY; QUANTUM THEORY; REACTION KINETICS; TRANSITION FLOW; UNCERTAINTY ANALYSIS;

RATE CONSTANTS;

EID: 81155138813     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3657440     Document Type: Article

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