Solubility and thermodynamic properties of carbonate-bearing hydrotalcite-pyroaurite solid solutions with a 3:1 Mg/(Al+Fe) mole ratio

Clays and Clay Minerals

Volumn 59, Issue 3, 2011, Pages 215-232

  Rozov, K B ^a,b   Berner, U ^a   Kulik, D A ^a   Diamond, L W ^b  

^a PAUL SCHERRER INSTITUTE   (Switzerland)

^b UNIVERSITY OF BERN   (Switzerland)

Author keywords

Aqueous solubility; Hydrotalcite; LDH; Molar volume; Pyroaurite; Solid solutions; Thermodynamic modeling

Indexed keywords

AQUEOUS SOLUBILITY; HYDROTALCITES; LDH; PYROAURITE; THERMODYNAMIC MODELING;

ALUMINUM; ANALYTICAL GEOCHEMISTRY; DENSITY (SPECIFIC GRAVITY); EMISSION SPECTROSCOPY; EXPERIMENTS; INDUCTIVELY COUPLED PLASMA; OPTICAL EMISSION SPECTROSCOPY; SCINTILLATION COUNTERS; SOLUBILITY; STANDARDS; TERNARY SYSTEMS; THERMODYNAMIC PROPERTIES; THERMOGRAVIMETRIC ANALYSIS; VOLUME MEASUREMENT; X RAY DIFFRACTION;

SOLID SOLUTIONS;

CATION; CHEMICAL COMPOSITION; CLAY MINERAL; DISSOLUTION; EXPERIMENTAL STUDY; GIBBS FREE ENERGY; HYDROTALCITE; HYDROXIDE; PRECIPITATION (CHEMISTRY); SOLID SOLUTION; SOLUBILITY; THERMODYNAMIC PROPERTY;

INSECTIVORA;

EID: 81055133560     PISSN: 00098604     EISSN: 15528367     Source Type: Journal    
DOI: 10.1346/CCMN.2011.0590301     Document Type: Article

References (32)

1. Allada, R.K., Navrotsky, A., and Boerio-Goates, J. (2005) Thermochemistry of hydrotalcite-like phases in the MgOAl2O3- CoO2-H2O system: A determination of enthalpy, entropy and free energy. American Mineralogist, 90, 329-335.
2. Allmann, R. (1968) Crystal structure of pyroaurite. Acta Crystallographica. Section B. Structural Crystallography and Crystal Chemistry, B 24, 972.
3. Bish, D.L. and Howard, S.A. (1988) Quantitative phaseanalysis using the Rietveld method. Journal of Applied Crystallography, 21, 86-91.
4. Brindley, G.W. and Kikkawa, S. (1979) A crystal-chemical study of Mg, Al and Ni, Al hydroxy-perchlorates and hydroxy-carbonates. American Mineralogists, 64, 836-843.
5. Brindley, G.W. and Kikkawa, S. (1980) Thermal-behavior of hydrotalcite and of anion-exchanged forms of hydrotalcite. Clays and Clay Minerals, 28, 87-91.
6. Carrado, K.A., Kostapapas, A., and Suib, S.L. (1988) Layered double hydroxides (LDHs). Solid State Ionics, 26, 77-86.
7. Cavani, F., Trifiro, F., and Vaccari, A. (1991) Hydrotalcitetype anionic clays: Preparation, properties and applications. Catalysis Today, 11, 173-301.
8. Chibwe, K. and Jones, W. (1989) Intercalation of organic and inorganic anions into layered double hydroxides. Journal of the Chemical Society - Chemical Communications, 926-927.
9. Chisem, I.C. and Jones, W. (1994) Ion-exchange properties of lithium aluminum layered double hydroxides. Journal of Materials Chemistry, 4, 1737-1744.
10. Danton, A.R. (1991) Vegard's law. Physical Review, 43, 3161-3164.
11. De Roy, A., Forano, C., El Malki, M., and Besse, J.-P. (1992) Anionic clays: Trends in Pillaring Chemistry. Van Nostrand Reinhold, New York.
12. Drits, V.A. and Bookin, A.S. (2001) Crystal structure and X-ray identification of layered double hydroxides. Pp. 41-100 in: Layered Double Hydroxides. Present and Future (V. Rives, editor). Nova Science Publishers, New York.
13. Drits, V.A., Sokolova, T.N., Sokolova, G.V., and Cherkashin, V.I. (1987) New members of the hydrotalcite-manasseite group. Clays and Clay Minerals, 35, 401-417.
14. Frost, R.L. and Reddy, B.J. (2006) Thermo-Raman spectroscopic study of the natural layered double hydroxide manasseite. Spectrochimica Acta. Part A. Molecular and Biomolecular Spectroscopy, 65, 553-559.
15. Gutmann, N. and Mü ller, B. (1996) Insertion of the dinuclear dihydroxo-bridged Cr(IV) aquo complex into the layered double hydroxides of hydrotalcite-type. Journal of Solid State Chemistry, 122, 214-220.
16. Helgeson, H.C., Delany, J.M., Nesbitt, H.W., and Bird, D.K. (1978) Summary and critique of the thermodynamic properties of rock-forming minerals. American Journal of Science, 278A, 1-229.
17. Hummel, W. (2002) Nagra/PSI Chemical Thermodynamic Database 01/01. Universal-Publishers, Parkland, Florida, USA, 589 pp.
18. Johnson, C.A. and Glasser, F.P. (2003) Hydrotalcite-like minerals (M2Al(OH)6(CO3)0.5·nH2O, where M = Mg, Zn, Co, Ni) in the environment: Synthesis, characterization and thermodynamic stability. Clays and Clay Minerals, 51, 1-8.
19. Khan, A.I. and O'Hare, D. (2002) Intercalation chemistry of layered double hydroxides: Recent developments and applications. Journal of Materials Chemistry, 12, 3191-3198.
20. Kovanda, F., Koulousek, D., Cilova, Z., and Hulinski, V. (2005) Crystallization of synthetic hydrotalcite under hydrothermal conditions. Applied Clay Science, 28, 101-109.
21. Lippmann, F. (1980) Phase diagrams depicting aqueous solubility of binary mineral systems. Neues Jahrbuch für Mineralogie Abhandlungen, 139, 1-25.
22. Majzlan, J., Grevel, K.D., and Navrotsky, A. (2003a) Thermodynamics of Fe oxides: Part II. Enthalpies of formation and relative stability of goethite (α-FeOOH), lepidocrocite (γ-FeOOH), and maghemite (γ-Fe2O3). American Mineralogist, 88, 855-859.
23. Majzlan, J., Lang, B.E., Stevens, R., Navrotsky, A., Woodfield, B.F., and Boerio-Goates, J. (2003b) Thermodynamics of Fe oxides: Part I. Entropy at standard temperature and pressure and heat capacity of goethite (α -FeOOH), lepidocrocite (γ-FeOOH), and maghemite (γ -Fe2O3). American Mineralogist, 88, 846-854.
24. Miyata, S. (1975) The syntheses of hydrotalcite-like compounds and their structures and physico-chemical properties. Clays and Clay Minerals, 23, 369-375.
25. Miyata, S. (1980) Physicochemical properties of synthetichydrotalcites in relation to composition. Clays and Clay Minerals, 28, 50-56.
26. Miyata, S. (1983) Anion-exchange properties of hydrotalcitelike compounds. Clays and Clay Minerals, 31, 305-311.
27. Parkhurst, D.L. and Appelo, C.A.J. (1999) User's guide to PHREEQC (version 2). Pp. 99-4259. US Geological Survey Water Resources Investigations Report.
28. Prikhod'ko, R.V., Sychev, M.V., Astrelin, I.M., Erdmann, K., Mangel, A., and van Santen, R.A. (2001) Synthesis and structural transformations of hydrotalcite-like materials Mg- Al and Zn-Al. Russian Journal of Applied Chemistry, 74, 1621-1626.
29. Rozov, K., Berner, U., Taviot-Gueho, C., Leroux, F., Renaudin, G., Kulik, D., and Diamond, L.W. (2010) Synthesis and characterization of the LDH hydrotalcitepyroaurite solid solution series. Cement and Concrete Research, 40, 1248-1254.
30. Trave, A., Selloni, A., Goursot, A., Tichit, D., and Weber, J. (2002) First principles study of the structure and chemistry of Mg-based hydrotalcite-like anionic clays. Journal of Physical Chemistry, 106, 12291-12296.
31. Vagvolgyi, V., Palmer, S.J., Kristof, J., Frost, R.L., and Horvath, E. (2008) Mechanism for hydrotalcite decomposition: A controlled rate thermal analysis study. Journal of Colloid and Interface Science, 318, 302-308.
32. Vidal, O. and Dubacq, B. (2009) Thermodynamic modelling of clay dehydration, stability and compositional evolution with temperature, pressure and H2O activity. Geochimica et Cosmochimica Acta, 73, 6544-6564.