A unified surface structural model for ferrihydrite: Proton charge, electrolyte binding, and arsenate adsorption

Revista Internacional de Contaminacion Ambiental

Volumn 27, Issue 2, 2011, Pages 139-151

  Villalobos, Mario ^a,b   Antelo, Juan ^c  

^a Facultad de Quimica   (Mexico)

^b UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^c UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

Ferrihydrite; Point of zero charge; Specific surface area; Surface structure

Indexed keywords

ADSORPTION; AGGREGATION; AQUATIC ENVIRONMENT; ARSENATE; ELECTROLYTE; ENVIRONMENTAL FATE; FERRIHYDRITE; GOETHITE; PARTICLE SIZE; SURFACE AREA; THERMODYNAMICS;

EID: 80955149371     PISSN: 01884999     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (38)

1. Antelo J., Fiol S., Perez C., Marino S., Arce F., Gondar D. and Lopez R. (2010). Analysis of phosphate adsorption onto ferrihydrite using the CD-MUSIC model: J. Colloid Interface Sci. 347, 112-119.
2. Boily J.-F., Lutzenkirchen J., Balmes O., Beattie J. and Sjoberg S. (2001). Modeling proton binding at the goethite (alpha-FeOOH)-water interface: Colloids and Surfaces A 179, 11-27.
3. Davis J.A. (1977). Adsorption of trace metals and complexing ligands at the oxide/water interface. Ph.D. Thesis. Stanford University, Stanford, California, 286 pp.
4. Dixit S. and Hering J.G. (2003). Comparison of arsenic(V) and arsenic (III) sorption onto iron oxide minerals: Implications for arsenic mobility: Environ. Sci. Technol. 37, 4182-4189.
5. Drits V.A., Sakharov B.A., Salyn A.L. and Manceau A. (1993). Structural model for ferrihydrite: Clay Min. 28, 185-207.
6. Dzombak D.A. and Morel F.M.M. (1990). Surface complexation modeling. Hydrous ferric oxide. John Wiley. New York, 393 pp.
7. Gilbert B., Lu G. and Kim C.S. (2007). Stable cluster formation in aqueous suspensions of iron oxyhydroxide nanoparticles. J. Colloid Interface Sci. 313, 152-159.
8. Gilbert B., Ono R.K., Ching K.A. and Kim C.S. (2009). The effects of nanoparticle aggregation processes on aggregate structure and metal uptake. J. Colloid Interface Sci. 339, 285-295.
9. Herbelin A.L. and Westall J.C. (1996), FITEQL. A computer program for determination of chemical equilibrium constants from experimental data. Report 94-01. Version 3.2. Department of Chemistry, Oregon State University. Corvallis, Oregon, USA.
10. Hiemstra T. and Van Riemsdijk W.H. (2009). A surface structural model for ferrihydrite: I. Sites related to primary charge, molar mass, and mass density. Geochim. Cosmochim. Acta 73, 4423-4436.
11. Hiemstra T., Van Riemsdijk W.H., Rossberg A. and Ulrich K.-U. (2009). A surface structural model for ferrihydrite: II. Adsorption of uranyl and carbonate. Geochim. Cosmochim. Acta 73, 4437-4451.
12. Hofmann A., van Beinum W., Meeussen J.C.L. and Kretzschmar R. (2005). Sorption kinetics of strontium in porous hydrous ferric oxide aggregates II. Comparison of experimental results and model predictions. J. Colloid Interface Sci. 283, 29-40.
13. Hsi C.-K. D. and Langmuir D. (1985). Adsorption of uranyl onto ferric oxyhydroxides: Application of the surface complexation site-binding model. Geochim. Cosmochim. Acta 49, 1931-1941.
14. Jain A., Raven K.P. and Loeppert R.H. (1999). Arsenite and arsenate adsorption on ferrihydrite: Surface charge reduction and net OHrelease stoichiometry. Environ. Sci. Technol. 33, 1179-1184.
15. Janney D.E., Cowley J.M. and Buseck P.R. (2000). Transmission electron microscopy of synthetic 2 and 6-line ferrihydrite. Clay Clay Min. 48, 111-119.
16. Kosmulski M. (2002). The pH-dependent surface charging and the points of zero charge. J. Colloid Interface Sci. 253, 77-87.
17. Kosmulski M. (2009). Compilation of PZC and IEP of sparingly soluble metal oxides and hydroxides from literature. Adv. Colloid Interface Sci. 152, 14-25.
18. Loring J.S., Sandstrom M.H., Noren K. and Persson P.(2009). Rethinking arsenate coordination at the surface of goethite. Chem.-Eur. J. 15, 5063-5072.
19. Lumsdon D.G. and Evans L.J. (1994). Surface complexation model parameters for goethite (a-FeOOH). J. Colloid Interface Sci. 164, 119-125.
20. Michel F.M., Ehm L., Antao S. M., Lee P. L., Chupas P. J., Liu G., Strongin D. R., Schoonen M. A. A., Phillips B. L. and Parise J. B. (2007). The structure of ferrihydrite, a nanocrystalline material: Science 316(5832), 1726-1729.
21. Michel F.M., Barron V., Torrent J., Morales M.P., Serna C.J., Boily J.F., Liu Q.S., Ambrosini A., Cismasu A.C. and Brown G.E. (2010). Ordered ferrimagnetic form of ferrihydrite reveals links among structure, composition, and magnetism. Proc. Natl. Acad. Sci. U. S. A. 107, 2787-2792.
22. Murphy P.J., Posner A.M. and Quirk J.P. (1976). Characterization of partially neutralized ferric nitrate solutions. J. Colloid Interface Sci. 56, 270-283.
23. Nagata T., Fukushi K. and Takahashi Y. (2009). Prediction of iodide adsorption on oxides by surface complexation modeling with spectroscopic confirmation. J. Colloid Interface Sci. 332, 309-316.
24. Pierce M.L. and Moore C.B. (1982). Adsorption of arsenite and arsenate on amorphous iron hydroxide. Water Res. 16, 1247-1253.
25. Rahnemaie R., Hiemstra T. and Van Riemsdijk W.H. (2006). A new surface structural approach to ion adsorption: Tracing the location of electrolyte ions. J. Colloid Interface Sci. 293, 312-321.
26. Raven K.P., Jain A. and Loeppert R.H. (1998). Arsenite and arsenate adsorption on ferrihydrite: Kinetics, equilibrium, and adsorption envelopes: Environmental Science and Technology, 32, 344-349.
27. Salazar-Camacho C. and Villalobos M. (2010). Goethite surface reactivity: III. Unifying arsenate adsorption behavior through a variable crystal face site density model. Geochim. Cosmochim. Acta 74, 2257-2280.
28. Schwertmann U. and Cornell R.M. (2000). Iron oxides in the laboratory. Preparation and characterization. John Wiley. Weinheim, Germany, 188 pp.
29. Sherman D.M. and Randall S.R. (2003). Surface complexation of arsenic(V) to iron(III) (hydr)oxides: Structural mechanism from ab initio molecular and RXAFS spectroscopy. Geochim. Cosmochim. Acta 67, 4223-4230.
30. Spadini L., Schindler P.W., Charlet L., Manceau A. and Ragnarsdottir K.V. (2003). Hydrous ferric oxide: Evaluation of Cd-HFO surface complexation models combining Cdk EXAFS data, potentiometric titration results, and surface site structures identified from mineralogical knowledge. J. Colloid Interface Sci. 266, 1-18.
31. Stachowicz M., Hiemstra T. and van Riemsdijk W.H. (2006). Surface speciation of As(III) and As(V) in relation to charge distribution. J. Colloid Interface Sci. 302, 62-75.
32. Theng B.K.G. and Yuan G. (2008). Nanoparticles in the soil environment. Elements 4, 395-399.
33. Van Geen A., Robertson A.P. and Leckie J.O. (1994). Complexation of carbonate species at the goethite surface: Implications for adsorption of metal ions in natural waters. Geochim. Cosmochim. Acta 58(9), 2073-2086.
34. Villalobos M. and Leckie J.O. (2000). Carbonate adsorption onto goethite under closed and open CO2 conditions. Geochim. Cosmochim. Acta 64, 3787-3802.
35. Villalobos M., Toner B., Bargar J. and Sposito G. (2003). Characterization of the Mn oxide produced by Pseudomonas putida strain MnB1. Geochim. Cosmochim. Acta 67, 2649-2662.
36. Waychunas G.A. and Zhang H. (2008). Structure, chemistry, and properties of mineral nanoparticles. Elements 4, 381-387.
37. Yates D.E. (1975) The structure of the oxide/aqueous electrolyte interface. Ph.D. Thesis. University of Melbourne. Melbourne, Australia, 272 pp.
38. Zeltner W.A. and Anderson M.A. (1988). Surface charge development at the goethite/aqueous solution interface: effects of CO2 adsorption. Langmuir 4, 468-474.