Homolytic reactive mass spectrometry of fullerenes: Interaction of C 60 and C 70 with ketones in the electron impact ion source of a mass spectrometer and the comparison of results with those of photochemical reactions of C 60 with several ketones in solution

Journal of the American Society for Mass Spectrometry

Volumn 22, Issue 11, 2011, Pages 2021-2032

  Shilova, Elena A ^a   Lyakhovetsky, Yury I ^a   Belokon, Alexander I ^a   Ponomareva, Tatyana V ^a   Gasanov, Rashid G ^a   Tumanskii, Boris L ^a,b   Nekrasov, Yuri S ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

^b TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

Electron impact; Fullerenes; Ketones; Photochemical reactions; Reactive mass spectrometry

Indexed keywords

DECALIN; ELECTRON IMPACT; EXPERIMENTAL EVIDENCE; HOMOLYTIC DISSOCIATION; HYDROGEN ADDITION; ORGANOMERCURY; REACTIVE MASS; SUPEREXCITED STATE; UV IRRADIATION;

FREE RADICAL REACTIONS; FULLERENES; ION SOURCES; IRRADIATION; KETONES; MASS SPECTROMETERS; MASS SPECTROMETRY; ORGANIC COMPOUNDS; ORGANIC SOLVENTS; PARAMAGNETISM;

PHOTOCHEMICAL REACTIONS;

FULLERENE DERIVATIVE; KETONE DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CONFORMATION; ELECTRON SPIN RESONANCE; IONIZATION; MASS SPECTROMETRY; PHOTOCHEMISTRY; REACTIVE MASS SPECTROMETRY; VAPORIZATION;

EID: 80755168419     PISSN: 10440305     EISSN: 18791123     Source Type: Journal    
DOI: 10.1007/s13361-011-0219-4     Document Type: Article

References (24)

1. Shilova, E.A., Lyakhovetsky, Y.I., Tumanskii, B.L., Belokon', A.I., Nekrasov, Y.S.: Alkylation and Phenylation of [60]- and [70]-Fullerenes by the Reaction with Ketones in the Ionization Chamber of a Mass Spectrometer. Mendeleev. Commun 176-177 (1999).
2. CN McEwen MA Rudat 1979 Fast Radical Reactions in a Mass Spectrometer Ion Source: Radical Addition to 7,7,8,8-Tetracyanoquinodimethane J. Am. Chem. Soc. 101 6470 6472 10.1021/ja00515a072 1:CAS:528:DyaE1MXlvFant7c%3D
3. CN McEwen MA Rudat 1981 Radical Trapping in a Mass Spectrometer Ion Source. 1 J. Am. Chem. Soc. 103 4343 4349 10.1021/ja00405a009 1:CAS:528:DyaL3MXksFensbY%3D
4. MA Rudat CN McEwen 1981 Gas-Phase Radical Structures. Radical Trapping. 2 J. Am. Chem. Soc. 103 4349 4354 10.1021/ja00405a010 1:CAS:528: DyaL3MXltlajsrg%3D
5. CN McEwen MA Rudat 1981 Isomerization of Gas-Phase Hydrocarbon Ions. Radical Trapping. 3 J. Am. Chem. Soc. 103 4355 4359 10.1021/ja00405a011 1:CAS:528:DyaL3MXltlajsrs%3D
6. D Stöckl H Budzikiewicz 1982 Negative-Ion Mass Spectrometry. 5. Molecule Radical Reactions Prior to Ionization under Negative Chemical Ionization Conditions Org. Mass. Spectrom 17 376 381 10.1002/oms.1210170807
7. G-R Her GG Dolnikowski J Throck Watson 1986 Hydrogen Radical/Molecule Reactions in the Negative-Ion Mass Spectrometry of Dicyanomethane Derivatives of 9-Fluorenone and Benzophenone Org. Mass. Spectrom 21 329 334 10.1002/oms.1210210606 1:CAS:528:DyaL2sXhtF2is7c%3D
8. Tumanskii, B., Kalina, O.: Radical Reactions of Fullerenes and Their Derivatives. Developments in Fullerene Science, 2, p. 25. Kluwer Academic Publishers, Dordrecht (2001)
9. 60 as a Radical Sponge J. Am. Chem. Soc. 114 4412 4414 10.1021/ja00037a064 1:CAS:528:DyaK38XisVOhs7s%3D
10. YI Lyakhovetsky EA Shilova BL Tumanskii AV Usatov EA Avetysian SR Sterlin AP Pleshkova YN Novikov YS Nekrasov R Taylor 1999 Trifluoromethylation of [60]- and [70]Fullerene in the Ionization Chamber of a Mass Spectrometer Fuller. Sci. Technol. 7 263 287 10.1080/10641229909350283 1:CAS:528:DyaK1MXis1Cqtrg%3D
11. 70 with Mercury(II) Trifluoroacetate Fuller. Nanotub. Carbon Nanostruct 17 85 98 10.1080/15363830802674530 1:CAS:528:DC%2BD1MXivFygsro%3D
12. 60 Performed in Solution J. Phys. Chem. A 113 13700 13710 10.1021/jp906058q 1:CAS:528:DC%2BD1MXhsVantbrM
13. YN Sukharev VF Sizoi YS Nekrasov 1981 The Computer Processing and Interpretation of Mass Spectral Information. VI. Computing the Isotopic Spectrum of Assumed Composition Org. Mass. Spectrom 16 23 25 10.1002/oms.1210160107 1:CAS:528:DyaL3MXitFyguro%3D
14. BL Tumanskii OG Kalina VV Bashilov 2000 EPR Study of Radical Reactions of Fullerenes and Their Derivatives Mol. Mater 13 23 30 1:CAS:528: DC%2BD3cXosVKmu7c%3D
15. VI Makarov LS Polak 1970 Excited and Superexcited Electronic States of Atoms and Molecules and Their Role in Radiation Chemistry Khim. Vys. Energ 4 3 23 1:CAS:528:DyaE3cXhtVGrsrs%3D [High Energy Chem. 1970, 4, 1 (Eng. Transl.)]
16. DK Bohme 2009 Buckminsterfullerene Cations: New Dimensions in Gas Phase Ion Chemistry Mass Spectrom. Rev 28 672 693 10.1002/mas.20227 1:CAS:528:DC%2BD1MXos1WhsLw%3D
17. 3+ with Aldehydes, Ketones, Carboxylic Acids, and Esters Int. J. Mass Spectrom. Ion Process 138 187 208 10.1016/0168-1176(94)04057-5 1:CAS:528:DyaK2MXivVKrsL4%3D
18. S Petrie DK Bohme 2000 Laboratory Studies of Ion/Molecule Reactions of Fullerenes: Chemical Derivatization of Fullerenes within Dense Interstellar Clouds and Circumstellar Shells Astrophys. J. 540 869 885 10.1086/309346 1:CAS:528:DC%2BD3cXnsF2htLk%3D
19. 70 by Ion/Molecule Reactions Rapid Commun. Mass Spectrom 9 213 214 10.1002/rcm.1290090307
20. + Adduct Cations J. Mass Spectrom 32 241 246 10.1002/(SICI)1096-9888(199702)32:2<241::AID-JMS468>3.0.CO;2-Q 1:CAS:528:DyaK2sXhsVaru70%3D (Pubitemid 27087391)
21. D Sun Zi Liu Zh Liu X Guo C Hao W Xu S Liu 1997 Gas Phase Derivations of Endohedral Metallofullerenes by Ion-Molecular Reactions Fuller. Sci. Technol. 5 1461 1477 10.1080/15363839708013333 1:CAS:528:DyaK1cXitVWhtg%3D%3D (Pubitemid 127593833)
22. Einführung in die Photochemie von Einem Autorencollective: Veb Deutcher Verlag der Wissenschaften, Berlin, (1976) [pp. 167-172. Izdatelstvo Khimia, Leningrad (1976) (Russ. Transl.]
23. 60 Science 254 1183 1185 10.1126/science.254.5035.1183 1:CAS:528:DyaK38XhvFemurk%3D (Pubitemid 21917446)
24. 60 Radicals Can. J. Chem. 72 776 782 10.1139/v94-103 1:CAS:528:DyaK2cXkvVagtbs%3D