Hydrotalcite-like compounds containing transition metals as solid base catalysts for transesterification

Chemical Engineering Journal

Volumn 175, Issue 1, 2011, Pages 548-554

  Wang, Yu Bin ^a   Jehng, Jih Mirn ^a  

^a NATIONAL CHUNG HSING UNIVERSITY   (Taiwan)

Author keywords

Biodiesel; FAME (esters of fatty acids); Heterogeneous base catalysts; Hydrotalcite like compounds (HTLCs); Transesterification

Indexed keywords

COPRECIPITATION METHOD; FAME (ESTERS OF FATTY ACIDS); HETEROGENEOUS BASE CATALYST; HYDROTALCITE-LIKE COMPOUND; HYDROTALCITE-LIKE STRUCTURES; LAYERED DOUBLE HYDROXIDES; MG CONTENT; MOLAR RATIO; NITROGEN ADSORPTION-DESORPTION; OPTIMUM CONDITIONS; SOLID BASE CATALYSTS; SOYBEAN OIL; STIRRING SPEED; SURFACE AREA; XRD;

ALUMINUM; BIODIESEL; CALCINATION; CARBON DIOXIDE; FATTY ACIDS; GAS ADSORPTION; METHANOL; PHYSISORPTION; PRECIPITATION (CHEMICAL); SYNTHETIC FUELS; TEMPERATURE PROGRAMMED DESORPTION; THERMOGRAVIMETRIC ANALYSIS; TRANSESTERIFICATION; TRANSITION METALS; X RAY POWDER DIFFRACTION;

CATALYSTS;

GLYCINE MAX;

EID: 80755128994     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.09.126     Document Type: Article

References (42)

1. Xu Q., Ni Z.-m., Mao J.-h. First principles study of microscopic structures and layer-anion interactions in layered double hydroxides intercalated various univalent anions. Journal of Molecular Structure: THEOCHEM 2009, 915:122-131.
2. Xi Y., Davis R.J. Influence of textural properties and trace water on the reactivity and deactivation of reconstructed layered hydroxide catalysts for transesterification of tributyrin with methanol. J. Catal. 2009, 268:307-317.
3. Costantino U., Marmottini F., Nocchetti M., Vivani R. New synthetic routes to hydrotalcite-like compounds - characterisation and properties of the obtained materials. Eur. J. Inorg. Chem. 1998, 1998:1439-1446.
4. Tichit D., Lutic D., Coq B., Durand R., Teissier R. The aldol condensation of acetaldehyde and heptanal on hydrotalcite-type catalysts. J. Catal. 2003, 219:167-175.
5. Prescott H.A., Li Z.-J., Kemnitz E., Trunschke A., Deutsch J., Lieske H., Auroux A. Application of calcined Mg-Al hydrotalcites for Michael additions: an investigation of catalytic activity and acid-base properties. J. Catal. 2005, 234:119-130.
6. Antunes W.M., Veloso C.d.O., Henriques C.A. Transesterification of soybean oil with methanol catalyzed by basic solids. Catal. Today 2008, 133-135:548-554.
7. Bulbule V.J., Borate H.B., Munot Y.S., Deshpande V.H., Sawargave S.P., Gaikwad A.G. Transesterification of [alpha]-haloesters and [beta]-ketoesters over Mg-Al-hydrotalcites (HT)-like anionic clays. J. Mol. Catal. A. Chem. 2007, 276:158-161.
8. Albuquerque M.C.G., Azevedo D.C.S., Cavalcante C.L., Santamaría-González J., Mérida-Robles J.M., Moreno-Tost R., Rodríguez-Castellón E., Jiménez-López A., Maireles-Torres P. Transesterification of ethyl butyrate with methanol using MgO/CaO catalysts. J. Mol. Catal. A: Chem. 2009, 300:19-24.
9. Guan G., Kusakabe K., Sakurai N., Moriyama K. Transesterification of vegetable oil to biodiesel fuel using acid catalysts in the presence of dimethyl ether. Fuel 2009, 88:81-86.
10. López D.E., Goodwin J.J.G., Bruce D.A., Lotero E. Transesterification of triacetin with methanol on solid acid and base catalysts. Appl. Catal. A: Gen. 2005, 295:97-105.
11. Kim H.-J., Kang B.-S., Kim M.-J., Park Y.M., Kim D.-K., Lee J.-S., Lee K.-Y. Transesterification of vegetable oil to biodiesel using heterogeneous base catalyst. Catal. Today 2004, 93-95:315-320.
12. Xie W., Peng H., Chen L. Transesterification of soybean oil catalyzed by potassium loaded on alumina as a solid-base catalyst. Appl. Catal. A: Gen. 2006, 300:67-74.
13. Yang Z., Xie W. Soybean oil transesterification over zinc oxide modified with alkali earth metals. Fuel Process. Technol. 2007, 88:631-638.
14. Soumanou M.M., Bornscheuer U.T. Improvement in lipase-catalyzed synthesis of fatty acid methyl esters from sunflower oil. Enzyme Microb. Technol. 2003, 33:97-103.
15. Du W., Xu Y., Liu D. Lipase-catalysed transesterification of soya bean oil for biodiesel production during continuous batch operation. Biotechnol. Appl. Biochem. 2003, 38:103-106.
16. 2O salt. Fuel 2010, 89:1961-1972.
17. Xie W., Huang X. Synthesis of biodiesel from soybean oil using heterogeneous KF/ZnO catalyst. Catal. Lett. 2006, 107:53-59.
18. Ngamcharussrivichai C., Totarat P., Bunyakiat K. Ca and Zn mixed oxide as a heterogeneous base catalyst for transesterification of palm kernel oil. Appl. Catal. A: Gen. 2008, 341:77-85.
19. Shishido T., Sukenobu M., Morioka H., Kondo M., Wang Y., Takaki K., Takehira K. Partial oxidation of methane over Ni/Mg-Al oxide catalysts prepared by solid phase crystallization method from Mg-Al hydrotalcite-like precursors. Appl. Catal. A: Gen. 2002, 223:35-42.
20. Takehira K., Shishido T., Shouro D., Murakami K., Honda M., Kawabata T., Takaki K. Novel and effective surface enrichment of active species in Ni-loaded catalyst prepared from Mg-Al hydrotalcite-type anionic clay. Appl. Catal. A: Gen. 2005, 279:41-51.
21. N. 2003, Fat and Oil Derivates-Fatty Acid Methyl Ester (FAME)-Determination of Ester and Linolenic Acid Methyl Ester Contents, National Standard Authority of Ireland, I.S. EN 14103:12003.
22. Cantrell D.G., Gillie L.J., Lee A.F., Wilson K. Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis. Appl. Catal. A: Gen. 2005, 287:183-190.
23. Cesteros Y., Salagre P., Medina F., Sueiras J.E., Tichit D., Coq B. Hydrodechlorination of 1,2,4-trichlorobenzene on nickel-based catalysts prepared from several Ni/Mg/Al hydrotalcite-like precursors. Appl. Catal. B: Environ. 2001, 32:25-35.
24. 4 reforming. Catal. Commun. 2004, 5:209-213.
25. Rodrigues A.C.C., Henriques C.A., Monteiro J.L.F. Influence of Ni content on physico-chemical characteristics of Ni, Mg, Al-hydrotalcite like compounds. Mater. Res. 2003, 563-568.
26. Shannon R. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A 1976, 751-767.
27. Choudhary V.R., Chaudhari P.A., Narkhede V.S. Solvent-free liquid phase oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using non-noble transition metal containing hydrotalcite-like solid catalysts. Catal. Commun. 2003, 4:171-175.
28. Fraile J.M., García N., Mayoral J.A., Pires E., Roldán L. The influence of alkaline metals on the strong basicity of Mg-Al mixed oxides: the case of transesterification reactions. Appl. Catal. A: Gen. 2009, 364:87-94.
29. Xie W., Peng H., Chen L. Calcined Mg-Al hydrotalcites as solid base catalysts for methanolysis of soybean oil. J. Mol. Catal. A: Chem. 2006, 246:24-32.
30. Tantirungrotechai J., Chotmongkolsap P., Pohmakotr M. Synthesis, characterization, and activity in transesterification of mesoporous Mg-Al mixed-metal oxides. Micropor. Mesopor. Mater. 2010, 128:41-47.
31. Shumaker J.L., Crofcheck C., Tackett S.A., Santillan-Jimenez E., Morgan T., Ji Y., Crocker M., Toops T.J. Biodiesel synthesis using calcined layered double hydroxide catalysts. Appl. Catal. B: Environ. 2008, 82:120-130.
32. Albuquerque M.C.G., Santamaría-González J., Mérida-Robles J.M., Moreno-Tost R., Rodríguez-Castellón E., Jiménez-López A., Azevedo D.C.S., Cavalcante C.L., Maireles-Torres P. MgM (M=Al and Ca) oxides as basic catalysts in transesterification processes. Appl. Catal. A: Gen. 2008, 347:162-168.
33. Sree R., Seshu Babu N., Sai Prasad P.S., Lingaiah N. Transesterification of edible and non-edible oils over basic solid Mg/Zr catalysts. Fuel Process. Technol. 2009, 90:152-157.
34. Di Serio M., Cozzolino M., Giordano M., Tesser R., Patrono P., Santacesaria E. From homogeneous to heterogeneous catalysts in biodiesel production. Ind. Eng. Chem. Res. 2007, 46:6379-6384.
35. Jitianu M., Bãlãsoiu M., Marchidan R., Zaharescu M., Crisan D., Craiu M. Thermal behaviour of hydrotalcite-like compounds: study of the resulting oxidic forms. Int. J. Inorg. Mater. 2000, 2:287-300.
36. López T., Bosch P., Asomoza M., Gómez R., Ramos E. DTA-TGA and FTIR spectroscopies of sol-gel hydrotalcites: aluminum source effect on physicochemical properties. Mater. Lett. 1997, 31:311-316.
37. Othman M.R., Rasid N.M., Fernando W.J.N. Mg-Al hydrotalcite coating on zeolites for improved carbon dioxide adsorption. Chem. Eng. Sci. 2006, 61:1555-1560.
38. Prinetto F., Ghiotti G., Graffin P., Tichit D. Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples. Micropor. Mesopor. Mater. 2000, 39:229-247.
39. Yan K., Xie X., Li J., Wang X., Wang Z. Preparation, characterization, and catalytical application of MgCoAl-hydrotalcite-like compounds. J. Nat. Gas Chem. 2007, 16:371-376.
40. Zeng H.-y., Feng Z., Deng X., Li Y.-q. Activation of Mg-Al hydrotalcite catalysts for transesterification of rape oil. Fuel 2008, 87:3071-3076.
41. Li E., Xu Z.P., Rudolph V. MgCoAl-LDH derived heterogeneous catalysts for the ethanol transesterification of canola oil to biodiesel. Appl. Catal. B: Environ. 2009, 88:42-49.
42. Xi Y., Davis R.J. Influence of water on the activity and stability of activated MgAl hydrotalcites for the transesterification of tributyrin with methanol. J. Catal. 2008, 254:190-197.