Effect of reaction solvent on the preparation of thermo-responsive stationary phase through a surface initiated atom transfer radical polymerization

Journal of Chromatography A

Volumn 1218, Issue 48, 2011, Pages 8617-8628

  Nagase, Kenichi ^a   Mizutani Akimoto, Aya ^a,b,d   Kobayashi, Jun ^a   Kikuchi, Akihiko ^c   Akiyama, Yoshikatsu ^a   Kanazawa, Hideko ^b   Okano, Teruo ^a  

^a Tokyo Women s Medical University Waseda University Joint Institution for Advanced Biomedical Sciences   (Japan)

^b KEIO UNIVERSITY   (Japan)

^c TOKYO UNIVERSITY OF SCIENCE   (Japan)

^d INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

Author keywords

Atom transfer radical polymerization; Poly(N isopropylacrylamide); Polymer brush; Reaction solvent; Thermo responsive polymer

Indexed keywords

2-PROPANOL; ADSORPTION DESORPTION; ANALYTES; BIOACTIVE COMPOUNDS; CALIBRATION CURVES; CHROMATOGRAPHIC STATIONARY PHASE; ELUTION PROFILES; HIGHER RESOLUTION; N ,N-DIMETHYLFORMAMIDE; N-ISOPROPYLACRYLAMIDES; POLYMER BRUSH; PORE DIAMETERS; PULLULANS; REACTION SOLVENTS; SEPARATION EFFICIENCY; SILICA BEADS; STATIONARY PHASE; SURFACE INITIATED-ATOM TRANSFER RADICAL POLYMERIZATION; SURFACE-INITIATED ATOM TRANSFER; TEMPERATURE DEPENDENT; THERMO-RESPONSIVE; THERMORESPONSIVE POLYMER;

ACRYLIC MONOMERS; ADSORPTION; ATOMS; BRUSHES; DESORPTION; DIMETHYLFORMAMIDE; FREE RADICAL REACTIONS; GLUCOSE; GRAFTING (CHEMICAL); ORGANIC SOLVENTS; POLYMERIZATION; POLYMERS; PROPANOL; SILICA; SOLVENTS; SURFACE REACTIONS;

ATOM TRANSFER RADICAL POLYMERIZATION;

2 PROPANOL; ADENOSINE; DEXAMETHASONE; GLUCOSE; HYDROCORTISONE; HYDROCORTISONE ACETATE; N,N DIMETHYLFORMAMIDE; NITROGEN; POLY(N ISOPROPYLACRYLAMIDE); PULLULAN; SILICON DIOXIDE; SOLVENT; WATER;

ADSORPTION; ARTICLE; ATOM TRANSFER RADICAL POLYMERIZATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; DESORPTION; ELUTION; HEAT SENSITIVITY; HYDROPHOBICITY; POROSITY; PRIORITY JOURNAL; SEPARATION TECHNIQUE; TEMPERATURE;

ACRYLAMIDES; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; HYDROPHOBIC AND HYDROPHILIC INTERACTIONS; PARTICLE SIZE; POLYMERIZATION; POLYMERS; POROSITY; SILICON DIOXIDE; SOLVENTS; STEROIDS; TEMPERATURE;

EID: 80455158209     PISSN: 00219673     EISSN: 18733778     Source Type: Journal    
DOI: 10.1016/j.chroma.2011.09.082     Document Type: Article

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