Dihydrogen addition in a dinuclear rare-earth metal hydride complex supported by a metalated TREN ligand

Journal of the American Chemical Society

Volumn 133, Issue 44, 2011, Pages 17574-17577

  Venugopal, Ajay ^a   Fegler, Waldemar ^a   Spaniol, Thomas P ^a   Maron, Laurent ^b   Okuda, Jun ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b INSA   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DICATIONS; DIHYDRIDES; DIHYDROGEN; DINUCLEAR; RARE-EARTH METALS; TRIPODAL LIGANDS;

LIGANDS; MOLECULAR ORBITALS;

HYDRIDES;

ANION; CATION; HYDROGEN; LUTETIUM; LUTETIUM DIHYDRIDE; UNCLASSIFIED DRUG; YTTRIUM;

ARTICLE; CHEMICAL BINDING; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; GEOMETRY; HYDROGENATION; HYDROGENOLYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY DIFFRACTION;

COORDINATION COMPLEXES; ETHYLENEDIAMINES; HYDROGEN; LIGANDS; METALS, RARE EARTH; MODELS, MOLECULAR; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 80455129418     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja207180x     Document Type: Article

References (43)

1. Orimo, S.-I.; Nakamori, Y.; Elisco, J. R.; Züttel, A.; Jensen, C. M. Chem. Rev. 2007, 107, 4111
2. Schlapbach, L.; Züttel, A. Nature 2001, 414, 353
3. Kubas, G. J. Chem. Rev. 2007, 107, 4152
4. Evans, W. J.; Meadows, J. H.; Hanusa, T. P. J. Am. Chem. Soc. 1984, 106, 4454
5. Evans, W. J.; Meadows, J. H.; Wayda, A. L.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1982, 104, 2015
6. Evans, W. J.; Meadows, J. H.; Wayda, A. L.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1982, 104, 2008
7. Schumann, H.; Genthe, W. J. Organomet. Chem. 1981, 213, C7
8. Takenaka, Y.; Hou, Z. Organometallics 2009, 28, 5196
9. Ephritikhine, M. Chem. Rev. 1997, 97, 2193
10. Watson, P. L.; Parshall, G. W. Acc. Chem. Res. 1985, 18, 51
11. Watson, P. L. J. Am. Chem. Soc. 1983, 105, 6491
12. Watson, P. L. J. Chem. Soc., Chem. Commun. 1983, 276
13. Nishiura, M.; Hou, Z. Nat. Chem. 2010, 2, 257
14. Hou, Z.; Nishiura, M.; Shima, T. Eur. J. Inorg. Chem. 2007, 2535
15. Hultzsch, K. C.; Spaniol, T. P.; Okuda, J. Angew. Chem., Int. Ed. 1999, 38, 227
16. Cheng, J.-H.; Ferguson, M. J.; Takats, J. J. Am. Chem. Soc. 2010, 132, 2
17. Ohashi, M.; Konkol, M.; Del, R. I.; Poteau, R.; Maron, L.; Okuda, J. J. Am. Chem. Soc. 2008, 130, 6920
18. Cheng, J.; Saliu, K.; Kiel, G. Y.; Ferguson, M. J.; McDonald, R.; Takats, J. Angew. Chem., Int. Ed. 2008, 47, 4910
19. Lyubov, D. M.; Döring, C.; Fukin, G. K.; Cherkasov, A. V.; Shavyrin, A. S.; Kempe, R.; Trifonov, A. A. Organometallics 2008, 27, 2905
20. Konkol, M.; Okuda, J. Coord. Chem. Rev. 2008, 252, 1577 and references therein
21. Luconi, L.; Lyubov, D. M.; Bianchini, C.; Rossin, A.; Faggi, C.; Fukin, G. K.; Cherkasov, A. V.; Shavyrin, A. S.; Trifonov, A. A.; Giambastiani, G. Eur. J. Inorg. Chem. 2010, 608
22. Tardif, O.; Nishiura, M.; Hou, Z. Organometallics 2003, 22, 1171
23. Ciampolini, M.; Nardi, N. Inorg. Chem. 1966, 5, 41
24. Davidson, M. G.; Garcia-Vivo, D.; Kennedy, A. R.; Mulvey, R. E.; Robertson, S. D. Chem.-Eur. J. 2011, 17, 3364
25. Cousins, D. M.; Davidson, M. G.; Frankis, C. J.; Garcia-Vivo, D.; Mahon, M. F. Dalton Trans. 2010, 39, 8278
26. Lyubov, D. M.; Döring, C.; Ketkov, S. Y.; Kempe, R.; Trifonov, A. A. Chem.-Eur. J. 2011, 17, 3824
27. Li, X.; Baldamus, J.; Nishiura, M.; Tardif, O.; Hou, Z. Angew. Chem., Int. Ed. 2006, 45, 8184
28. Cheng, J.; Shima, T.; Hou, Z. Angew. Chem., Int. Ed. 2011, 50, 1857
29. Elvidge, B. R.; Arndt, S.; Zeimentz, P. M.; Spaniol, T. P.; Okuda, J. Inorg. Chem. 2005, 44, 6777
30. Arndt, S.; Spaniol, T. P.; Okuda, J. Angew. Chem., Int. Ed. 2003, 42, 5075
31. Ge, S.; Meetsma, A.; Hessen, B. Organometallics 2007, 26, 5278
32. Bambirra, S.; Boot, S. J.; van Leusen, D.; Meetsma, A.; Hessen, B. Organometallics 2004, 23, 1891
33. Hayes, P. G.; Piers, W. E.; Lee, L. W. M.; Knight, L. K.; Parvez, M.; Elsegood, M. R. J.; Clegg, W. Organometallics 2001, 20, 2533
34. Mu, Y.; Piers, W. E.; MacQuarrie, D. C.; Zaworotko, M. J.; Young, V. G., Jr. Organometallics 1996, 15, 2720
35. Booij, M.; Kiers, N. H.; Meetsma, A.; Teuben, J. H.; Smeets, W. J. J.; Spek, A. L. Organometallics 1989, 8, 2454
36. Arndt, S.; Spaniol, T. P.; Okuda, J. Chem. Commun. 2002, 896
37. Zhang, L.; Suzuki, T.; Luo, Y.; Nishiura, M.; Hou, Z. Angew. Chem., Int. Ed. 2007, 46, 1909
38. Voth, P.; Spaniol, T. P.; Okuda, J. Organometallics 2003, 22, 3921
39. Coughlin, E. B.; Bercaw, J. E. J. Am. Chem. Soc. 1992, 114, 7606
40. Trifonov, A. A.; Fedorova, E. A.; Fukin, G. K.; Bochkarev, M. N. Eur. J. Inorg. Chem. 2004, 4396
41. Hultzsch, K. C.; Voth, P.; Beckerle, K.; Spaniol, T. P.; Okuda, J. Organometallics 2000, 19, 228
42. Schumann, H.; Genthe, W.; Hahn, E.; Hossain, M. B.; Van Der Helm, D. J. Organomet. Chem. 1986, 299, 67
43. Cationic rare-earth metal alkyls are also nucleophilic/basic: Arndt, S.; Elvidge, B. R.; Zeimentz, P. M.; Okuda, J. Chem. Rev. 2006, 106, 2404