Advanced oxidation process based on the Cr(III)/Cr(VI) redox cycle

Environmental Science and Technology

Volumn 45, Issue 21, 2011, Pages 9332-9338

  Bokare, Alok D ^a   Choi, Wonyong ^a  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

4-CHLOROPHENOL (4-CP); ACIDIC CONDITIONS; ADVANCED OXIDATION PROCESSES; AQUEOUS ORGANIC POLLUTANTS; BENZOIC ACID; DUAL ROLE; FENTON LIKES; MODEL SUBSTRATES; OXIDATION RATES; OXIDATIVE CAPACITY; OXIDATIVE DEGRADATION; P-HYDROXYBENZOIC ACID; PROBE REACTIONS; REDOX CYCLES; REDUCTANTS; STEPWISE OXIDATION; WIDE PH RANGE;

ALKALINITY; CARBOXYLIC ACIDS; DEGRADATION; METHANOL; OLIGOMERS; ORGANIC POLLUTANTS; OXIDATION; OXIDATION RESISTANCE; REDOX REACTIONS;

CHROMIUM COMPOUNDS;

4 CHLOROPHENOL; 4 HYDROXYBENZOIC ACID; BENZOIC ACID; CHROMIUM; HYDROGEN PEROXIDE; METHANOL; OLIGOMER; ORGANIC COMPOUND;

ALKALINITY; AQUEOUS SOLUTION; CHROMIUM; ENVIRONMENTAL DEGRADATION; ENVIRONMENTAL MONITORING; HYDROGEN PEROXIDE; HYDROLYSIS; ORGANIC ACID; ORGANIC POLLUTANT; OXIDATION; PH; PHENOL; REDOX POTENTIAL;

ALKALINITY; ARTICLE; DEGRADATION KINETICS; FENTON REACTION; HYDROLYSIS; MOLECULAR PROBE; OXIDATION KINETICS; OXIDATION REDUCTION REACTION; PH; POLLUTANT;

CHROMIUM; HYDROGEN PEROXIDE; HYDROLYSIS; HYDROXYBENZOIC ACIDS; MODELS, CHEMICAL; OXIDATION-REDUCTION;

EID: 80055087233     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es2021704     Document Type: Article

References (45)

1. Gogate, P. R.; Pandit, A. B. A review of imperative technologies for wastewater treatment. I: Oxidation technologies at ambient conditions Adv. Environ. Res. 2004, 8, 501-551
2. Mägerlein, W.; Dreisbach, C.; Hugl, H.; Tse, M. K.; Klawonn, M.; Bhor, S.; Beller, M. Homogeneous and heterogeneous ruthenium catalysts in the synthesis of fine chemicals Catal. Today 2007, 121, 140-150
3. Pignatello, J. J.; Oliveros, E.; MacKay, A. Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry Crit. Rev. Environ. Sci. Technol. 2006, 36, 1-84
4. Laine, D. F.; Cheng, I. F. The destruction of organic pollutants under mild reaction conditions: A review Microchem. J. 2007, 85, 183-193
5. 2 system Chemosphere 2001, 45, 59-65
6. Collins, T. J. TAML oxidant activators: A new approach to the activation of hydrogen peroxide for environmentally significant problems Acc. Chem. Res. 2002, 35, 782-90
7. 2 systems: Effects of pH and copper speciation J. Catal. 2005, 232, 117-126
8. Shah, V.; Verma, P.; Stopka, P.; Gabriel, J.; Baldrian, P.; Nerud, F. Decolorization of dyes with copper(II)/organic acid/hydrogen peroxide systems Appl. Catal., B 2003, 46, 287-292
9. Pestunova, O. P.; Ogorodnikova, O. L.; Parmon, V. N. Studies on the phenol wet peroxide oxidation in the presence of solid catalysts Chem. Sustain. Dev. 2003, 11, 227-232
10. Beverskog, B.; Puigdomenech, I. Revised Pourbaix diagrams for chromium at 25-300 °C Corros. Sci. 1997, 39, 43-57
11. Owlad, M.; Aroua, M. K.; Daud, W. A. W.; Baroutian, S. Removal of hexavalent chromium-contaminated water and wastewater: A review Water, Air Soil Pollut. 2009, 200, 59-77
12. Wang, W. X.; Griscom, S. B.; Fisher, N. S. Bioavailability of Cr(III) and Cr(VI) to marine mussels from solute and particulate pathways Environ. Sci. Technol. 1997, 31, 603-611
13. CRC Handbook of Chemistry and Physics, 85 th ed.; CRC Press: Boca Raton, FL, 2004.
14. Rai, D.; Eary, L. E.; Zacharia, J. M. Environmental chemistry of chromium Sci. Total Environ. 1989, 86, 15-23
15. 2 (I) Characterization Environ. Sci. Technol. 1992, 26, 79-85
16. Zhang, H.; Bartlett, R. J. Light-induced oxidation of aqueous chromium(III) in the presence of iron(III) Environ. Sci. Technol. 1999, 33, 588-594
17. Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry; Wiley-Interscience: New York, 1999.
18. Richard, F. C.; Bourg, A. C. M. Aqueous geochemistry of chromium: A review Water Res. 1991, 25, 807-816
19. 2 in acidic solutions Environ. Sci. Technol. 2002, 36, 901-907
20. Bokare, A. D.; Choi, W. Chromate-induced activation of hydrogen peroxide for oxidative degradation of aqueous organic pollutants Environ. Sci. Technol. 2010, 44, 7232-7237
21. APHA, AWWA, WEF. Standard Methods for the Examination of Water and Wastewater, 20 th ed; APHA: Washington, DC, 1988; pp 3-65-3-68.
22. Pettine, M.; La Noce, T.; Liberatori, A.; Loreti, L. Hydrogen peroxide interference in the determination of chromium(VI) by the diphenylcarbazide method Anal. Chim. Acta 1988, 209, 315-319
23. Hunt, J. P. Metal Ions in Aqueous Solutions; Benjamin, Inc: New York, 1963.
24. Joo, S. H.; Feitz, A. Z.; Sedlak, D. L.; Waite, T. D. Quantification of the oxidizing capacity of nanoparticulate zero-valent iron Environ. Sci. Technol. 2005, 39, 1263-1268
25. Shi, X.; Mao, Y.; Knapton, A. D.; Ding, M.; Rojanasakul, Y.; Gannett, P. M.; Dalal, N. S.; Liu, K. Reaction of Cr(VI) with ascorbate and hydrogen peroxide generates hydroxyl radicals and causes DNA damage: Role of a Cr(IV)-mediated Fenton-like reaction Carcinogenesis 1994, 15, 2475-2478
26. Tsou, T.-C.; Yang, J.-L. Formation of reactive oxygen species and DNA strand breakage during interaction of chromium(III) and hydrogen peroxide in vitro: Evidence for a chromium(III)-mediated Fenton-like reaction Chem.-Biol. Interact. 1996, 102, 133-153
27. Haight, G. P., Jr. ; Huang, T. J.; Shakhashiri, B. Z. Reactions of Cr(IV) J. Inorg. Nucl. Chem. 1971, 33, 2169-2176
28. Shi, X.; Dalal, N. S. ESR spin trapping detection of hydroxyl radicals in the reactions of Cr(V) complexes with hydrogen peroxide Free Radical Res. Commun. 1990, 10, 17-26
29. Shi, X.; Dalal, N. S.; Kasprzak, K. S. Generation of free radicals from hydrogen peroxide and lipid hydroperoxides in the presence of Cr(III) Arch. Biochem. Biophys. 1993, 302, 294-299
30. Codd, R.; Dillon, C. T.; Levina, A.; Lay, P. A. Studies on the genotoxicity of chromium: From the test tube to the cell Coord. Chem. Rev. 2001, 216, 537-582
31. Zhang, L.; Lay, P. A. EPR spectroscopic studies on the formation of chromium(V) peroxo complexes in the reaction of chromium(VI) with hydrogen peroxide Inorg. Chem. 1998, 37, 1729-1733
32. Perez-Benito, J. F.; Arias, C. A kinetic study of the chromium(VI)-hydrogen peroxide reaction. Role of the diperoxochromate(VI) intermediates J. Phys. Chem. A 1997, 101, 4726-4733
33. Stünzi, H.; Spiccia, L.; Rotzinger, F. P.; Marty, W. Early stages of the hydrolysis of chromium(III) in aqueous solution. 4. Stability constants of the hydrolytic dimer, trimer, and tetramer at 25 °C and I = 1.0 M Inorg. Chem. 1989, 28, 66-71
34. Stünzi, H.; Marty, W. Early stages of the hydrolysis of chromium(III) in aqueous solution. 1. Characterization of a tetrameric species Inorg. Chem. 1983, 22, 2145-2150
35. Rao, L.; Zhang, Z.; Friese, J. I.; Ritherdon, B.; Clark, S. B.; Hess, N. J.; Rai, D. Oligomerization of chromium(III) and its impact on the oxidation of chromium(III) by hydrogen peroxide in alkaline solutions J. Chem. Soc., Dalton Trans. 2002, 267-274
36. Szejtli, J. Introduction and general overview of cyclodextrin chemistry Chem. Rev. 1998, 98, 1743-1753
37. Norkus, E. Metal ion complexes with native cyclodextrins J. Inclusion Phenom. Macrocyclic Chem. 2009, 65, 237-248
38. McNamara, M.; Russell, N. R. FT-IR and Raman spectra of a series of metallo- β -cyclodextrin complexes J. Inclusion Phenom. Mol. Recogn. Chem. 1991, 10, 485-495
39. Stünzi, H.; Rotzinger, F. P.; Marty, W. Early stages of the hydrolysis of chromium(III) in aqueous solution. 2. Kinetics and mechanism of the interconversion between two tetrameric species Inorg. Chem. 1984, 23, 2160-2164
40. 2 J. Phys. Chem. A 2003, 107, 5722-5731
41. Lay, P. A. Recent developments on the mechanisms of substitution reactions of octahedral coordination complexes Coord. Chem. Rev. 1991, 110, 213-233
42. Xu, F.-C.; Krouse, R.; Swaddle, T. W. Conjugate base pathway for water exchange on aqueous chromium(III): Variable-pressure and -temperature kinetic study Inorg. Chem. 1985, 24, 267-270
43. Espenson, J. H. Formation rates of monosubstituted chromium(III) complexes in aqueous solution Inorg. Chem. 1969, 8, 1554-1556
44. Crimp, S. J.; Spiccia, L.; Krouse, H. R.; Swaddle, T. W. Early stages of the hydrolysis of chromium(III) in aqueous solution. 9. Kinetics of water exchange on the hydrolytic dimer Inorg. Chem. 1994, 33, 465-470
45. 2 Geochim. Cosmochim. Acta 2008, 72, 5692-5707