Natural gas hydrate formation and decomposition in the presence of kinetic inhibitors. 2. Stirred reactor experiments

Energy and Fuels

Volumn 25, Issue 10, 2011, Pages 4384-4391

  Daraboina, Nagu ^a   Linga, Praveen ^a,b   Ripmeester, John ^c   Walker, Virginia K ^d   Englezos, Peter ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^b NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

^c NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^d QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFREEZE PROTEIN; DECOMPOSITION KINETICS; HYDRATE DECOMPOSITION; HYDRATE FORMATION; HYDRATE INHIBITION; INDUCTION TIME; KINETIC INHIBITOR; POLYVINYL PYRROLIDONE; SINGLE STAGE; STIRRED REACTORS; TWO STAGE; WATER CONTROL;

EXPERIMENTS; GAS HYDRATES; HYDRATION; IODINE; KINETICS; PROTEINS;

DECOMPOSITION;

EID: 80054915558     PISSN: 08870624     EISSN: 15205029     Source Type: Journal    
DOI: 10.1021/ef200813v     Document Type: Article

References (45)

1. Sloan, E. D. and Koh, C. A. Clathrate Hydrates of Natural Gases, 3rd ed.; CRC Press, Taylor & Francis Group: New York, 2008.
2. Sloan, E. D. Clathrate Hydrates of Natural Gases; Marcel-Dekker, Inc.: New York, 1998; p 664.
3. Freer, E.; Sloan, E. D. An engineering approach to kinetic inhibitor design using molecular dynamics simulations Ann. N. Y. Acad. Sci. 2000, 912, 651
4. Kelland, M. A. History of the development of low dosage hydrate inhibitors Energy Fuels 2006, 20 (3) 825-847 (Pubitemid 43984703)
5. Walker, V. K.; Zeng, H.; Gordienko, R.; Kuiper, M. J.; Huva, E. I.; Ripmeester, J. A. The mysteries of memory effect and its elimination with antifreeze proteins. Proceedings of 6th International Conference on Gas Hydrates, Vancouver, July 2008.
6. Zeng, H.; Moudrakovski, I. L.; Ripmeester, J. A.; Walker, V. K. Effect of antifreeze protein on nucleation, growth and memory of gas hydrates AIChE J. 2006, 52 (9) 3304-3309 (Pubitemid 44368713)
7. Zeng, H.; Wilson, L. D.; Walker, V. K.; Ripmeester, J. A. The inhibition of tetrahydrofuran clathrate-hydrate formation with antifreeze protein Can. J. Phys. 2003, 81 (1-2) 17-24
8. Zeng, H.; Wilson, L. D.; Walker, V. K.; Ripmeester, J. A. Effect of antifreeze proteins on the nucleaton, growth, and the memory effect during tetrahydrofuran clathrate hydrate formation J. Am. Chem. Soc. 2006, 128 (9) 2844-2850
9. Al-Adel, S.; Dick, J. A. G.; El-Ghafari, R.; Servio, P. The effect of biological and polymeric inhibitors on methane gas hydrate growth kinetics Fluid Phase Equilib. 2008, 267 (1) 92-98
10. Ohno, H.; Susilo, R.; Gordienko, R.; Ripmeester, J.; Walker, V. K. Interaction of antifreeze proteins with hydrocarbon hydrates Chem.-Eur. J. 2010, 16 (34) 10409-10417
11. Yeh, Y.; Feeney, R. E. Antifreeze proteins: structures and mechanisms of function Chem. Rev. 1996, 96 (2) 601-617
12. Davies, P. L.; Baardsnes, J.; Kuiper, M. J.; Walker, V. K. Structure and function of antifreeze proteins Philos. Trans. R. Soc. London 2002, 357 (1423) 927-933
13. Jensen, L.; Thomsen, K.; von Solms, N. Inhibition of structure I and II gas hydrates using synthetic and biological kinetic inhibitors Energy Fuels 2011, 25, 17-23
14. Seo, Y.; Kang, S. P.; Jang, W. Structure and composition analysis of natural gas hydrates: C-13 NMR spectroscopic and gas uptake measurements of mixed gas hydrates J. Phys. Chem. A 2009, 113 (35) 9641-9649
15. Uchida, T.; Takeya, S.; Kamata, Y.; Ohmura, R.; Narita, H. Spectroscopic measurements on binary, ternary, and quaternary mixed-gas molecules in clathrate structures Ind. Eng. Chem. Res. 2007, 46 (14) 5080-5087 (Pubitemid 47116502)
16. Kumar, R.; Linga, P.; Moudrakovski, I.; Ripmeester, J. A.; Englezos, P. Structure and kinetics of gas hydrates from methane/ethane/propane mixtures relevant to the design of natural gas hydrate storage and transport facilities AIChE J. 2008, 54 (8) 2132-2144
17. Rydzy, M. B.; Schicks, J. M.; Naumann, R.; Erzinger, J. Dissociation enthalpies of synthesized multicomponent gas hydrates with respect to the guest composition and cage occupancy J. Phys. Chem. B 2007, 111 (32) 9539-9545 (Pubitemid 47317881)
18. Nihous, G. C.; Kuroda, K.; Lobos-Gonzalez, J. R.; Kurasaki, R. J.; Masutani, S. M. An analysis of gas hydrate dissociation in the presence of thermodynamic inhibitors Chem. Eng. Sci. 2010, 65 (5) 1748-1761
19. Bruusgaard, H.; Lessard, L. D.; Servio, P. Morphology Study of Structure I Methane Hydrate Formation and Decomposition of Water Droplets in the Presence of Biological and Polymeric Kinetic Inhibitors Cryst. Growth Des. 2009, 9 (7) 3014-3023
20. Nakagawa, R.; Akihiro, H.; Shoji, H. Dissociation and specific heats of gas hydrates under submarine and sublacustrine environments. Proceedings of 6th International Conference on Gas Hydrates, Vancouver, July 2008.
21. Vysniauskas, A.; Bishnoi, P. R. A Kinetic-Study of Methane Hydrate Formation Chem. Eng. Sci. 1983, 38 (7) 1061-1072
22. Englezos, P.; Kalogerakis, N.; Dholabhai, P. D.; Bishnoi, P. R. Kinetics of formation of methane and ethane gas hydrates Chem. Eng. Sci. 1987, 42 (11) 2647-2658 (Pubitemid 18531907)
23. Englezos, P.; Kalogerakis, N.; Dholabhai, P. D.; Bishnoi, P. R. Kinetics of gas hydrate formation from mixtures of methane and ethane Chem. Eng. Sci. 1987, 42 (11) 2659-2666 (Pubitemid 18531908)
24. Cohen, J. M.; Wolf, P. F.; Young, W. D. Enhanced hydrate inhibitors: powerful synergism with glycol ethers Energy Fuels 1998, 12 (2) 216-218 (Pubitemid 128545386)
25. McCallum, S. D.; Riestenberg, D. E.; Zatsepina, O. Y.; Phelps, T. J. Effect of pressure vessel size on the formation of gas hydrates J. Pet. Sci. Eng. 2007, 56 (1-3) 54-64 (Pubitemid 46488680)
26. Linga, P.; Kumar, R.; Englezos, P. Gas hydrate formation from hydrogen/carbon dioxide and nitrogen/carbon dioxide gas mixtures Chem. Eng. Sci. 2007, 62 (16) 4268-4276 (Pubitemid 47058447)
27. Daraboina, N.; Ripmeester, J. A.; Walker, V. K.; Englezos, P. Natural gas hydrate formation and decomposition in the presence of kinetic inhibitors. 1. High pressure calorimetry. Energy Fuels 2011, DOI: 10:10.21/ef200812m.
28. Englezos, P. Nucleation and Growth of Gas Hydrate Crystals in Relation to "Kinetic Inhibition Rev. IFP 1996, 51 (6) 789
29. Moon, C.; Taylor, P. C.; Rodger, P. M. Computer modelling of gas hydrate formation. Proceedings of the 4th International Conference on Gas Hydrates, Yokohama, Japan, May 19-23, 2002; pp 665-668.
30. Moon, C.; Taylor, P. C.; Rodger, P. M. Molecular dynamics study of gas hydrate formation J. Am. Chem. Soc. 2003, 125 (16) 4706-4707 (Pubitemid 36505353)
31. Kumar, R.; Lee, J. D.; Song, M.; Englezos, P. Kinetic inhibitor effects on methane/propane clathrate hydrate-crystal growth at the gas/water and water/ n -heptane interfaces J. Cryst. Growth 2008, 310 (6) 1154-1166
32. Carstensen, A.; Creek, J. L.; Koh, C. A. Investigating the performance of clathrate hydrate inhibitors using in situ Raman spectroscopy and differential scanning calorimetry Am. Mineral. 2004, 89 (8-9) 1215-1220 (Pubitemid 39174491)
33. King, H. E., Jr.; Hutter, J. L.; Lin, M. Y.; Sun, T. Polymer conformations of gas-hydrate kinetic inhibitors: a small-angle neutron scattering study J. Chem. Phys. 2000, 112 (5) 2523-2532
34. Anderson, B. J.; Tester, J. W.; Borghi, G. P.; Trout, B. L. Properties of inhibitors of methane hydrate formation via molecular dynamics simulations J. Am. Chem. Soc. 2005, 127, 17852-17862 (Pubitemid 43003397)
35. Gordienko, R.; Ohno, H.; Singh, V. K.; Jia, Z. C.; Ripmeester, J. A.; Walker, V. K. Towards a green hydrate inhibitor: imaging antifreeze proteins on clathrates PLoS ONE 2010, 5 (2) e8953
36. Kvamme, B.; Kuznetsova, T.; Aasoldsen, K. Molecular dynamics simulations for selection of kinetic hydrate inhibitors J. Mol. Graphics Modell. 2005, 23 (6) 524-536 (Pubitemid 40800756)
37. Wathen, B.; Kwan, P.; Jia, Z. C.; Walker, V. K. Modeling the interactions between poly(n -vinylpyrrolidone) and gas hydrates: factors involved in suppressing and accelerating hydrate growth. In High Performance Computing Systems and Applications; Kent, R. D.; Sands, T. W., Eds.; Kluwer Academic Publishers: Norwell, MA, 2010; Vol. 5976, pp 117-133, 418.
38. Daraboina, N. Understanding the action of gas hydrate kinetic inhibitors. Ph.D Dossier, University of British Columbia, 2011.
39. Makogon, Y. F.; Holditch, S. A. Gas hydrates-conclusion: experiments illustrate hydrate: morphology, kinetics Oil Gas J. 2001, 99 (7) 45-50
40. Makogon, Y. F.; Holditch, S. A. Lab work clarifies gas hydrate formation, dissociation Oil Gas J. 2001, 99 (6) 47-48
41. 50-52.
42. Lee, J. D.; Englezos, P. Unusual kinetic inhibitor effects on gas hydrate formation Chem. Eng. Sci. 2006, 61 (5) 1368-1376 (Pubitemid 43071236)
43. Subramanian, S. Measurements of clathrate hydrates containing methane and ethane using Raman spectroscopy. Ph.D. Thesis, Colorado School of Mines, Golden, CO, 2000.
44. Schicks, J. M.; Naumann, R.; Erzinger, J.; Hester, K. C.; Koh, C. A.; Sloan, E. D. Phase transitions in mixed gas hydrates: experimental observations versus calculated data J. Phys. Chem. B 2006, 110 (23) 11468-11474 (Pubitemid 43999516)
45. Daraboina, N.; Ripmeester, J. A.; Walker, V. K.; Englezos, P. Natural gas hydrate formation and decomposition in the presence of kinetic inhibitors. 3. Structural and compositional changes. Energy Fuels 2011, DOI: 10.1021/ef200814z.