A silanol protection mechanism: Understanding the decomposition behavior of surfactants in mesostructured solids

Journal of Materials Research

Volumn 26, Issue 6, 2011, Pages 804-814

  Pan, Dahai ^a   Zhao, Lingzhi ^b   Qian, Kun ^b   Tan, Lei ^b   Zhou, Liang ^b   Zhang, Jun ^b   Huang, Xiaodan ^b   Fan, Yu ^a   Liu, Haiyan ^a   Yu, Chengzhong ^b,c   Bao, Xiaojun ^a  

^a CHINA UNIVERSITY OF PETROLEUM   (China)

^b FUDAN UNIVERSITY   (China)

^c UNIVERSITY OF QUEENSLAND   (Australia)

Author keywords

Porosity; Self assembly; Sol gel

Indexed keywords

ACIDIC SOLUTIONS; BLOCK COPOLYMER TEMPLATES; DECOMPOSITION BEHAVIORS; DECOMPOSITION MECHANISM; FOURIER TRANSFORM INFRARED SPECTROMETRY; HIGH TEMPERATURE; HIGH VACUUM; HIGHER TEMPERATURES; HYDROGEN BONDING INTERACTIONS; HYDROTHERMAL TREATMENTS; INORGANIC-ORGANIC; MAGIC ANGLE SPINNING NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; MESOSTRUCTURED; PROTECTION MECHANISMS; SELF-ASSEMBLED; SILANOLS;

BLOCK COPOLYMERS; COPOLYMERIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; HYDROGEN; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PYROLYSIS; RESONANCE; SURFACE ACTIVE AGENTS;

THERMOGRAVIMETRIC ANALYSIS;

EID: 80054904388     PISSN: 08842914     EISSN: 20445326     Source Type: Journal    
DOI: 10.1557/jmr.2010.98     Document Type: Article

References (50)

1. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, and J. S. Beck: Ordered mesoporous molecular-sieves synthesized by a liquid-crystal template mechanism. Nature. 359, 710 (1992).
2. J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, and J. L. Schlenker: A new family of mesoporous molecular-sieves prepared with liquid-crystal templates. J. Am. Chem. Soc. 114, 10834 (1992).
3. A. Corma: From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem. Rev. 97, 2373 (1997).
4. K. Ariga, A. Vinu, J. P. Hill, and T. Mori: Coordination chemistry and supramolecular chemistry in mesoporous nanospace. Coord. Chem. Rev. 251, 2562 (2007).
5. Y. Wan, Y. F. Shi, and D. Y. Zhao: Designed synthesis of mesoporous solids via nonionic-surfactant-templating approach. Chem. Commun. (Camb.). 897 (2007).
6. Y. S. Tao, H. Kanoh, L. Abrams, and K. Kaneko: Mesoporemodified zeolites: Preparation, characterization, and applications. Chem. Rev. 106, 896 (2006).
7. A. Sayari: Catalysis by crystalline mesoporous molecular sieves. Chem. Mater. 8, 1840 (1996).
8. S. Kuchibhatla, A. S. Karakoti, D. Bera, and S. Seal: One-dimensional nanostructured materials. Prog. Mater. Sci. 52, 699 (2007).
9. D. T. On, D. Desplantier-Giscard, C. Danumah, and S. Kaliaguine: Perspectives in catalytic applications of mesostructured materials. Appl. Catal. A 222, 299 (2001).
10. R. Srivastava, M. Choi, and R. Ryoo: Mesoporous materials with zeolite framework: Remarkable effect of the hierarchical structure for retardation of catalyst deactivation. Chem. Commun. (Camb.). 4489 (2006).
11. Y. Wan and D. Y. Zhao: On the controllable soft-templating approach to mesoporous silicates. Chem. Rev. 107, 2821 (2007).
12. A. Taguchi and F. Schuth: Ordered mesoporous materials in catalysis. Microporous Mesoporous Mater. 77, 1 (2005).
13. S. A. Bagshaw, E. Prouzet, and T. J. Pinnavaia: Templating of mesoporous molecular-sieves by nonionic polyethylene oxide surfactants. Science. 269, 1242 (1995).
14. G. S. Attard, J. C. Glyde, and C. G. Goltner: Liquid-crystalline phases as templates for the synthesis of mesoporous silica. Nature. 378, 366 (1995).
15. D. Y. Zhao, J. L. Feng, Q. S. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka, and G. D. Stucky: Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science. 279, 548 (1998).
16. D. Y. Zhao, Q. S. Huo, J. L. Feng, B. F. Chmelka, and G. D. Stucky: Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J. Am. Chem. Soc. 120, 6024 (1998).
17. Y. Han and J. Y. Ying: Generalized fluorocarbon-surfactantmediated synthesis of nanoparticles with various mesoporous structures. Angew. Chem. Int. Ed. 44, 288 (2005).
18. Y. Han, D. F. Li, L. Zhao, J. W. Song, X. Y. Yang, N. Li, Y. Di, C. J. Li, S. Wu, X. Z. Xu, X. J. Meng, K. F. Lin, and F. S. Xiao: Hightemperature generalized synthesis of stable ordered mesoporous silica-based materials by using fluorocarbon-hydrocarbon surfactant mixtures. Angew. Chem. Int. Ed. 42, 3633 (2003).
19. X. Y. Liu, B. Z. Tian, C. Z. Yu, F. Gao, S. H. Xie, B. Tu, R. C. Che, L. M. Peng, and D. Y. Zhao: Room-temperature synthesis in acidic media of large-pore three-dimensional bicontinuous mesoporous silica with Ia3d symmetry. Angew. Chem. Int. Ed. 41, 3876 (2002).
20. F. Kleitz, S. H. Choi, and R. Ryoo: Cubic Ia3d large mesoporous silica: Synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes. Chem. Commun. (Camb.). 2136 (2003).
21. T. W. Kim, F. Kleitz, B. Paul, and R. Ryoo: MCM-48-like large mesoporous silicas with tailored pore structure: Facile synthesis domain in a ternary triblock copolymer-butanol-water system. J. Am. Chem. Soc. 127, 7601 (2005).
22. J. Fan, C. Z. Yu, T. Gao, J. Lei, B. Z. Tian, L. M. Wang, Q. Luo, B. Tu, W. Z. Zhou, and D. Y. Zhao: Cubic mesoporous silica with large controllable entrance sizes and advanced adsorption properties. Angew. Chem. Int. Ed. 42, 3146 (2003).
23. S. S. Kim, A. Karkamkar, T. J. Pinnavaia, M. Kruk, and M. Jaroniec: Synthesis and characterization of ordered, very large pore MSU-H silicas assembled from water-soluble silicates. J. Phys. Chem. B. 105, 7663 (2001).
24. C. L. Li, Y. Q. Wang, Y. L. Guo, X. H. Liu, Y. Guo, Z. G. Zhang, Y. S. Wang, and G. Z. Lu: Synthesis of highly ordered, extremely hydrothermal stable SBA-15/Al-SBA-15 under the assistance of sodium chloride. Chem. Mater. 19, 173 (2007).
25. D. F. Li, Y. Han, H. W. Song, L. Zhao, X. Z. Xu, Y. Di, and F. S. Xiao: High-temperature synthesis of stable ordered mesoporous silica materials by using fluorocarbon-hydrocarbon surfactant mixtures. Chemistry. 10, 5911 (2004).
26. C. Y. Wang, Y. C. Du, D. F. Li, X. G. Guan, F. Li, and F. S. Xiao: Design and synthesis of ordered mesoporous silica materials with high degree of silica condensation at high temperature from a mixture of polymer surfactant with small organic ammonium. J. Colloid Interface Sci. 319, 370 (2008).
27. N. Xiao, L. Wang, S. Liu, Y. C. Zou, C. Y. Wang, Y. Y. Ji, J. W. Song, F. Li, X. J. Meng, and F. S. Xiao: High-temperature synthesis of ordered mesoporous silicas from solo hydrocarbon surfactants and understanding of their synthetic mechanisms. J. Mater. Chem. 19, 661 (2009).
28. D. H. Pan, P. Yuan, L. Z. Zhao, N. A. Liu, L. Zhou, G. F. Wei, J. Zhang, Y. C. Ling, Y. Fan, B. Y. Wei, H. Y. Liu, C. Z. Yu, and X. J. Bao: New understanding and simple approach to synthesize highly hydrothermally stable and ordered mesoporous materials. Chem. Mater. 21, 5413 (2009).
29. S. Ruthstein, J. Schmidt, E. Kesselman, Y. Talmon, and D. Goldfarb: Resolving intermediate solution structures during the formation of mesoporous SBA-15. J. Am. Chem. Soc. 128, 3366 (2006).
30. A. Vinu, T. Mori, and K. Ariga: New families of mesoporous materials. Sci. Technol. Adv. Mater. 7, 753 (2006).
31. M. Imperor-Clerc, I. Grillo, A. Y. Khodakov, D. Durand, and V. L. Zholobenko: New insights into the initial steps of the formation of SBA-15 materials: An in situ small angle neutron scattering investigation. Chem. Commun. (Camb.). 834 (2007).
32. S. Ruthstein, V. Frydman, and D. Goldfarb: Study of the initial formation stages of the mesoporous material SBA-15 using spinlabeled block co-polymer templates. J. Phys. Chem. B. 108, 9016 (2004).
33. K. Flodstrom, C. V. Teixeira, H. Amenitsch, V. Alfredsson, and M. Linden: In situ synchrotron small-angle x-ray scattering/x-ray diffraction study of the formation of SBA-15 mesoporous silica. Langmuir. 20, 4885 (2004).
34. K. Flodstrom, H. Wennerstrom, and V. Alfredsson: Mechanism of mesoporous silica formation. A time-resolved NMR and TEM study of silica-block copolymer aggregation. Langmuir. 20, 680 (2004).
35. S. Ruthstein, V. Frydman, S. Kababya, M. Landau, and D. Goldfarb: Study of the formation of the mesoporous material SBA-15 by EPR spectroscopy. J. Phys. Chem. B. 107, 1739 (2003).
36. F. Berube and S. Kaliaguine: Calcination and thermal degradation mechanisms of triblock copolymer template in SBA-15 materials. Microporous Mesoporous Mater. 115, 469 (2008).
37. C. R. E. Mansur, G. Gonzalez, and E. F. Lucas: Calorimetry and thermogravimetry as tools for the assessment of the thermal stability of polyoxide-based nonionic surfactants. Polym. Degrad. Stab. 80, 579 (2003).
38. A. Coutinho, S. A. Quintella, A. S. Araujo, J. M. F. Barros, A. M. G. Pedrosa, V. J. Fernandes, and M. J. B. Souza: Thermogravimetry applied to characterization of SBA-15 nanostructured material. J. Therm. Anal. Calorim. 87, 457 (2007).
39. M. Kruk, M. Jaroniec, C. H. Ko, and R. Ryoo: Characterization of the porous structure of SBA-15. Chem. Mater. 12, 1961 (2000).
40. Y. K. Bae and O. H. Han: Removal of copolymer template from SBA-15 studied by H-1 MAS NMR. Microporous Mesoporous Mater. 106, 304 (2007).
41. J. L. Blin and C. Carteret: Investigation of the silanols groups of mesostructured silica prepared using a fluorinated surfactant: Influence of the hydrothermal temperature. J. Phys. Chem. C. 111, 14380 (2007).
42. 2. Microporous Mesoporous Mater. 96, 413 (2006).
43. J. Nawrocki: The silanol group and its role in liquid chromatography. J. Chromatogr. A. 779, 29 (1997).
44. B. Camarota, B. Onida, Y. Goto, S. Inagaki, and E. Garrone: Hydroxyl species in large-pore phenylene-bridged periodic mesoporous organosilica. Langmuir. 23, 13164 (2007).
45. T. I. Titova and L. S. Kosheleva: IR spectroscopic study of silica-triethylamine interaction. Colloids Surf. A 63, 97 (1992).
46. L. L. Hench and J. K. West: The sol-gel process. Chem. Rev. 90, 33 (1990).
47. J. Cihlar: Hydrolysis and polycondensation of ethyl silicates. 2. Hydrolysis and polycondensation of ETS40 (ethyl silicate-40). Colloids Surf., A 70, 253 (1993).
48. B. K. Coltrain and L. W. Kelts: The Chemistry of Hydrolysis and Condensation of Silica Sol-Gel Precursors (American Chemical Society, Washington, DC, 1994).
49. C. Boissiere, A. Larbot, C. Bourgaux, E. Prouzet, and C. A. Bunton: A study of the assembly mechanism of the mesoporous MSU-X silica two-step synthesis. Chem. Mater. 13, 3580 (2001).
50. F. Kleitz, W. Schmidt, and F. Schuth: Calcination behavior of different surfactant-templated mesostructured silica materials. Microporous Mesoporous Mater. 65, 1 (2003).