Petrological consequences of variations in metamorphic reaction affinity

Journal of Metamorphic Geology

Volumn 29, Issue 9, 2011, Pages 953-977

  Pattison, D R M ^a   de Capitani, C ^b   Gaidies, F ^a,c  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF BASEL   (Switzerland)

^c CARLETON UNIVERSITY   (Canada)

Author keywords

Kinetics; Metamorphic facies; Metamorphic reactions; Reaction affinity; Reaction overstepping

Indexed keywords

APPROACH TO EQUILIBRIUM; DEHYDRATION REACTIONS; DISCRETE INTERVALS; DRIVING FORCES; EQUILIBRIUM PHASE DIAGRAMS; FREE-ENERGY DIFFERENCE; HYDROUS PHASIS; KINETIC BARRIER; KINETIC EFFECT; METAMORPHIC FACIES; METAMORPHIC REACTIONS; MINERAL REACTIONS; NUCLEATION AND GROWTH; PER UNIT; REACTION AFFINITY; REACTION OVERSTEPPING; SECOND-ORDER FEATURES; THERMOBAROMETRY; THERMODYNAMIC DATA; THERMODYNAMICALLY STABLE;

DEHYDRATION; GROWTH KINETICS; KINETICS; METAMORPHIC ROCKS; METASTABLE PHASES; MICA; MINERALS; PETROLOGY; PHASE DIAGRAMS;

REACTION KINETICS;

DEHYDRATION; ENTROPY; GEOBAROMETRY; GIBBS FREE ENERGY; METAMORPHIC FACIES; NUCLEATION; P-T CONDITIONS; P-T-T PATH; PETROLOGY; PROGRADE METAMORPHISM; REACTION KINETICS;

EID: 80054035525     PISSN: 02634929     EISSN: 15251314     Source Type: Journal    
DOI: 10.1111/j.1525-1314.2011.00950.x     Document Type: Article

References (61)

1. Austrheim, H., 1987. Eclogitization of lower crustal granulites by fluid migration through shear zones. Earth and Planetary Science Letters, 81, 221-232.
2. Bell, T.H. & Hayward, N., 1991. Episodic metamorphic reactions during orogenesis - the control of deformation partitioning on reaction sites and reaction duration. Journal of Metamorphic Geology, 9, 619-640.
3. Buick, I.S., Stevens, G. & Gibson, R.L., 2004. The role of water retention in the anatexis of metapelites in the Bushveld Complex aureole, South Africa: an experimental study. Journal of Petrology, 45, 1777-1797.
4. de Capitani, C. & Brown, T.H., 1987. The computation of chemical equilibria in complex systems containing non-ideal solutions. Geochimica et Cosmochimica Acta, 51, 2639-2652.
5. de Capitani, C. & Petrakakis, K., 2010. The computation of equilibrium assemblage diagrams with Theriak/Domino software. American Mineralogist, 95, 1006-1016.
6. 2O activity as inferred from rates of intergranular diffusion of aluminum. Journal of Metamorphic Geology, 28, 735-752.
7. Connolly, J.A.D. & Cesare, B., 1993. C-O-H-S fluid compositions and oxygen fugacity in graphitic metapelites. Journal of Metamorphic Geology, 11, 379-388.
8. DeBuhr, C.L., 1999. Metamorphic Petrology and Mass Balance Analysis in the Bugaboo Contact Aureole. Doctoral Thesis, University of Calgary, Calgary, AB, Canada.
9. de Donder, T., 1922. Affinity. Bulletin of the Royal Academy of Belgium (Cl. Sc.) 7, 197, 205. Available at:.
10. de Donder, T., 1936. Thermodynamic Theory of Affinity: A Book of Principles. Oxford University Press, Oxford.
11. Eskola, P., 1915. On the relation between chemical and mineralogical composition in the metamorphic rocks in the Orijarvi region. Bulletin de la Commission Geologique de Finlande, 44, 167-225.
12. Evans, T.P., 2004. A method for calculating effective bulk composition modification due to crystal fractionation in garnet-bearing schist; implications for isopleth thermobarometry. Journal of Metamorphic Geology, 22, 547-557.
13. Ferry, J.M., 1980. A comparative study of geothermometers and geobarometers in pelitic schists from south-central Maine. American Mineralogist, 65, 720-732.
14. Ferry, J.M., 1988. Infiltration-driven metamorphism in northern New England, USA. Journal of Petrology, 29, 1121-1159.
15. Ferry, J.M., 1991. Dehydration and decarbonation reactions as a record of fluid infiltration. In: Contact Metamorphism (ed. Kerrick, D.M.), Mineralogical Society of America Reviews in Mineralogy, 26, 351-394.
16. Ferry, J.M., 1994. Role of fluid flow in the contact metamorphism of siliceous dolomitic limestones. American Mineralogist, 79, 719-736.
17. Ferry, J.M. & Gerdes, M.L., 1998. Chemically reactive fluid flow during metamorphism. Annual Review of Earth and Planetary Science, 26, 255-287.
18. Gaidies, F., Pattison, D.R.M. & de Capitani, C., 2011. Towards a quantitative model of metamorphic nucleation and growth. Contributions to Mineralogy and Petrology. doi:.
19. Ghent, E.D., 1975. Temperature, pressure and mixed volatile equilibria attending metamorphism of staurolite-kyanite-bearing assemblages, Esplanade Range, British Columbia. Geological Society of America Bulletin, 86, 1654-1660.
20. 2O in metamorphism and unexpected behavior in the preservation of metamorphic mineral assemblages. Journal of Metamorphic Geology, 19, 445-454.
21. Hillert, M., 1999. Solute drag, solute trapping and diffusional dissipation of Gibbs energy. Acta Materialia, 47, 4481-4505.
22. Hillert, M., 2008. Phase Equilibria, Phase Diagrams and Phase Transformations: Their Thermodynamic Basis, 2nd edn. Cambridge University Press, Cambridge.
23. Hillert, M. & Rettenmayr, M., 2003. Deviation from local equilibrium at migrating phase interfaces. Acta Materialia, 51, 2803-2809.
24. Holland, T.J.B. & Powell, R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, 309-344.
25. Holland, T.J.B. & Powell, R., 2003. Activity-composition relations for phases in petrological calculations: an asymmetric multicomponent formulation. Contributions to Mineralogy and Petrology, 145, 492-501.
26. Hudson, N.F.C., 1980. Regional metamorphism of some Dalradian pelites in the Buchan area, northeast Scotland. Contributions to Mineralogy and Petrology, 73, 39-51.
27. Kretz, R., 1983. Symbols for rock-forming minerals. American Mineralogist, 68, 277-279.
28. Lang, H.M. & Rice, J.M., 1985a. Metamorphism of pelitic rocks in the Snow Peak area, northern Idaho: sequence of events and regional implications. Bulletin of the Geological Society of America, 96, 731-736.
29. Lang, H.M. & Rice, J.M., 1985b. Regression modelling of metamorphic reactions in metapelites, Snow Peak, Northern Idaho. Journal of Petrology, 26, 857-887.
30. Lang, H.M. & Rice, J.M., 1985c. Geothermometry, geobarometry and T-X(Fe-Mg) relations in metapelites, Snow Peak, Northern Idaho. Journal of Petrology, 26, 889-924.
31. Lasaga, A.C., 1986. Metamorphic reaction rate laws and development of isograds. Mineralogical Magazine, 50, 359-373.
32. Lasaga, A.C., 1998. Kinetic Theory in the Earth Sciences. Princeton University Press, Princeton.
33. Lasaga, A.C. & Rye, D.M., 1993. Fluid flow and chemical reactions in metamorphic systems. American Journal of Science, 293, 361-404.
34. Manning, C.E., Ingebrisen, S.E. & Bird, D.K., 1993. Missing mineral zones in contact metamorphosed basalts. American Journal of Science, 293, 894-938.
35. Muller, T., Baumgartner, L.P., Foster, C.T. & Vennemann, T.W., 2004. Metastable prograde mineral reactions in contact aureoles. Geology, 32, 821-824.
36. Osberg, P.H., 1968. Stratigraphy, structural geology, and metamorphism of the Waterville-Vassalboro area, Maine. Maine Geological Survey Bulletin, 20, 64 pp.
37. 5 triple point: constraints from the Ballachulish aureole, Scotland. Journal of Geology, 100, 423-446.
38. Pattison, D.R.M., 2006. The fate of graphite in prograde metamorphism of pelites: an example from the Ballachulish aureole, Scotland. Lithos, 88, 85-99.
39. Pattison, D.R.M. & Tinkham, D.T., 2009. Interplay between equilibrium and kinetics in prograde metamorphism of pelites: an example from the Nelson aureole, British Columbia. Journal of Metamorphic Geology, 27, 249-279.
40. Pattison, D.R.M. & Tracy, R.J., 1991. Phase equilibria and thermobarometry of metapelites. In: Contact Metamorphism (ed. Kerrick, D.M.), Mineralogical Society of America Reviews in Mineralogy, 26, 105-206.
41. Pattison, D.R.M. & Vogl, J.J., 2005. Contrasting sequences of metapelitic mineral-assemblages in the aureole of the tilted Nelson Batholith, British Columbia: implications for phase equilibria and pressure determination in andalusite-sillimanite type settings. Canadian Mineralogist, 43, 51-88.
42. Pattison, D.R.M., Spear, F.S. & Cheney, J.Y., 1999. Polymetamorphic origin of muscovite + cordierite + staurolite + biotite assemblages: implications for the metapelitic petrogenetic grid and for P-T paths. Journal of Metamorphic Geology, 17, 685-703.
43. 2O: constraints from natural assemblages and implications for the metapelitic petrogenetic grid. Journal of Metamorphic Geology, 20, 99-118.
44. Powell, R. & Holland, T.J.B., 2008. On thermobarometry. Journal of Metamorphic Geology, 26, 155-179.
45. Prigogine, I. & Defay, R.F., 1954. Chemical Thermodynamics. Longmans Green, London.
46. Ridley, J. & Thompson, A.B., 1986. The role of mineral kinetics in the development of metamorphic microtextures. In: Fluid-Rock Interactions During Metamorphism (eds Walther, J.V. & Wood, B.J.), Advances in Physical Geochemistry, 5, Springer-Verlag, New York, 154-193.
47. Rubie, D.C., 1986. The catalysis of mineral reactions by water and restrictions on the presence of aqueous fluid during metamorphism. Mineralogical Magazine, 50, 399-415.
48. Rubie, D.C., 1998. Disequilibrium during metamorphism: the role of nucleation kinetics. In: What Drives Metamorphism and Metamorphic Reactions? (eds Treloar, P.J. & O'Brien, P.J.), Geological Society of London Special Publication, 138, 199-214.
49. Thompson, J.B., 1957. The graphical analysis of mineral assemblages in pelitic schists. American Mineralogist, 42, 842-858.
50. Thompson, A.B., 1976. Mineral reactions in pelitic rocks: I. Prediction of P-T-XFe-Mg phase relations. II. Calculation of some P-T-XFe-Mg phase relations. American Journal of Science, 276, 401-424.
51. Thompson, A.B., 1983. Fluid-absent metamorphism. Journal of the Geological Society of London, 140, 533-547.
52. Thompson, C.V. & Spaepen, F., 1983. Homogeneous crystal nucleation in binary metallic melts. Acta Metallurgica, 31, 2021-2027.
53. Tinkham, D.K. & Ghent, E.D., 2005. Estimating P-T conditions of garnet growth with isochemical phase diagram sections and the problem of effective bulk-composition. Canadian Mineralogist, 43, 35-50.
54. Vernon, R.H. & Powell, C.M., 1976. Porphyroblastesis and displacement - some new textural criteria from pelitic hornfels - reply. Mineralogical Magazine, 40, 787-788.
55. Vernon, R.H., White, R.W. & Clarke, G.L., 2008. False metamorphic events inferred from misinterpretation of microstructural evidence and P-T data. Journal of Metamorphic Geology, 26, 437-449.
56. Walther, J.V. & Wood, B.J., 1984. Rate and mechanism in prograde metamorphism. Contributions to Mineralogy and Petrology, 88, 246-259.
57. Waters, D.J., 1990. Nucleation and overstepping in prograde metamorphic reactions. In: Abstracts Volume: Textures in Metamorphic Rocks Conference, University of Manchester, England.
58. Waters, D.J., 2010. Equilibrium calculation and real metamorphic process - scenes from a troubled relationship. In: Abstracts Volume: Interplay Between Thermodynamics, Kinetics and Deformation in Metamorphism Symposium; GeoCanada 2010 Conference, Calgary, Alberta.
59. Waters, D.J. & Lovegrove, D.P., 2002. Assessing the extent of disequilibrium and overstepping of prograde metamorphic reactions in metapelites from the Bushveld Complex aureole, South Africa. Journal of Metamorphic Geology, 20, 135-149.
60. Wilbur, D.E. & Ague, J.J., 2006. Chemical disequilibrium during garnet growth: Monte Carlo simulations of natural crystal morphologies. Geology, 34, 689-692.
61. Zeh, A. & Holness, M.B., 2003. The effect of reaction overstep on garnet microtextures in metapelitic rocks of the Ilesha Schist Belt, SW Nigeria. Journal of Petrology, 44, 967-994.