Insights into the mechanism of photocatalytic water reduction by DFT-supported in situ EPR/Raman spectroscopy

Angewandte Chemie - International Edition

Volumn 50, Issue 43, 2011, Pages 10246-10250

  Hollmann, Dirk ^a   Gärtner, Felix ^a   Ludwig, Ralf ^a   Barsch, Enrico ^a   Junge, Henrik ^a   Blug, Matthias ^b   Hoch, Sascha ^b   Beller, Matthias ^a   Brückner, Angelika ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b EVONIK DEGUSSA GMBH   (Germany)

Author keywords

density functional calculations; EPR spectroscopy; iron; photocatalytic water splitting; Raman spectroscopy

Indexed keywords

EPR SPECTROSCOPY; IN-SITU; PHOTO-CATALYTIC; PHOTOCATALYTIC WATER SPLITTING; TRIETHYLAMINES; WATER REDUCTION;

IRIDIUM; PARAMAGNETIC RESONANCE; PHOTOSENSITIZERS; RAMAN SPECTROSCOPY;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

EID: 80054035344     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201103710     Document Type: Article

References (52)

1. Q. Schiermeier, J. Tollefson, T. Scully, A. Witze, O. Morton, Nature 2008, 454, 816
2. N. Armaroli, V. Balzani, Angew. Chem. 2007, 119, 52
3. Angew. Chem. Int. Ed. 2007, 46, 52.
4. M. Kitano, M. Hara, J. Mater. Chem. 2010, 20, 627
5. A. Kudo, Y. Miseki, Chem. Soc. Rev. 2009, 38, 253
6. L. L. Tinker, N. D. McDaniel, S. Bernhard, J. Mater. Chem. 2009, 19, 3328
7. Y. Inoue, Energy Environ. Sci. 2009, 2, 364
8. F. E. Osterloh, Chem. Mater. 2008, 20, 35.
9. J. Zhang, J. Sun, K. Maeda, K. Domen, P. Liu, M. Antonietti, X. Fu, X. Wang, Energy Environ. Sci. 2011, 4, 675
10. K. Maeda, A. Xiong, T. Yoshinaga, T. Ikeda, N. Sakamoto, T. Hisatomi, M. Takashima, D. Lu, M. Kanehara, T. Setoyama, T. Teranishi, K. Domen, Angew. Chem. 2010, 122, 4190
11. Angew. Chem. Int. Ed. 2010, 49, 4096
12. K. Maeda, M. Higashi, D. Lu, R. Abe, K. Domen, J. Am. Chem. Soc. 2010, 132, 5858.
13. G. Armstrong, Nat. Chem. 2010, DOI
14. Z. Chen, J. J. Concepcion, H. Luo, J. F. Hull, A. Paul, T. J. Meyer, J. Am. Chem. Soc. 2010, 132, 17670
15. W. C. Ellis, N. D. McDaniel, S. Bernhard, T. J. Collins, J. Am. Chem. Soc. 2010, 132, 10990
16. D. J. Wasylenko, C. Ganesamoorthy, B. D. Koivisto, M. A. Henderson, C. P. Berlinguette, Inorg. Chem. 2010, 49, 2202
17. J. J. Concepcion, J. W. Jurss, M. R. Norris, Z. Chen, J. L. Templeton, T. J. Meyer, Inorg. Chem. 2010, 49, 1277
18. L. Duan, Y. Xu, P. Zhang, M. Wang, L. Sun, Inorg. Chem. 2010, 49, 209
19. J. F. Hull, D. Balcells, J. D. Blakemore, C. D. Incarvito, O. Eisenstein, G. W. Brudvig, R. H. Crabtree, J. Am. Chem. Soc. 2009, 131, 8730.
20. F. Gärtner, D. Cozzula, S. Losse, A. Boddien, G. Anilkumar, H. Junge, T. Schulz, N. Marquet, A. Spannenberg, S. Gladiali, M. Beller, Chem. Eur. J. 2011, 17, 6998
21. J. D. Knoll, S. M. Arachchige, K. J. Brewer, ChemSusChem 2011, 4, 252
22. T. M. McCormick, B. D. Calitree, A. Orchard, N. D. Kraut, F. V. Bright, M. R. Detty, R. Eisenberg, J. Am. Chem. Soc. 2010, 132, 15480
23. P. Zhang, M. Wang, Y. Na, X. Li, Y. Jiang, L. Sun, Dalton Trans. 2010, 39, 1204
24. D. Streich, Y. Astuti, M. Orlandi, L. Schwartz, R. Lomoth, L. Hammarström, S. Ott, Chem. Eur. J. 2010, 16, 60
25. B. Probst, A. Rodenberg, M. Guttentag, P. Hamm, R. Alberto, Inorg. Chem. 2010, 49, 6453
26. M. Wang, Y. Na, M. Gorlov, L. Sun, Dalton Trans. 2009, 6458.
27. L. L. Tinker, S. Bernhard, Inorg. Chem. 2009, 48, 10507
28. P. N. Curtin, L. L. Tinker, C. M. Burgess, E. D. Cline, S. Bernhard, Inorg. Chem. 2009, 48, 10498
29. E. D. Cline, S. E. Adamson, S. Bernhard, Inorg. Chem. 2008, 47, 10378
30. L. L. Tinker, N. D. McDaniel, P. N. Curtin, C. K. Smith, M. J. Ireland, S. Bernhard, Chem. Eur. J. 2007, 13, 8726
31. J. I. Goldsmith, W. R. Hudson, M. S. Lowry, T. H. Anderson, S. Bernhard, J. Am. Chem. Soc. 2005, 127, 7502.
32. F. Gärtner, B. Sundararaju, A.-E. Surkus, A. Boddien, B. Loges, H. Junge, P. H. Dixneuf, M. Beller, Angew. Chem. 2009, 121, 10147
33. Angew. Chem. Int. Ed. 2009, 48, 9962.
34. F. Gärtner, A. Boddien, E. Barsch, K. Fumino, S. Losse, H. Junge, D. Hollmann, A. Brückner, R. Ludwig, M. Beller, Chem. Eur. J. 2011, 17, 6425.
35. .+:, W. Miao, J.-P. Choi, A. J. Bard, J. Am. Chem. Soc. 2002, 124, 14478.
36. 4:, W. Liu, S. Yamanaka, M. Shiotani, J. Michalik, A. Lund, Phys. Chem. Chem. Phys. 2001, 3, 1611.
37. J.-M. Lu, D. Beckert, Res. Chem. Intermed. 2000, 26, 621
38. J. Säuberlich, O. Brede, D. Beckert, J. Phys. Chem. A 1997, 101, 5659.
39. S. Dobos, S. Nunziante-Cesaro, M. Maltese, Inorg. Chim. Acta 1986, 113, 167.
40. Review:, Y. A. Belousov, Russ. Chem. Rev. 2007, 76, 41.
41. 18CO labels was described by Krusic et al.
42. P. J. Krusic, J. S. Filippo, Jr., B. B. Hutchinson, R. L. Hance, L. M. Daniels, J. Am. Chem. Soc. 1981, 103, 2129
43. P. J. Krusic, J. Am. Chem. Soc. 1981, 103, 2131.
44. S. Onaka, D. F. Shriver, Inorg. Chem. 1976, 15, 915.
45. 12] only at 10 K:, C. B. Cooper III, S. Onaka, D. F. Shriver, L. Daniels. R. L. Hance, B. Hutchinson, R. Shipley, Inorg. Chim. Acta 1977, 24, L92.
46. W. McFarlane, G. Wilkinson, W. Hübel, Inorg. Synth. 1966, 8, 181.
47. Y. A. Belousov, Russ. Chem. Bull. 1997, 46, 1010.
48. Sim14S program: G. P. Lozos, B. M. Hoffman, C. G. Franz, Quantum Chemistry, Programs Exchange 1973, no. 265.
49. Gaussian 03 (RevisionD.01), M. J. Frisch, et al. Gaussian Inc., Wallingford, CT, 2004, see the Supporting Information.
50. A. B. Becke, J. Chem. Phys. 1993, 98, 5648
51. J. P. Perdew, Y. Wang, Phys. Rev. B 1992, 45, 13244.
52. J. P. Merrick, D. Moran, L. Radom, J. Phys. Chem. A 2007, 111, 11683.