Effect of deactivation and reactivation of palladium anode catalyst on performance of direct formic acid fuel cell (DFAFC)

International Journal of Hydrogen Energy

Volumn 36, Issue 22, 2011, Pages 14719-14724

  Baik, S M ^a   Han, Jonghee ^b   Kim, Jinsoo ^a   Kwon, Yongchai ^c  

^a Kyung Hee University   (South Korea)

^b Korea Institute of Science and Technology   (South Korea)

^c Seoul National University of Science and Technology   (South Korea)

Author keywords

ATR FTIR; Direct formic acid fuel cell; Palladium deactivation; Palladium electroredox reaction; Palladium reactivation

Indexed keywords

ANODE CATALYSTS; ATR FTIR; CATALYST COATED MEMBRANES; CATHODE CATALYST; CELL PERFORMANCE; CONTINUOUS PRODUCTION; DIRECT FORMIC ACID FUEL CELLS; NAFION MEMBRANE; SINGLE CELLS;

CYCLIC VOLTAMMETRY; ELECTROOXIDATION; EXPERIMENTS; FORMIC ACID; FORMIC ACID FUEL CELLS (FAFC); PLATINUM; REDOX REACTIONS;

CATALYST DEACTIVATION;

EID: 80054019137     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.04.181     Document Type: Article

References (34)

1. C. Rice, S. Ha, R.I. Masel, P. Waszczuk, A. Wieckowski, and T. Barnard Direct formic acid fuel cells J Power Sourc 111 2002 83
2. X. Yu, and P.G. Pickup Recent advances in direct formic acid fuel cells J Power Sourc 182 2008 124
3. Y. Kwon, S. Back, B. Kwon, J. Kim, and J. Han Evaluation of direct formic acid fuel cells with catalysis layers coated by electrospray Korean J Chem Eng 27 2010 836
4. J.H. Choi, K.J. Jeong, Y. Dong, J.H. Han, T.H. Im, and J.S. Lee Electro-oxidation of methanol and formic acid on PtRu and PtAu for direct formic acid fuel cells J Power Sourc 163 2006 71
5. C. Rice, S. Ha, R.I. Masel, and A. Wieckowski Catalysts of direct formic acid fuel cells J Power Sourc 115 2003 229
6. H. Choi, J. Kim, Y. Kwon, and J. Han Comparative study of three different catalyst coating methods for direct formic acid fuel cells J Power Sourc 195 2010 160
7. L.L. Zhang, T.H. Lu, J.C. Bao, Y.W. Tang, and C. Li Preparation method of an ultrafine carbon supported Pd catalyst as an anodic catalyst in a direct formic acid fuel cell Electrochem Commun 8 2006 1625
8. V. Neburchilov, J. Martin, H.J. Wang, and J.J. Zhang A review of polymer electrolyte membranes for direct methanol fuel cells J Power Sourc 169 2007 221
9. X.C. Zhou, W. Xing, C.P. Liu, and T.H. Lu Platinum-macrocycle co-catalyst for electro-oxidation of formic acid Electrochem Commun 9 2007 1469
10. W.S. Jung, J.H. Han, and S. Ha Analyst of palladium-based anode electrode using electrochemical impedance spectra in direct formic acid fuel cells J Power Sourc 173 2007 53
11. R. Larsen, S. Ha, J. Zakzeski, and R.I. Masel Unusually active palladium-based catalysts for the electrooxidation of formic acid J Power Sourc 157 2006 78
12. 4 at platinum electrodes J Electrochem Soc 140 1993 2559
13. M. Arenz, V. Stamenkovic, P.N. Ross, and N.M. Markovic Surface (electro-) chemistry on Pt (111) modified by a pseudomorphic Pd monolayer Surf Sci 573 2005 57
14. M.F. Mrozek, H. Luo, and M.J. Weaver Formic acid electrooxidation on platinum-group metals:Is adsorbed carbon monoxide solely a catalytic poison Langmuir 16 2000 8463
15. W.P. Zhou, A. Lewera, R. Larsen, R.I. Masel, and A. Wieckowski Size effects in electronic and catalytic properties of unsupported nanoparticles in electrooxidation of formic acid J Phys Chem B 110 2006 13393
16. Y. Pan, R. Zhang, and S.L. Blair Anode poisoning study in direct formic acid fuel cells Electrochem Solid State Lett 12 2009 B23
17. H. Miyake, T. Okada, G. Samjeske, and M. Osawa Formic acid electrooxidation on Pd in acidic solutions studied by surface enhanced infrared absorption spectroscopy Phys Chem Chem Phys 10 2008 3662
18. W. Zhou, and J.Y. Lee Particle size effects in Pd-catalyzed electrooxidation of formic acid J Phys Chem C 112 2008 3789
19. S. Ha, C. Rice, R. Masel, and A. Wieckowski Methanol conditioning for improved performance of formic acid fuel cells J Power Sourc 112 2002 655
20. D.A.J. Rand, and R. Woods The nature of adsorbed oxygen on rhodium, palladium and gold electrodes J Electroanal Chem 31 1971 29
21. M.W. Breiter Comparative voltammetric study of methanol oxidation and adsorption on noble metal electrodes in perchloric acid solutions Electrochim Acta 8 1963 973
22. A. Bolzan, M.E. Martins, and A.J. Arvia Thin layer voltammetry of palladium in acid electrolytes J Electroanal Chem 207 1986 279
23. G.L. Beltramo, T.E. Shubina, and M.T.M. Koper Oxidation of formic acid and carbon monoxide on gold electrodes studied by surface-enhanced Raman spectroscopy and DFT Chem Phys Chem 6 2005 2597
24. 4 in the potential range of oxygen electroadsorption-electrodesorption reactions J Electroanal Chem 157 1983 339
25. M.J. Weaver Electrostatic-field effects on adsorbate bonding and structure at metal surfaces: parallels between electrochemical and vacuum systems Appl Surf Sci 67 1993 147
26. G. Li, and P.G. Pickup Measurement of single electrode potentials and impedances in hydrogen and direct methanol PEM fuel cells Electrochim Acta 49 2004 4119
27. S. Uhm, S.T. Chung, and J. Lee Characterization of direct formic acid fuel cells by impedance studies: comparison of direct methanol fuel cells J Power Sourc 178 2008 34
28. K. Nakanishi, and P.H. Solomon Infrared absorption spectroscopy 2nd ed. 1977 Holden-Day, Inc Oakland
29. A. Garton Infrared spectroscopy of polymer blends, composites and surfaces 1992 Hanser Publishers New York
30. K. Ataka, T. Yotsuyanagi, and M. Osawa Potential-dependant reorientation of water molecules at a electrode/electrolyte interface studied by surface-enhanced infrared absorption spectroscopy J Phys Chem 100 1996 10664
31. A. Miki, S. Ye, and M. Osawa Surface-enhanced IR absorption on platinum nanoparticles: an application to real-time monitoring of electrocatalytic reactions Chem Comm 2002 1500
32. J.R. Schere Advances in infrared and Raman spectroscopy 1978
33. C.C. Hu, and T.C. Wen Voltammetric investigation of palladium oxides-I: their formation/reduction in NaOH Electrochim Acta 40 1995 495
34. H. Miyake, E. Hosono, M. Osawa, and T. Okada Surface-enhanced infrared absorption spectroscopy using chemically deposited Pd thin film electrodes Chem Phys Lett 428 2006 451