Formation and destruction of physical crosslinks by mild treatments in chemically crosslinked poly(vinyl alcohol) gels

Polymer Bulletin

Volumn 67, Issue 7, 2011, Pages 1215-1226

  Otsuka, Emiko ^a   Sugiyama, Masaaki ^b   Suzuki, Atsushi ^a  

^a YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

FT IR; Microcrystallite; Poly(vinyl alcohol) gel; SAXS; Swelling ratio; WAXS

Indexed keywords

FT-IR; MICROCRYSTALLITE; POLYVINYL ALCOHOL GELS; SAXS; SWELLING RATIO; WAXS;

ALDEHYDES; CROSSLINKING; DRYING; INFRARED IMAGING; WASHING;

GELS;

EID: 80053950968     PISSN: 01700839     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00289-011-0450-y     Document Type: Article

References (16)

1. T Tanaka 1981 Gels Sci Am 244 124 136 10.1038/scientificamerican0181-124 1:CAS:528:DyaL3MXntF2ktg%3D%3D
2. A Suzuki 1993 Phase transition in gels of sub-millimeter size induced by interaction with stimuli Adv Polym Sci 110 199 240 10.1007/BFb0021134 1:CAS:528:DyaK2cXlsFynsb0%3D
3. Finch CA (ed) (1997) Polyvinyl alcohol-developments, 2nd edn. Wiley, New Jersey
4. CM Hassan NA Peppas 2000 Structure and applications of poly(vinyl alcohol) hydrogels produced by conventional crosslinking or by freezing/thawing methods Adv Polym Sci 153 37 65 10.1007/3-540-46414-X-2 1:CAS:528: DC%2BD3cXnt1yju70%3D (Pubitemid 32373332)
5. S Kudo E Otsuka A Suzuki 2010 Swelling behavior of chemically crosslinked PVA gels in mixed solvents J Polym Sci B 48 1978 1986 10.1002/polb.22076 1:CAS:528:DC%2BC3cXpvFWhs7c%3D
6. E Otsuka S Kudo M Sugiyama A Suzuki 2011 Effects of microcrystallites on swelling behavior in chemically crosslinked poly(vinyl alcohol) gels J Polym Sci B 49 96 102 10.1002/polb.22161 1:CAS:528:DC%2BC3cXhsFOjsrvI
7. CW Bunn 1948 Crystal structure of polyvinyl alcohol Nature 161 929 930 10.1038/161929a0 1:CAS:528:DyaH1MXhtFY%3D
8. E Otsuka A Suzuki 2009 A simple method to obtain a swollen PVA gel crosslinked by hydrogen bonds J Appl Polym Sci 114 10 16 10.1002/app.30546 1:CAS:528:DC%2BD1MXosVGqsLk%3D
9. HS Costa MF Rocha GI Andrade EF Barbosa-Stancioli MM Pereira RL Orefice WL Vasconcelos HS Mansur 2008 Sol-gel derived composite from bioactive glass-polyvinyl alcohol J Mater Sci 43 494 502 10.1007/s10853-007-1875-4 1:CAS:528:DC%2BD2sXhsVaqurfN (Pubitemid 350275896)
10. 2+ ions doped polyvinylalcohol films Polymer 45 5407 5415 10.1016/j.polymer.2004.05.068 1:CAS:528: DC%2BD2cXmtFKlurc%3D (Pubitemid 39090946)
11. 4SCN gel electrolytes Solid State Ion 178 951 958 10.1016/j.ssi.2007.04.001 1:CAS:528:DC%2BD2sXmsFCjs7o%3D (Pubitemid 46891099)
12. S Yi W Peiyi 2003 Two-dimensional ATR-FTIR spectroscopic investigation on water diffusion in polypropylene film: Water bending vibration J Phys Chem B 107 4224 4226 10.1021/jp0269975
13. M Miya R Iwamoto S Mima 1984 FT-IR study of intermolecular interactions in polymer blends J Polym Sci B 22 1149 1151 1:CAS:528:DyaL2cXktl2itrc%3D (Pubitemid 14620748)
14. J Lee KJ Lee J Jang 2008 Effect of silica nanofillers on isothermal crystallization of poly(vinyl alcohol): in situ ATR-FTIR study Polym Test 27 360 367 10.1016/j.polymertesting.2007.12.005 1:CAS:528:DC%2BD1cXksFygt7g%3D
15. HS Mansur CM Sadahira AN Souza AAP Mansur 2008 FTIR spectroscopy characterization of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde Mat Sci Eng C 28 539 548 10.1016/j.msec.2007.10.088 1:CAS:528:DC%2BD1cXjvF2rtro%3D (Pubitemid 351417808)
16. SK Mallapragada NA Peppas 1996 Dissolution mechanism of semicrystalline poly(vinyl alcohol) in water J Polym Sci B 34 1339 1346 10.1002/(SICI)1099- 0488(199605)34:7<1339::AID-POLB15>3.0.CO;2-B 1:CAS:528:DyaK28XisVOlsLs%3D (Pubitemid 126558226)