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Volumn 7, Issue , 2011, Pages 1379-1386

Combination of gold catalysis and Selectfluor for the synthesis of fluorinated nitrogen heterocycles

Author keywords

Cycloisomerization reactions; Fluorinated pyrrolidines; Gold catalysis; Selectfluor

Indexed keywords


EID: 80053932672     PISSN: 18605397     EISSN: 18605397     Source Type: Journal    
DOI: 10.3762/bjoc.7.162     Document Type: Article
Times cited : (34)

References (32)
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    • 19F NMR monitoring of the reaction of an equimolar mixture of Selectfluor and PPh3AuCl in CD3CN indicated that it is a rather slow process. After 3 h at rt a 5:1 Selectrfluor/A ratio was obtained; after 5 h, this ratio became 4:1 and after 24 h, gold nanoparticles were observed and signals of A vanished. This precluded the isolation of species A and its further use as a reagent
    • 19F NMR monitoring of the reaction of an equimolar mixture of Selectfluor and PPh3AuCl in CD3CN indicated that it is a rather slow process. After 3 h at rt, a 5:1 Selectrfluor/A ratio was obtained; after 5 h, this ratio became 4:1 and after 24 h, gold nanoparticles were observed and signals of A vanished. This precluded the isolation of species A and its further use as a reagent.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.