On the mechanism of Re(I)-carboxylate bond cleavage by perchloric acid: A kinetic and spectroscopic study

Journal of Physical Chemistry A

Volumn 115, Issue 40, 2011, Pages 10979-10987

  Fagioli, Ulises N ^a   García Einschlag, Fernando S ^a   Cobos, Carlos J ^a   Ruiz, Gustavo T ^a   Féliz, Mario R ^a   Wolcan, Ezequiel ^a  

^a FACULTAD DE CIENCIAS EXACTAS   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

BOND CLEAVAGES; CARBOXYL GROUPS; CONCENTRATION PROFILES; DECAY RATE CONSTANTS; DFT CALCULATION; MATRIX; MODEL PARAMETERS; MULTIVARIATE CURVE RESOLUTION; NON-LINEAR REGRESSION; PERCHLORIC ACIDS; PROTONATED; REACTION MIXTURE; SOLVATED PROTONS; SPECTRAL CHANGE; SPECTROSCOPIC STUDIES; STRUCTURAL PARAMETER; TIME-RESOLVED; UV-VIS SPECTRA; X-RAY STRUCTURE;

ACETONITRILE; CARBOXYLATION; DECAY (ORGANIC); EQUILIBRIUM CONSTANTS; INORGANIC ACIDS; PROTONATION; RATE CONSTANTS; REACTION INTERMEDIATES; RUNGE KUTTA METHODS; SPECTROSCOPIC ANALYSIS; SPECTROSCOPY;

CARBON DIOXIDE;

CARBOXYLIC ACID; ORGANOMETALLIC COMPOUND; PERCHLORIC ACID; RHENIUM;

ARTICLE; CHEMISTRY; INFRARED SPECTROPHOTOMETRY; KINETICS; ULTRAVIOLET SPECTROPHOTOMETRY;

CARBOXYLIC ACIDS; KINETICS; ORGANOMETALLIC COMPOUNDS; PERCHLORIC ACID; RHENIUM; SPECTROPHOTOMETRY, INFRARED; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 80053912307     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp206328q     Document Type: Article

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