Low-temperature synthesis of lithium manganese oxide using LiCl-Li 2CO3 and manganese acetate eutectic mixture

Materials and Manufacturing Processes

Volumn 26, Issue 11, 2011, Pages 1369-1373

  Helan, M ^a   Berchmans, L John ^b  

^a JAMAL MOHAMED COLLEGE   (India)

^b CENTRAL ELECTROCHEMICAL RESEARCH INSTITUTE   (India)

Author keywords

Characterization; Diffusion; EPR; LiMn2O4; XRD

Indexed keywords

ATOMIC ABSORPTION SPECTROSCOPY; AVERAGE PARTICLE SIZE; CHEMICAL COMPOSITIONS; CUBIC STRUCTURE; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; ENERGY DISPERSIVE X-RAY SPECTROSCOPY; EUTECTIC MIXTURE; FLUX METHODS; LIMN2O4; LITHIUM CARBONATES; LITHIUM CHLORIDE; LITHIUM MANGANESE OXIDE; LOW TEMPERATURE SYNTHESIS; MAGNETIC BEHAVIOR; MANGANESE ACETATE; MOLTEN SALT SYNTHESIS; NITROGEN-SULFUR; PRECURSOR SALTS; SYNTHESIZED POWDER; TGA/DTA; THERMAL DECOMPOSITION BEHAVIOR; X-RAY POWDER; XRD;

ATOMIC SPECTROSCOPY; CHARACTERIZATION; CHEMICAL ANALYSIS; CHLORINE COMPOUNDS; CRYSTALLINE MATERIALS; DIFFERENTIAL THERMAL ANALYSIS; DIFFUSION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ENERGY DISPERSIVE SPECTROSCOPY; EUTECTICS; FUSED SALTS; HYDROGEN; LITHIUM; MANGANESE; OXIDES; PARAMAGNETIC RESONANCE; PARAMAGNETISM; POWDERS; PYROLYSIS; RAMAN SPECTROSCOPY; SCANNING ELECTRON MICROSCOPY; SPECTRUM ANALYSIS; SULFUR; THERMOGRAVIMETRIC ANALYSIS; VOLATILE FATTY ACIDS; X RAY POWDER DIFFRACTION;

MANGANESE OXIDE;

EID: 80053639332     PISSN: 10426914     EISSN: 15322475     Source Type: Journal    
DOI: 10.1080/10426914.2010.536932     Document Type: Article

References (43)

1. 4 by microwave-assisted sol-gel method. J. Power Sources 2006, 154, 239-245.
2. 4 from mechanically activated solid-state synthesis. J. Solid State Chem. 2006, 179, 590-596. (Pubitemid 43124075)
3. 4 using direct solid state reaction. Mater. Lett. 2002, 56, 357-363. (Pubitemid 35173574)
4. 4 cathode doped with excess lithium and synthesized by co-precipitation for Li-ion batteries. J. Power Sources 2003, 115, 110-118. (Pubitemid 41325505)
5. 4 synthesized by citric acid sol-gel method. J. Power Sources 2001, 97-98, 443-446. (Pubitemid 32631299)
6. 4 cathode by a hydrothermal method. J. Power Sources 2006, 161, 1260-1263. (Pubitemid 44738756)
7. 5-BaO system. Mater. Res. Bull. 2004, 39, 1679-1689.
8. 3 mixtures obtained in molten alkali metal nitrates: Effect of the metal precursor. Appl. Catal. A: Gen. 2000, 196, 261-269.
9. 2 nanorods. Solid. State. Commun. 2003, 125, 301-304.
10. 3 and KOH. J. Eur. Ceram. Soc. 2004, 24, 3541-3546. (Pubitemid 38927033)
11. 2 photocatalysts by the molten salts method: Application to the photocatalytic degradation of Prosulfuron. Appl. Catal. B: Environ. 2004, 50, 219-226. (Pubitemid 38700328)
12. 3 for rechargeable lithium-ion batteries. Electrochem. Commun. 2004, 6, 789-794.
13. 4 spinel for 5 V class cathode material of Li-ion secondary battery. Electrochim. Acta, 2004, 49, 219-227.
14. 3:LiCl) synthesis for Li-ion batteries. J. Power Sources 2005, 147, 241-248.
15. Liang, H.Y.; Qiu, X.P.; Zhang, S.C.; He, Z.Q.; Zhu, W.T.; Chen, L.Q. High performance lithium cobalt oxides prepared in molten KCl for rechargeable lithium-ion batteries. Electrochem. Commun. 2004, 6, 505-509.
16. Yang, X.Y.; Tang, W.P.; Kanoh, H.; Ooi, K. Synthesis of lithium manganese oxide in different lithium-containing fluxes. J. Mater. Chem. 1999, 9, 2683-2690.
17. 3. J. Am. Ceram. Soc. 1991, 74, 38-41.
18. 3 prepared by molten salt synthesis. J. Am. Ceram. Soc. 1993, 76, 1373-1376.
19. Arent, R.H.; Rosolowski, Z.H.; Szymaszek, J.W. Lead zirconate titanate ceramics from molten salt solvent synthesized powders. Mater. Res. Bull. 1979, 14, 703-709. (Pubitemid 9467632)
20. Xu, R.; Pang, W. Inorganic Synthesis and Preparation Chemistry; Higher Education Press: Beijing, 2001.
21. 4 spinels by lithiation and heat-treatment of defective spinels. J. Mater. Chem. 2002, 12, 489-495.
22. 7 (A = K, Rb). Chem. Mater. 1993, 5, 1061-1063.
23. 5 system: A comparative study of materials obtained by ceramic and molten salt synthesis routes Bull. Mater. Sci. 2000, 23, 255-261.
24. Zhu, L.H.; Huang, Q.W.; Gu, H. Preparation of acicular strontium barium potassium niobate seed crystals J. Cryst. Growth, 2004, 267, 199-203.
25. 3 powders by molten salt methods. Materials and Manufacturing Processes 2008, 23, 791-795.
26. Yoon, K.H.; Cho, Y.S.; Kang, D.H. Molten salt synthesis of lead-based relaxors. J. Mater. Sci. 1998, 33, 2977-2984. (Pubitemid 128509180)
27. 4) spinel powder. J. Am. Ceram. Soc. 2006, 89, 1724-1726.
28. 4. J. Mater. Chem. 2002, 12, 2991-2997.
29. 4 by molten salt technique. Ionics 2010, 16, 227-231.
30. 4 by molten salt technique. J. Rare Earths 2010, 28, 225-259.
31. 4 by a citrate route with combustion. J. Alloy. Comp. 2003, 352, 250-254.
32. 4. J. Power Sources 2002, 111, 232-238.
33. Ammundsen, B.; Burns, G.R.; Islam, M.S.; Kanoh, H.; Roziere, J. Lattice dynamics and vibrational spectra of lithium manganese oxides: A computer simulation and spectroscopic study. J. Phys. Chem B. 1999, 103, 5175-5180.
34. 2 cathode material for rechargeable lithium batteries. Ionics 1997, 3, 170-176. (Pubitemid 128038471)
35. 4 for lithium-ion batteries. Mater. Res. Bull. 2007, 42, 1499-1506. (Pubitemid 46817585)
36. 4, spinels Mater. Res. Bull. 1996, 31, 935-941. (Pubitemid 126405299)
37. Preudhomme, J.; Tarte, P. Infrared studies of spinels - III: The normal II-III spinels. Spectrochim. Acta 1971, 27, 1817-1835.
38. 4 spinel prepared at moderate temperatue. Ionics 1998, 4, 8-15.
39. 4: Warnings on laser-induced thermal decomposition. Solid State Ionics 2004, 170, 135-138.
40. 4 thin film cathode grown at high, medium and low temperatures by pulsed laser deposition. J. Solid State Chem. 2006, 179, 3831-3838. (Pubitemid 44820180)
41. 4: A comparison with other M-doped Li-Mn spinels. Solid State Commun. 2003, 125, 179-183.
42. 4 spinels prepared by wet chemical methods. J. Magn. Magn. Mater. 2007, 309, 100-105. (Pubitemid 44585139)
43. 4 with 0 ≤ x ≤ 0.1. J. Phys. Chem. Solids 2000, 61, 609-614. (Pubitemid 32131953)