Conventional and first derivative synchronous fluorometric determination of ethamsylate in pharmaceutical preparations and biological fluids. Application to stability studies

Journal of Fluorescence

Volumn 21, Issue 4, 2011, Pages 1371-1384

  Belal, Fathalla ^a   El Brashy, Amina ^a   El Enany, Nahed ^a   Tolba, Manar ^a  

^a MANSOURA UNIVERSITY   (Egypt)

Author keywords

Degradation kinetics; Ethamsylate; Human plasma; Hydroquinone; Stability study; Synchronous fluorimetry

Indexed keywords

DEGRADATION-KINETICS; ETHAMSYLATE; HUMAN PLASMA; HYDROQUINONE; STABILITY STUDY; SYNCHRONOUS FLUORIMETRY;

ACTIVATION ENERGY; CALIBRATION; FLUORESCENCE; KETONES; METHANOL; PHENOLS; PLASMA (HUMAN); RATE CONSTANTS;

DEGRADATION;

DRUG; ETAMSYLATE; FLUORESCENT DYE; SURFACTANT;

ADULT; ARTICLE; BODY FLUID; CHEMICAL STRUCTURE; CHEMISTRY; DRUG STABILITY; FEMALE; HUMAN; PH; REFERENCE VALUE; SPECTROFLUOROMETRY;

ADULT; BODY FLUIDS; DRUG STABILITY; ETHAMSYLATE; FEMALE; FLUORESCENT DYES; HUMANS; HYDROGEN-ION CONCENTRATION; MOLECULAR STRUCTURE; PHARMACEUTICAL PREPARATIONS; REFERENCE VALUES; SPECTROMETRY, FLUORESCENCE; SURFACE-ACTIVE AGENTS;

EID: 80053386730     PISSN: 10530509     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10895-010-0819-6     Document Type: Article

References (26)

1. Sweetman SC (ed) (2007) Martindale, the complete drug reference, 35th edn. Pharmaceutical Press, London, p 959
2. The British Pharmacopoeia (2007) The Stationery Office: London; Electronic version
3. Kaul N, Agrawal H, Kakad A, Dhaneshwar SR, Patil B (2005) Stress degradation studies on etamsylate using stability-indicating chromatographic methods. Anal Chim Acta 536(1-2):49-70 (Pubitemid 40522277)
4. Zhang M, Zhang Y, Li Q (2010) A novel visible spectrophotometric method for the determination of ethamsylate in pharmaceutical preparations and biological samples. Spectrochim Acta A 75(3):1013-1017
5. Goyal A, Singhvi I (2008) Spectrophotometric estimation of ethamsylate and mefenamic Acid from a binary mixture by dual wavelength and simultaneous equation methods. Indian J Pharm Sci 70(1):108-111 (Pubitemid 351670582)
6. El-Enany N, Belal F, Rizk M (2007) Kinetic spectrophotometric determination of ethamsylate in dosage forms. J AOAC Int 90 (3):679-685 (Pubitemid 46945133)
7. El-Shabrawy Y, El-Enany N, Salem K (2004) Sensitive kinetic spectrophotometric determination of captopril and ethamsylate in pharmaceutical preparations and biological fluids. Farmaco 59 (10):803-808 (Pubitemid 39335950)
8. Xu ZC, Li XY, Shi J, Yao XJ, Liu AZ, He ZS (1994) Determination of Dicynone [ethamsylate] in gastric mucosa by ultra-violet spectrophotometry. Fenxi Huaxue 22(4):420
9. Jaiswal YS, Talele GS, Surana SJ (2005) Quantitative analysis of ethamsylate and mefenamic acid in tablets by use of planar chromatography. J Planar Chromatogr Mod TLC 18(106):460-464 (Pubitemid 43013569)
10. Jaiswal YS, Talele GS, Surana SJ (2005) A simple and sensitive HPTLC method for quantitative analysis of ethamsylate in tablets. J Planar Chromatogr Mod TLC 105(18):380-383 (Pubitemid 41671692)
11. Ma J, Liu Y (1984) Quantitative analysis of etamsylate by h.p.l.c. Yaowu Fenxi Zazhi 4(4):209-211
12. Wang SF, Xu Q (2007) Electrochemical parameters of ethamsylate at multi-walled carbon nanotube modified glassy carbon electrodes. Bioelectrochemistry 70(2):296-300 (Pubitemid 46507945)
13. Wang ZH, Li ZG, Zhou SP (2005) Voltammetric behavior of embedded super-thin carbon film electrode and its application. Fenxi Huaxue 33(4):523-526
14. Zhang XH, Wang SF (2005) Determination of ethamsylate in the presence of catecholamines using 4-amino-2-mercaptopyrimidine self-assembled monolayer gold electrode. Sens Actuators B 104 (1):29-34
15. Wang ZH, Zhang D, Zhang Y, Zhou SP (2001) Voltammetric behaviour of Dicynone at a poly(4-aminopyridine) film-modified electrode and its determination by adsorptive stripping voltammetry. Fenxi Huaxue 29(1):83-86
16. Yang FZ, Zhang C, Baeyens WRG, Zhang XR (2002) Determination of ethamsylate in pharmaceutical preparations based on an auto-oxidation chemiluminescence reaction. J Pharm Biomed Anal 30(3):473-478 (Pubitemid 35279675)
17. Li YH, Du JX, Lu JR (2002) Chemiluminescence reaction of luminol-[potassium ferricyanide-potassium ferrocyanide]-ethamsylate system. Fenxi Huaxue 30(6):742-744
18. Du JX, Li YH, Tang Y, Lu J.R. (2002) Flow-injection chemiluminescence determination of ethamsylate based on permanganate oxidation. Anal Lett 35(3):463-472 (Pubitemid 34270433)
19. Zhang CX, Huang JC, Feng ML, Zhang ZJ (1998) Flow injection chemiluminescence determination of etamsylate with electrogenerated hypochlorite. Anal Lett 31(11):1917-1928
20. Li J, Ju H (2006) Simultaneous determination of ethamsylate, tramadol and lidocaine in human urine by capillary electrophoresis with electrochemiluminescence detection. Electrophoresis 27 (17):3467-3474 (Pubitemid 44430727)
21. Skoog DA, Holler FJ, Crouch SR (2007) Principles of instrumental analysis, 6th edn. Thomson, Belmont, p 406
22. Miller JN, Miller JC et al (2005) Statistics and chemometrics for analytical chemistry. Pearson Education Limited, Harlow, pp 39- 73, 107-149, 256
23. ICH Harmonized Tripartite Guideline, Validation of Analytical Procedures: Text and Methodology, Q2(R1), Current Step 4 Version, Parent Guidelines on Methodology Dated November 6 1996, Incorporated in November 2005. http://www.ich.org/LOB/ media/MEDIA417.pdf (accessed February 15, 2008).
24. http://www.ompharma.com/dicynone/pharmacokinetics.html
25. Sun Y, Nakashima MN, Takahashi M, Kuroda N, Nakashima K (2002) Determination of bisphenol A in rat brain by microdialysis and column switching high-performance liquid chromatography with fluorescence detection. Biomed Chromatogr 16:319-326 (Pubitemid 34982343)
26. Martin A, Bustamante P (1993) Physical pharmacy, 4th edn. Lea and Febiger, Pheladelphia, p 295