Analytical approach for estimating kinetics of elementary steps on transition metals: Tunneling, trends and Brönsted-Evans-Polanyi relation

Journal of Electroanalytical Chemistry

Volumn 660, Issue 2, 2011, Pages 261-275

  German, E D ^a   Sheintuch, M ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

Adiabatic approach; Br nsted Evans Polanyi relation; Surface reactions; Tunneling

Indexed keywords

CHEMICAL ANALYSIS; CHEMICAL BONDS; DISSOCIATION; ELECTRON TUNNELING; GAS ADSORPTION; KINETICS; OXYGEN; PALLADIUM; PLATINUM; QUANTUM CHEMISTRY; RATE CONSTANTS; SURFACE REACTIONS; TRANSITION METALS;

ADIABATIC APPROACH; ADIABATIC POTENTIAL ENERGY SURFACE; ADSORPTION CHARACTERISTIC; ADSORPTION ENERGIES; ANALYTICAL APPROACH; ANALYTICAL METHOD; CO OXIDATION; DISSOCIATIVE ADSORPTION; ELEMENTARY STEPS; KINETIC CHARACTERISTICS; METAL SURFACES; NUMERICAL RESULTS; REACTION COORDINATES; REACTION ENERGY; SADDLE POINT; SEMI-EMPIRICAL; SUBSURFACE OXYGEN; SURFACE COVERAGES; WATER DISSOCIATION; ZERO-COVERAGE LIMIT;

ACTIVATION ENERGY;

EID: 80053100017     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2010.09.021     Document Type: Article

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