Effects of the [OC 6F 5] moiety upon structural geometry: Crystal structures of half-sandwich tantalum(V) aryloxide complexes from reaction of Cp*Ta(N tBu)(CH 2 R) 2 with pentafluorophenol

Acta Crystallographica Section B: Structural Science

Volumn 67, Issue 5, 2011, Pages 416-424

  Cole, Jacqueline M ^a,b   Chan, Michael C W ^c   Gibson, Vernon C ^d   Howard, Judith A K ^e  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF NEW BRUNSWICK   (Canada)

^c CITY UNIVERSITY OF HONG KONG   (Hong Kong)

^d IMPERIAL COLLEGE LONDON   (United Kingdom)

^e DURHAM UNIVERSITY   (United Kingdom)

Author keywords

agostic interactions; pentamethylcyclopentadienyltantalum imido complexes

Indexed keywords

AGOSTIC INTERACTIONS; ARYLOXIDE; ARYLOXIDE COMPLEXES; ELECTRONIC FACTORS; ELECTRONIC STABILITY; ELECTRONWITHDRAWING; HALF-SANDWICH; IMIDO COMPLEXES; ORBITALS; PENTAFLUOROPHENYL; PENTAMETHYLCYCLOPENTADIENYL; PENTAMETHYLCYCLOPENTADIENYLTANTALUM IMIDO COMPLEXES; STERIC CONGESTION; STRUCTURAL CHARACTERIZATION; STRUCTURAL GEOMETRY; TETRAKIS; TWIST ANGLES;

COMPETITION; CRYSTAL STRUCTURE; LIGANDS; SYNTHESIS (CHEMICAL);

TANTALUM;

EID: 80053081053     PISSN: 01087681     EISSN: None     Source Type: Journal    
DOI: 10.1107/S0108768111029259     Document Type: Article

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