Potassium-bearing clinopyroxene: A review of experimental, crystal chemical and thermodynamic data with petrological applications

Mineralogical Magazine

Volumn 75, Issue 4, 2011, Pages 2467-2484

  Safonov, O G ^a,b   Bindi, L ^c,d   Vinograd, V L ^e  

^a RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

^b UNIVERSITY OF JOHANNESBURG   (South Africa)

^c UNIVERSITY OF FLORENCE   (Italy)

^d SEZIONE DI FIRENZE   (Italy)

^e FORSCHUNGSZENTRUM JÜLICH   (Germany)

Author keywords

clinopyroxene; igneous geochemistry; igneous mineralogy; mantle rocks; potassium

Indexed keywords

ATOMISTIC SIMULATIONS; CHEMICAL COMPOSITIONS; CLINOPYROXENES; CRUSTAL ROCKS; ENDMEMBERS; EXCESS ENTHALPIES; EXPERIMENTAL DATA; FIRST-PRINCIPLES; HIGH TEMPERATURE; IGNEOUS GEOCHEMISTRIES; ISOTHERMAL BULK MODULUS; MANTLE ROCKS; MINERAL ASSEMBLAGE; MINERAL EQUILIBRIA; MIXING PROPERTY; NONIDEALITY; STANDARD ENTHALPY OF FORMATION; STANDARD ENTROPY; THERMAL EXPANSION COEFFICIENTS; THERMODYNAMIC CALCULATIONS; THERMODYNAMIC DATA; VOLUME EFFECT;

CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ENTHALPY; MINERALOGY; POTASSIUM; SILICATE MINERALS; STANDARDS; THERMAL EXPANSION; THERMOANALYSIS; THERMODYNAMICS;

IGNEOUS ROCKS;

BULK MODULUS; CHEMICAL COMPOSITION; CLINOPYROXENE; CONFERENCE PROCEEDING; CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; DIOPSIDE; ENTHALPY; EXPERIMENTAL MINERALOGY; IGNEOUS GEOCHEMISTRY; PETROLOGY; POTASSIUM; SOLUBILITY; THERMAL EXPANSION; THERMODYNAMICS;

EID: 80052996071     PISSN: 0026461X     EISSN: 14718022     Source Type: Journal    
DOI: 10.1180/minmag.2011.075.4.2467     Document Type: Conference Paper

References (76)

1. 4: calorimetric measurements, thermochemical calculation, and geophysical application. Journal of Geophysical Research, 94, 15671-15685.
2. 6 at 10-25 kbar. Contributions to Mineralogy and Petrology, 61, 251-265.
3. Benna, P., Chiari, G. and Bruno, E. (1987) Structural modifications in clinopyroxene solid solution: the Ca-Mg and Ca-Srsubstitutions in the diopside structure. Mineralogy and Petrology, 36, 71-84.
4. Bindi, L., Safonov, O. G., Litvin, Yu. A., Perchuk, L. L. and Menchetti, S. (2002) Ultrahigh potassium content in the clinopyroxene structure: an X-ray single-crystal study. European Journal of Mineralogy, 14, 929-934.
5. Bindi, L., Safonov, O. G., Yapaskurt, V. O., Perchuk, L. L. and Menchetti, S. (2003) Ultrapotassic clinopyroxene from the Kumdy-Kol microdiamond mine, Kokchetav Complex, Kazakhstan: occurrence, composition and crystal-chemical characterization. American Mineralogist, 88, 464-468. (Pubitemid 36326151)
6. Bindi, L., Downs, R. T., Harlow, G. E., Safonov, O. G., Litvin, Yu. A., Perchuk, L. L. and Menchetti, S. (2006) Compressibility of synthetic potassium-rich clinopyroxene: In-situ high-pressure single-crystal X-ray study. American Mineralogist, 91, 802-808. (Pubitemid 43949987)
7. Bishop, F. C., Smith, J. V. and Dawson, J. B. (1978) Na, K, P and Ti in garnet, pyroxene and olivine from peridotite and eclogite xenoliths from African kimberlites. Lithos, 11, 155-173.
8. Carpenter, M. A. (1980) Mechanisms of exsolution in sodic pyroxenes. Contributions to Mineralogy and Petrology, 71, 289-300.
9. Chudinovskikh, L. T., Zharikov, V. A., Ishbulatov, R. A. and Matveev, Y. A. (2001) On the mechanism of incorporation of ultra-high amounts of potassium into clinopyroxene at high pressure. Doklady Earth Sciences, 380, 1-4.
10. Daniels, L. R. M. and Gurney, J. J. (1989) The chemistry of garnets, chromites and diamond inclusions from the Dokolwayo kimberlites, Kingdom of Swaziland. Pp. 1012-1021 in: Kimberlites and related rocks. Volume 2. Their Mantle/Crust Setting, Diamonds and Diamond Exploration (J. Ross, editor). Geological Society of Australia Special Publication, 14. Blackwell, Carlton, Australia.
11. 2-rich lamproite from Smoky Butte, Montana: derivation of siliceous lamproite magmas from enriched sources deep in the continental mantle. Journal of Petrology, 38, 457-477.
12. Edgar, A. D. and Vukadinovic, D. (1993) Potassium-rich clinopyroxene in the mantle: an experimental investigation of K-rich lamproite up to 60 kbar. Geochimica et Cosmochimica Acta, 57, 5063-5072. (Pubitemid 24422752)
13. Erlank, A. J. and Kushiro, I. (1970) Potassium contents of synthetic pyroxenes at high temperatures and pressures. Carnegie Institution Washington Yearbook, 68, 267-271.
14. Foley, S. F. (1992) Petrological characterization of the source components of potassic magmas: geochemical and experimental constraints. Lithos, 28, 187-204.
15. 2O between 40 and 60 kbar. Lithos, 112 S, 274-283.
16. Ghorbani, M. R. and Middlemost, E. A. K (2000) Geochemistry of pyroxene inclusions from the Warrumbungle Volcano, New South Wales, Australia. American Mineralogist, 85, 1349-1367.
17. Harlow, GE. (1996) Structure refinement of natural K-rich diopside: the effect of K on the average structure. American Mineralogist, 81, 632-638.
18. Harlow, GE. (1997) K in clinopyroxene at high pressure and temperature: an experimental study. American Mineralogist, 82, 259-269.
19. Harlow, GE. (1999) Interpretation of Kcpx and CaEs in Clinopyroxene from Diamond Inclusions and Mantle Samples. Pp. 321-331 in: Proceedings of Seventh International Kimberlite Convention, volume I (J. J. Gurney, J. L. Gurney, M. D. Pascoe and S. H. Richardson, editors). Redroof Design, Cape Town, South Africa.
20. 3, clinohumite and chondrodite. Geological Materials Research, 4, 1-28.
21. Harlow, GE. and Davies, R. (2004) Status report on stability of K-rich phases at mantle conditions. Lithos, 77, 647-653. (Pubitemid 40586997)
22. Harlow, GE. and Veblen, D. R (1991) Potassium in clinopyroxene inclusions from diamonds. Science, 251, 652-655. (Pubitemid 21916887)
23. Hart, S. R and Zindler, A. (1986) In search of a bulkearth composition. Chemical Geology, 57, 247-267.
24. Holland, T. J. B. and Powell, R. (1998) An internallyconsistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology, 16, 309-343. (Pubitemid 28388692)
25. 6. Contributions to Mineralogy and Petrology, 36, 63-72.
26. Jagoutz, E., Palme, H., Baddenhausen, H., Blum, K., Cendales, M., Dreibus, G., Spettel, B., Lorenz, V. and Wanke H. (1979) The abundances of major, minor and trace elements in the Earth's mantle as derived from primitive ultramafic nodules. Pp. 2031-2050 in: Proceedings of the 10th Lunar and Planetary Science Conference, (R. B. Merrill editor). Geochimica et Cosmochimica Acta Supplement 11. Pergamon Press, New York.
27. Jaques, A. L., O'Neill, H. St. C., Smith, C. B., Moon, J. and Chappell, B. W. (1990) Diamondiferous peridotite xenoliths from the Argyle (AK1) lamproite pipe, Western Australia. Contributions to Mineralogy and Petrology, 104, 255-276.
28. Kaminsky, F. V., Zakharchenko, O. D., Griffin, W. L., Channer, DeR. D. M. and Khachatryan-Blinova, G. K. (2000) Diamond from the Guaniamo area, Venezuela. The Canadian Mineralogist, 38, 1347-1370. (Pubitemid 32265688)
29. Konzett, J. and Fei, Y. (2000) Transport and storage of potassium in the Earth's upper mantle and transition zone: experimental study to 23 GPa in simplified and natural bulk compositions. Journal of Petrology, 41, 583-603. (Pubitemid 30218424)
30. Konzett, J. and Ulmer, P. (1999) The stability of hydrous potassic phases in lherzolitic mantle - an experimental study to 9.5 GPa in simplified and natural bulk compositions. Journal of Petrology, 40, 629-652. (Pubitemid 29255219)
31. 2-inclusions in omphacite. Contributions to Mineralogy and Petrology, 155, 215-228.
32. Liu, L. (1987) High-pressure transition of potassium aluminosilicates with an emphasis on leucite. Contributions to Mineralogy and Petrology, 95, 1-3.
33. Luth, R. W. (1992) Potassium in clinopyroxene at high pressure: experimental constraints. EOS Transactions of the American Geophysical Union, 73, 608.
34. Luth, RW. (1995) Potassium in clinopyroxene at high pressure. EOS Transactions of the American Geophysical Union, 76, F711.
35. Luth, R. W. (1997) Experimental study of the system phlogopite-diopside from 3.5 to 17 GPa. American Mineralogist, 82, 1198-1209.
36. 2-clinopyroxene-garnet system at 3.8-7.0 GPa: Modeling the genesis of diamondbearing rocks of Kazakhstan metamorphic complex. Journal of Conference Abstracts VIII Symposium EMPG, Bergamo, 5 (1).
37. McDonough, W. F. and Sun, S.-S. (1995) The composition of the Earth. Chemical Geology, 120, 223-253.
38. McDonough, W. F., Sun, S.-S., Ringwood, A. E., Jagoutz, E. and Hofmann, A. W. (1992) Potassium, rubidium, and cesium in the Earth and Moon and the evolution of the mantle of the Earth. Geochimica et Cosmochimica Acta, 56, 1001-1012.
39. Mellini, M. and Cundari, A. (1989) On the reported presence of potassium in clinopyroxene from potassium-rich lavas: a transmission electron microscope study. Mineralogical Magazine, 53, 311-314.
40. Mitchell, R. H. (1995) Melting experiments on a sanidine-phlogopite lamproite at 4-7 GPa and their bearing on the source of lamproitic magmas. Journal of Petrology, 36, 1455-1474. (Pubitemid 26458949)
41. 2O to 35 kbars: a better model for mica in the interior of the Earth. American Journal of Sciences, 273, 385-414.
42. 2. Geochimica et Cosmochimica Acta, 41, 369-377.
43. Okamoto, K and Maruyama, S. (1998) Multi-anvil reequilibration experiments of a Dabie Shan ultra-high pressure eclogite within the diamond-stability fields. Island Arc, 7, 52-69. (Pubitemid 28441235)
44. 6. American Mineralogist, 59, 549-557.
45. Papike, J. J. (1980) Pyroxene mineralogy of the Moon and meteorites. Pp 495-525 in: Pyroxenes (C. T. Prewitt, editor). Reviews in Mineralogy and Geochemistry, 7, Mineralogical Society of America, Washington D. C.
46. Perchuk, L. L., Safonov, O. G., Yapaskurt, V. O. and Barton, J. M., Jr. (2002) Crystal-melt equilibria involving potassium-bearing clinopyroxene as indicators of mantle-derived ultrahigh-potassic liquids: an analytical review. Lithos, 60, 89-111. (Pubitemid 34231561)
47. Pla Cid, J., Nardi, L. V. S., Stabel, L. Z., Conceicão, R. V. and Balzaretti, N. M. (2003) High-pressure minerals in mafic microgranular enclaves: evidences for comingling between lamprophyric and syenitic magmas at mantle conditions. Contributions to Mineralogy and Petrology, 145, 444-459. (Pubitemid 36964930)
48. Pokhilenko, N. P., Sobolev, N. V., Reutsky, V. N., Hall, A. E. and Taylor, L. A. (2004) Crystalline inclusions and C-isotope ratios in diamonds from the Snap Lake/King Lake kimberlite dyke system: evidence of ultradeep and enriched lithospheric mantle. Lithos, 77, 57-67 (Pubitemid 40578469)
49. Prinz, M., Manson, D. V., Hlava, P. F. and Keil, K. (1975) Inclusions in diamonds: garnet lherzolite and eclogite assemblages. Physics and Chemistry of the Earth, 9, 797-815.
50. Ricard, R. S., Harris, J. W., Gurney, J. J. and Cardoso, P. (1989) Mineral inclusions in diamonds from the Koffiefontein Mine. Geological Society of Australia Special Publications, 14, 1054-1062.
51. 2 at 5-7 GPa in relation to the genesis of garnet-clinopyroxene-carbonate rocks of the Kokchetav Complex (northern Kazakhstan). Petrology, 10, 519-539. (Pubitemid 36039696)
52. 6 at 7 GPa. Contributions to Mineralogy and Petrology, 146, 120-133. (Pubitemid 37348010)
53. 6. Petrology, 12, 84-97.
54. 8 join at 6 and 3.5 GPa as a model for formation of some potassium-bearing deep-seated mineral assemblages. Contributions to Mineralogy and Petrology, 149, 316-337. (Pubitemid 40735252)
55. Safonov, O. G., Perchuk, L. L. and Litvin, Yu. A. (2005b) Equilibrium K-bearing clinopyroxene-melt as a model for barometry of mantle-derived mineral assemblages. Russian Geology and Geophysics, 46, 1318-1334. (Pubitemid 44211225)
56. Safonov, O. G., Perchuk, L. L. and Litvin, Yu. A. (2006) Effect of carbonates on crystallization and composition of potassium-bearing clinopyroxene at high pressures. Doklady Earth Sciences, 408, 580-585. (Pubitemid 44944914)
57. Schmidt, M. W. (1996) Experimental constraints on recycling potassium from subducted oceanic crust. Science, 272, 1927-1930.
58. Schmidt, M. W. and Poli, S. (1998) Experimentally based waterbudgets for dehydrating slabs and consequences for arc magma generation. Earth and Planetary Science Letters, 163, 361-379. (Pubitemid 29094469)
59. Shannon, R. D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751-767.
60. Shimizu, N. (1971) Potassium content of synthetic clinopyroxenes at high pressures and temperatures. Earth and Planetary Science Letters, 11, 374-380.
61. Sobolev, N. V. (1977) Deep-seated inclusions in kimberlites and the problem of the composition of the upper mantle. AGU, Washington, 279 pp. [Translated from the Russian edition, 1974].
62. Sobolev, N. V. and Shatsky, V. S. (1990) Diamond inclusions in garnets from metamorphic rocks: a new environment for diamond formation. Nature, 343, 742-746.
63. Sobolev, N. V., Yefimova, E. S., Channer, D. M. DeR., Anderson, P. F. N. and Barron, K. M. (1998) Unusual uppermantle beneath Guaniamo, Guyana Shield, Venezuela: evidence from diamond inclusions. Geology, 26, 971-974. (Pubitemid 29089587)
64. Spandler, C., Yaxley, G., Green, D. H. and Rosenthal, A. (2008) Phase relations and melting of anhydrous K-bearing eclogite from 1200 to 1600°C and 3 to 5 GPa. Journal of Petrology, 49, 771.
65. Stachel, T., Brey, GP. and Harris, J. W. (2000) Kankan diamonds (Guinea) I: from the lithosphere down to the transition zone. Contributions to Mineralogy and Petrology, 140, 1-15.
66. 9. American Mineralogist, 68, 581-585.
67. Thomsen, T. B. and Schmidt, M. W. (2008) Melting of carbonated pelites at 2.5-5.0 GPa, silicate-carbonatite liquid immiscibility, and potassium-carbon metasomatism of the mantle. Earth and Planetary Science Letters, 267, 17-31.
68. Trønnes, R. G (2002) Stability range and decomposition of potassic richterite and phlogopite end members at 5-15 GPa. Mineralogy and Petrology, 74, 129-148.
69. Tsuruta, K. and Takahashi, E. (1998) Melting study of an alkali basalt JB-1 up to 12.5 GPa: behaviorof potassium in the deep mantle. Physics of the Earth and Planetary Interiors, 107, 119-130. (Pubitemid 28472327)
70. Vinograd, V. L. (2002) Thermodynamics of mixing and ordering in the diopside¡jadeite system: I. A CVM model. Mineralogical Magazine, 66, 513-536. (Pubitemid 35029043)
71. 6, solid solution from quantum mechanical and static lattice energy calculations. Petrology, 18, 447-459.
72. Wang, W. and Takahashi, E. (1999) Subsolidus and melting experiments of a K-rich basaltic composition to 27 GPa: Implication forbehaviorof potassium in the mantle. American Mineralogist, 84, 357-361. (Pubitemid 29285835)
73. Wood, B. J. and Henderson, C. M. B. (1978) Compositions and unit-cell parameters of synthetic non-stoichiometric tschermakitic clinopyroxenes. American Mineralogist, 63, 66-72.
74. Wood, BJ. and Nichols, J. (1978) The thermodynamic properties of reciprocal solid solutions. Contributions to Mineralogy and Petrology, 66, 389-400.
75. Wood, B. J., Holland, T. J. B., Newton, R. C. and Kleppa, O. J. (1980) Thermochemistry of jadeite-diopside pyroxenes. Geochimica et Cosmochimica Acta, 44, 1363-1371.
76. 8. Physics and Chemistry of Minerals, 33, 167-177.