Mineral replacement reactions in solid solution-aqueous solution systems: Volume changes, reactions paths and end-points using the example of model salt systems

American Journal of Science

Volumn 311, Issue 3, 2011, Pages 211-236

  Pollok, Kilian ^a,b   Putnis, Christine V ^b   Putnis, Andrew ^b  

^a UNIVERSITÄT BAYREUTH   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Dissolutionprecipitation; Pseudomorphism; Replacement; Solubility; SS AS systems; Volume change

Indexed keywords

AQUEOUS SOLUTION; DISSOLUTION; MODELING; POROSITY; PRECIPITATION (CHEMISTRY); REACTION KINETICS; SALT; SOLID SOLUTION; SOLUBILITY; TEXTURE; VOLUME CHANGE;

EID: 80052948811     PISSN: 00029599     EISSN: None     Source Type: Journal    
DOI: 10.2475/03.2011.02     Document Type: Article

References (71)

1. Astilleros, J. M., Pina, C. M., Ferńandez-D?́az, L., and Putnis, A., 2003, Supersaturation functions in binary solid solution-aqueous solution systems: Geochimica et Cosmochimica Acta, v. 67, p. 1601-1608, doi:10.1016/S0016-7037(02)01166-3. (Pubitemid 36551531)
2. Azimov, P. Y., and Shtukenberg, A. G., 2000, Simulation of phase diagrams for water-salt systems with solid solutions: Russian Journal of Inorganic Chemistry, v. 45, p. 1302-1309.
3. Baker, D. R., Paul, G., Sreenivasan, S., and Stanley, H. E., 2002, Continuum percolation threshold for interpenetrating squares and cubes: Physical Review E, v. 66, 046136, doi:10.1103/Phys- RevE.66.046136.
4. Berthelot, M., 1872, On the law which governs the distribution of a substance between two solvents: Annales de Chimie et Physique (in French), v. 26, p. 408-417.
5. Blum, J. R., 1843, Die Pseudomorphosen des Mineralreichs: Sttutgart, Schweizerbart'sche Verlagsbuchhandlung, 378 p. (in German).
6. Cartwright, I., 1997, Permeability generation and resetting of tracers during metamorphic fluid flow: implications for advection-dispersion models: Contributions to Mineralogy and Petrology, v. 129, p. 198-208, doi:10.1007/s004100050332. (Pubitemid 28456768)
7. Dejewska, B., 1993, Some physicochemical parameters of saturated ternary solutions of systems with mixed crystals in their solid phase: Crystal Research and Technology, v. 28, p. 697-705, doi:10.1002/crat.2170280521.
8. Doerner, H. A., and Hoskins, W. M., 1925, Co-precipitation of radium and barium sulfates: Journal of the American Chemical Society, v. 47, p. 662-675, doi:10.1021/ja01680a010.
9. 2O at 25 °C: Journal of the American Chemical Society., v. 75, p. 5792-5794, doi:10.1021/ja01119a007.
10. Engvik, A. K., Golla-Schindler, U., Berndt, J., Austrheim, H., and Putnis, A., 2009, Intragranular replacement of chlorapatite by hydroxy-fluor-apatite during metamorphism: Lithos, v. 112, p. 236-246, doi:10.1016/j.lithos.2009.02.005.
11. 2O: The Canadian Journal of Chemical Engineering, v. 71, p. 141-146, doi:10.1002/cjce.5450710119. (Pubitemid 23623050)
12. Ferry, J. M., 2000, Patterns of mineral occurrence in metamorphic rocks: American Mineralogist, v. 85, p. 1573-1588. (Pubitemid 32050577)
13. Geisler, T., Berndt, J., Meyer, H.-W., Pollok, K., and Putnis, A., 2004, Low-temperature aqueous alteration of crystalline pyrochlore: Correspondence between nature and experiment: Mineralogical Magazine, v. 68, p. 905-922, doi:10.1180/0026461046860230. (Pubitemid 40177813)
14. Geisler, T., P̈oml, P., Stephan, T., Janssen, A., and Putnis, A., 2005a, Experimental observation of an interface-controlled pseudomorphic replacement reaction in a natural crystalline pyrochlore: American Mineralogist, v. 90, p. 1683-1687, doi:10.2138/am.2005.1970. (Pubitemid 41555962)
15. Geisler, T., Janssen, A., Scheiter, D., Stephan, T., Berndt, J., and Putnis, A., 2010, Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism: Journal of Non-Crystalline Solids, v. 356, p. 1458-1465, doi:10.1016/j.jnoncrysol.2010.04.033.
16. Geisler, T., Seydoux-Guillaume, A. M., Poeml, P., Golla-Schindler, U., Berndt, J., Wirth, R., Pollok, K., Janssen, A., and Putnis, A., 2005b, Experimental hydrothermal alteration of crystalline and radiationdamaged pyrochlore: Journal of Nuclear Materials, v. 344, p. 17-23, doi:10.1016/j. jnucmat.2005.04.009. (Pubitemid 41119829)
17. Geisler, T., Schaltegger, U., and Tomaschek, F., 2007, Re-equilibration of zircon in aqueous fluids and melts: Elements, v. 3, n. 1, p. 43-50, doi:10.2113/gselements.3.1.43. (Pubitemid 46394235)
18. Glikin, A. E., 2008, Polymineral-metasomatic crystallogenesis: New York, Springer, 312 p.
19. Glynn, P. D., 2000, Solid-solution solubilities and thermodynamics: Sulfates, carbonates and halides, in Alpers, C. N., Jambor, J. L, and Nordstrom, D. K., editors, Sulfate Minerals: Reviews in Mineralogy and Geochemistry, v. 40, p. 481-511, doi:10.2138/rmg.2000.40.10.
20. Glynn, P. D., and Reardon, E. J., 1990, Solid-solution aqueous-solution equilibria: thermodynamic theory and representation: American Journal of Science, v. 290, p. 164-201, doi:10.2475/ajs.290.2.164.
21. Glynn, P. D., Reardon, E. J., Plummer, L. N., and Busenberg, E., 1990, Reaction paths and equilibrium end-points in solid-solution aqueous-solution systems: Geochimica et Cosmochimica. Acta, v. 54, n. 2, p. 267-282, doi:10.1016/0016-7037(90)90317-E.
22. Guggenheim, E. A., 1937, The theoretical basis for Raoult's law: Transactions of the Faraday Society, v. 33, p. 151-159, doi:10.1039/ tf9373300151.
23. Harlov, D. E., and Förster, H.-J., 2003, Fluid-induced nucleation of (Y-REE)-phosohate minerals within apatite: Nature and experiment. Part II. Fluoroapatite: American Mineralogist, v. 88, p. 1209-1229.
24. Harlov, D. E., Förster, H.-J., and Nijland, T. G., 2002, Fluid-induced nucleation of (Y-REE)-phosphate minerals within apatite: Nature and experiment-Part I. Chlorapatite: American Mineralogist, v. 87, p. 245-261.
25. Harlov, D. E., Wirth, R., and Förster, H.-J., 2005, An experimental study of dissolution-reprecipitation in fluorapatite: Fluid infiltration and the formation of monazite: Contributions to Mineralogy and Petrology, v. 150, n. 3, p. 268-286, doi:10.1007/s00410-005-0017-8. (Pubitemid 41601306)
26. Hövelmann, J., Putnis, A., Geisler, T., Schmidt, B. C., and Golla-Schindler, U., 2010, The replacement of plagioclase feldspars by albite: observations from hydrothermal experiments: Contributions to Mineralogy and Petrology, v. 159, n. 1, p. 43-59, doi:10.1007/s00410-009-0415-4.
27. Jamtveit, B., Austrheim, H., and Malthe-Sørenssen, A., 2000, Accelerated hydration of the Earth's deep crust induced by stress perturbations: Nature, v. 408, p. 75-79, doi:10.1038/35040537.
28. Königsberger, E., and Gamsjäger, H., 1987, Solid-solute phase equilibria in aqueous solution-I. Solubility constant and free enthalpy of formation of huntite: Berichte der Bunsengesellschaft fü r Physikalische Chemie, v. 91, p. 785-790. (Pubitemid 17652163)
29. Königsberger, E., and Gamsjäger, H., 1992, Comment: Solid-solution aqueous-solution equilibria: thermodynamic theory and representation: American Journal of Science, v. 292, p. 199-214, doi:10.2475/ajs.292.3.199.
30. Kulik, D. A., 2006, Dual-thermodynamic estimation of stoichiometry and stability of solid solution end members in aqueous-solid solution systems: Chemical Geology, v. 225, n. 2-3, p. 189-212, doi:10.1016/j.chemgeo.2005.08.014. (Pubitemid 43091832)
31. Kusiak, M. A., Dunkley, D. J., S?aby, E., Martin, H., and Budzyń , B., 2009, Sensitive high-resolution ion microprobe analysis of zircon reequilibrated by late magmatic fluids in a hybridized pluton: Geology, v. 37, n. 12, p. 1063-1066, doi:10.1130/G30048A.1.
32. Labotka, T. C., Cole, D. R., Fayek, M., Riciputi, L. R., and Staderman, F. J., 2004, Coupled cation and oxygen-isotope exchange between alkali feldspar and aqueous chloride solution: American Mineralogist, v. 89, n. 11-12, p. 1822-1825. (Pubitemid 40032647)
33. Lippmann, F., 1977, The solubility product of complex minerals, mixed crystals and three-layer clay minerals: Neues Jahrbuch fü r Mineralogie-Abhandlungen, v. 130, p. 243-263.
34. Lippmann, F., 1980, Phase diagrams depicting the aqueous solubility of mineral systems: Neues Jahrbuch für Mineralogie-Abhandlungen, v. 139, p. 1-25.
35. Lippmann, F., 1982, Stable and metastable solubility diagrams for the system CaCO3-MgCO3-H2O at ordinary temperature: Bulletin de Mineralogie, v. 105, p. 273-279.
36. Nernst, W., 1891, Distribution of a substance between two solvents and between solvents and vapor: Physical Chemistry, v. 8, p. 110-139.
37. Niedermeier, D. R. D., Putnis, A., Geisler, T., Golla-Schindler, U., and Putnis, C. V., 2009, The mechanism of cation and oxygen isotope exchange in alkali feldspars under hydrothermal conditions: Contributions to Mineralogy and Petrology, v. 157, n. 1, p. 65-76, doi:10.1007/s00410-008-0320-2.
38. O'Neil, J. R., and Taylor, H. P., 1967, The oxygen isotope and cation exchange chemistry of feldspars: American Mineralogist, v. 52, p. 1414-1437.
39. Parsons, I., and Lee, M. R., 2009, Mutual replacement reactions in alkali feldspars I: microtextures and mechanisms: Contributions to Mineralogy and Petrology, v. 157, n. 5, p. 641-661, doi:10.1007/s00410-008-0355-4.
40. Plummer, L. N., Parkhurst, D. L., Fleming, G. W., and Dunkle, S. A., 1988, A computer program incorporating Pitzer's equations for calculation of geochemical reactions in brines: U.S. Geological Survey, Water Resources Investigations Report 88-4153, 310 p.
41. Pollok, K., ms, 2005, Crystal growth patterns in solid solution systems: Case studies on oscillatory zoning and mineral replacement reactions: Münster, Germany, WestfälischeWilhelms-Universität Münster, Ph. D. thesis, p. 146, http://miami.uni-muenster.de/servlets/DerivateServlet/ Derivate-624/diss-pollok.pdf
42. Pollok, K., Lloyd, G. E., Austrheim, H., and Putnis, A., 2008, Complex replacement patterns in garnets from Bergen Arcs eclogites: A combined EBSD and analytical TEM study: Chemie der Erde-Geochemistry v. 68, n. 2, p. 177-191, doi:10.1016/j.chemer.2007.12.002.
43. Prieto, M., 2009, Thermodynamics of solid solution-aqueous solution systems: Reviews in Mineralogy and Geochemistry, v. 70, n. 1, p. 47-85, doi:10.2138/rmg.2009.70.2.
44. Putnis, A., 2002, Mineral replacement reactions: from macroscopic observations to microscopic mechanisms: Mineralogical Magazine, v. 66, p. 689-708 doi:10.1180/0026461026650056.
45. Putnis, A., 2009, Mineral replacement reactions: Reviews in Mineralogy and Geochemistry, v. 70, n. 1, p. 87-124, doi:10.2138/rmg.2009.70.3.
46. Putnis, A., and John, T., 2010, Replacement processes in the Earth's crust: Elements, v. 6, n. 3, p. 159-164, doi:10.2113/gselements.6.3.159.
47. Putnis, A., and Putnis, C. V., 2007, The mechanism of reequilibration of solids in the presence of a fluid phase: Journal of Solid State Chemistry, v. 180, n. 5, p. 1783-1786, doi:10.1016/j.jssc.2007.03.023. (Pubitemid 46754326)
48. Putnis, A., Putnis, C. V., and Giampaolo, C., 1994, The microstructure of analcime phenocrysts in igneous rocks: European Journal of Mineralogy, v. 6, p. 627-632.
49. Putnis, A., Prieto, M., and Fernandez-Diaz, L., 1995, Fluid supersaturation and crystallization in porous media: Geological Magazine, v. 132, p. 1-13, doi:10.1017/S0016756800011389.
50. Putnis, A., Hinrichs, R., Putnis, C. V., Golla-Schindler. U., and Collins, L. G., 2007a, Hematite in porous red-clouded feldspar: Evidence of large-scale crustal fluid-rock interaction: Lithos, v. 95, n. 1-2, p. 10-18, doi:10.1016/j.lithos.2006.07.004. (Pubitemid 46404560)
51. 2O: Geochimica et Cosmochimica Acta, v. 68, n. 13, p. 2839-2848, doi:10.1016/j.gca.2003.12.009. (Pubitemid 38804267)
52. Putnis, C. V., Tsukamoto, K., and Nishimura, Y., 2005, Direct observation for pseudomorphism: Compositional and textural evolution at a fluid-solid interface: American Mineralogist, v. 90, n. 11-12, p. 1909-1912, doi:10.2138/am.2005.1990. (Pubitemid 43085570)
53. Putnis, C. V., Geisler, T., Schmid-Beurmann, P., Stephan, T., and Giampaolo, C., 2007b, An experimental study of the replacement of leucite by analcime: American Mineralogist, v. 92, n. 1, p. 19-26, doi:10.2138/am.2007. 2249. (Pubitemid 46139549)
54. Ramdohr, P., 1980, The ore minerals and their intergrowths: Oxford, Pergamon Press, 1205 p.
55. Redlich, O., and Kister, A. T., 1948, Algebraic representation of thermodynamic properties and the classification of solutions: Industrial and Engineering Chemistry, v. 40, p. 345-348, doi:10.1021/ie50458a036.
56. Rendón-Angeles, J. C., Yanagisawa, K., Ishizawa, N., and Oishi, S., 2000a, Conversion of calcium fluoroapatite into calcium hydroxyapatite under alkaline hydrothermal conditions: Journal of Solid State Chemistry, v. 151, n. 1, p. 65-72, doi:10.1006/jssc.1999.8623.
57. Rendón-Angeles, J. C., Yanagisawa, K., Ishizawa, N., and Oishi, S., 2000b, Topotaxial conversion of chloroapatite and hydroxyapatite to fluorapatite by hydrothermal ion exchange: Chemistry of Materials, v. 12, p. 2143-2150, doi:10.1021/cm990797x.
58. Rendón-Angeles, J. C., Yanagisawa, K., Ishizawa, N., and Oishi, S., 2000c, Effect of metal ions of chloroapatites on the topotaxial replacement by hydroxyapatite under hydrothermal conditions: Journal of Solid State Chemistry, v. 154, p. 569-578, doi:10.1006/jssc.2000.8888.
59. Rubatto, D., Müntener, O., Barnhoorn, A., and Gregory, C., 2008, Dissolution-reprecipitation of zircon at low-temperature, high-pressure conditions (Lanzo Massif, Italy): American Mineralogist, v. 93, 1519-1529, doi:10.2138/am.2008.2874.
60. Rumble, D., III, and Spear, F. S., 1983, Oxygen isotope equilibration and permeability enhancement during regional metamorphism: Journal of the Geological Society, v. 140, p. 619-628, doi:10.1144/gsjgs.140.4.0619.
61. Seydoux-Giullaume, A.-M., Wirth, R., and Ingrin, J., 2007, Contrasting response of ThSiO4 and monazite to natural irridation: European Journal of Mineralogy, v. 19, n. 1, p. 7-14, doi:10.1127/0935-1221/2007/0019-007. (Pubitemid 46850858)
62. Shtukenberg, A. G., Punin, Y. O., and Azimov, P., 2006, Crystallization kinetics in binary solid solutionaqueous solution systems: American Journal of Science, v. 306, p. 553-574, doi:10.2475/07.2006.03. (Pubitemid 44848479)
63. Silcock, H. L., editor, 1979, Solubilities of Inorganic and Organic Compounds: Oxford, Pergamon Press, v. 3, 499 p.
64. Soman, A., Geisler, T., Tomaschek, F., Grange, M., and Berndt, J., 2010, Alteration of crystalline zircon solid solutions: a case study on zircon from an alkaline pegmatite from Zomba-Malosa, Malawi: Contributions to Mineralogy and Petrology, v. 160, n. 6, p. 909-930, doi 10.1007/s00410-010-0514-2.
65. Spandler, C., Hermann, J., and Rubatto, D., 2004, Exsolution of thortveitite, yttrialite, and xenotime during low-temperature recrystallization of zircon from New Caledonia, and their significance for trace element incorporation in zircon: American Mineralogist, v. 89, n. 11-12, p. 1795-1896.
66. Tenailleau, C., Pring, A., Etschmann, B., Brugger, J., Grguric, B. A., and Putnis, A., 2006, Transformation of pentlandite to violarite under mild hydrothermal conditions: American Mineralogist, v. 91, p. 706-709, doi:10.2138/am.2006.2131.
67. Tomaschek, F., Kennedy, A. K., Villa, I. M., Lagos, M., and Ballhaus, C., 2003, Zircons from Syros, Cyclades, Greece-recrystallization and mobilization of zircon during high-pressure metamorphism: Journal of Petrology, v. 44, p. 1977-2002, doi:10.1093/petrology/egg067. (Pubitemid 38149428)
68. Tovbin, M. V., and Krasnova, S. I., 1951, Stability of supersaturated solutions of salts: Russian Journal of Physical Chemistry A, v. 25, p. 161-166 (in Russian).
69. Walker, F. D. L., Lee, M. R., and Parsons, I., 1995, Micropores and micropermeable texture in alkalifeldspars: geochemical and geophysical implications: Mineralogical Magazine, v. 59, n. 3, p. 505-534, doi:10.1180/minmag.1995.059.396.12. (Pubitemid 26475561)
70. Xia, F., Brugger, J., Chen, G., Ngothai, Y., O'Neill, B., Putnis, A., and Pring, A., 2009, Mechanism and kinetics of pseudomorphic mineral replacement reactions: A case study on the replacement of pentlandite by violarite: Geochimica et Cosmochimica Acta, v. 73, n. 7, p. 1945-1969, doi:10.1016/j.gca. 2009.01.007.
71. Yanagisawa, K., Rendón-Angeles, J. C., Ishizawa, N., and Oishi, S., 1999, Topotaxial replacement of chloroapatite by hydroxyapatite during hydrothermal ion exchange: American Mineralogist, v. 84, n. 11-12, p. 1861-1869. (Pubitemid 30109866)