Electrocatalytic oxidation of sodium borohydride on metal ad-atom modified Au(111) single crystal electrodes in alkaline solution

International Journal of Hydrogen Energy

Volumn 36, Issue 20, 2011, Pages 12678-12685

  Ulubay Karabiberoǧlu, Ükriye ^a   Pelit, Levent ^a   Gelmez, Buket ^a   Dursun, Zekerya ^a  

^a EGE UNIVERSITY   (Turkey)

Author keywords

Au(111) single crystal electrode; Borohydride oxidation; Cd ad atom; Fuel cell; Pt ad atom; Zn ad atom

Indexed keywords

AD-ATOM MODIFIED ELECTRODES; ALKALINE MEDIA; ALKALINE SOLUTIONS; AU(1 1 1 ); BARE ELECTRODE; BOROHYDRIDE OXIDATION; BOROHYDRIDES; CD AD-ATOM; CONCENTRATION RANGES; ELECTRICAL CONTACTS; ELECTRO-CATALYTIC OXIDATION; ELECTRON TRANSFER; NEGATIVE POTENTIAL; OXIDATION PEAK; PEAK CURRENTS; PEAK POTENTIALS; POLYCRYSTALLINE; POSITIVE SHIFT; SINGLE CRYSTAL ELECTRODES; SODIUM BOROHYDRIDES;

ATOMS; CATALYST ACTIVITY; CATALYTIC OXIDATION; ELECTROCATALYSIS; ELECTROCHEMICAL OXIDATION; FUEL CELLS; PLATINUM; SINGLE CRYSTALS; SODIUM; ZINC;

ELECTROCHEMICAL ELECTRODES;

EID: 80052936442     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.06.123     Document Type: Article

References (37)

1. B.C. Chan, R. Liu, K. Jambunathan, H. Zhang, G. Chen, and T.E. Mallouk Comparison of high throughput electrochemical methods for testing direct methanol fuel cell anode electrocatalysts J Electrochem Soc 152 2005 A594 A600
2. C. Coutanceau, R.K. Koffi, J.-M. Léger, K. Marestin, R. Mercier, and C. Nayoze Development of materials for mini DMFC working at room temperature for portable applications J Power Source 160 2006 334 339 (Pubitemid 44344396)
3. E. Peled, V. Livshits, and T. Duvdevani High-power direct ethylene glycol fuel cell (DEGFC) based on nanoporous proton-conducting membrane (NP-PCM) J Power Source 106 2002 245 248
4. S.C. Amendola, P. Onnerud, M.T. Kelly, P.J. Petillo, S.L. Sharp-Goldman, and M. Binder A novel high power density borohydride-air cell J Power Source 84 1999 130 133 (Pubitemid 32082643)
5. H. Dong, R. Feng, X. Ai, Y. Cao, H. Yang, and C. Cha Electrooxidation mechanisms and discharge characteristics of borohydride on different catalytic metal surfaces J Phys Chem B 109 2005 10896 10901 (Pubitemid 40844526)
6. B.H. Liu, Z.P. Li, and S. Suda Electrocatalysts for the anodic oxidation of borohydrides Electrochim Acta 49 2004 3097 3105
7. E. Gyenge Electrooxidation of borohydride on platinum and gold electrodes: implications for direct borohydride fuel cell Electrochim Acta 49 2004 965 978
8. Z.P. Li, B.H. Liu, K. Arai, K. Asaba, and S. Suda Evaluation of alkaline borohydride solutions as the fuel for fuel cell J Power Source 126 2004 28 33 (Pubitemid 41331270)
9. B.H. Liu, Z.P. Li, K. Arai, and S. Suda Performance improvement of a micro borohydride fuel cell operating at ambient conditions Electrochim Acta 50 2005 3719 3725 (Pubitemid 40710281)
10. N.A. Choudhury, R.K. Raman, S. Sampath, and A.K. Shukla An alkaline direct borohydride fuel cell with hydrogen peroxide as oxidant J Power Source 143 2005 1 8
11. C. Ponce de Leon, F.C. Walsh, A. Rose, J.B. Lakeman, D.J. Browning, and R.W. Reeve A direct borohydride-acid peroxide fuel cell J Power Source 164 2007 441 448 (Pubitemid 46109197)
12. J.H. Morris, H.J. Gysing, and D. Reed Electrochemistry of boron compounds Chem Rev 85 1985 51 76
13. M.V. Mirkin, H. Yang, and A.J. Bard Borohydride oxidation at a gold electrode J Electrochem Soc 139 1992 2212 2217
14. M.E. Indig, and R.N. Snyder Sodium borohydride, an interesting anodic fuel J Electrochem Soc 109 1962 1104 1106
15. - electro-oxidation on Au and Ag catalysts Electrochim Acta 51 2006 5459 5467 (Pubitemid 44088395)
16. H. Cheng, and K. Scott Determination of kinetic parameters for borohydride oxidation on a rotating Au disk electrode Electrochim Acta 51 2006 3429 3433
17. S. Ben-Aoun, Z. Dursun, T. Koga, G.S. Bang, T. Sotomura, and I. Taniguchi Effect of metal ad-layers on Au(111) electrodes on electrocatalytic oxidation of glucose in an alkaline solution J Electroanal Chem 567 2004 175 183
18. Z. Dursun, L. Pelit, and I. Taniguchi Voltammetric determination of ascorbic acid and dopamine simultaneously at a single crystal Au(111) electrode Turk J Chem 33 2009 223 231
19. J.L. Gong, and C.B. Mullins Surface science investigations of oxidative chemistry on gold Acc Chem Res 42 2009 1063 1073
20. X.Y. Geng, H.M. Zhang, W. Ye, Y.W. Ma, and H.X. Zhong Ni-Pt/C as anode electrocatalyst for a direct borohydride fuel cell J Power Source 185 2008 627 632
21. C. Ponce-de-León, D.V. Bavykin, and F.C. Walsh The oxidation of borohydride ion at titanate nanotube supported gold electrodes Electrochem Commun 8 2006 1655 1660 (Pubitemid 44528334)
22. S. Ben-Aoun, Z. Dursun, T. Sotomura, and I. Taniguchi Effect of metal ad-layers on Au(111) electrodes on electrocatalytic reduction of oxygen in an alkaline solution Electrochem Commun 6 2004 747 752
23. A. Hamelin Cyclic voltammetry at gold single-crystal surfaces. Part 1. Behaviour at low-index faces J Electroanal Chem 407 1996 1 11 (Pubitemid 126368976)
24. M.D. Lay, K. Varazo, N. Srisook, and J.L. Stickney Cd underpotential deposition (upd) from sulfate on Au(111): studies by in-situ STM and UHV-EC J Electroanal Chem 554-555 2003 221 231
25. M. Nakamura, A. Aramata, A. Yamagishi, and M. Taniguchi Underpotential deposition of zinc ions on Au(111) in phosphate solution (pH 4.6): kinetic and STM studies J Electroanal Chem 446 1998 227 231 (Pubitemid 128408525)
26. L.A. Kibler, M. Kleinert, R. Randler, and D.M. Kolb Initial stages of Pd deposition on Au(hkl) Part I: Pd on Au(111) Surf Sci 443 1999 19 30 (Pubitemid 129588393)
27. H.F. Waibel, M. Kleinert, L.A. Kibler, and D.M. Kolb Initial stages of Pt deposition on Au(111) and Au(100) Electrochem Acta 47 2002 1461 1467 (Pubitemid 34187496)
28. X. Geng, H. Zhang, Y. Ma, and H. Zhong Borohydride electrochemical oxidation on carbon-supported Pt-modified Au nanoparticles J Power Source 195 2009 1583 1588
29. M. Chatenet, F.H.B. Lima, and E.A. Ticianelli Gold is not a Faradaic-efficient borohydride oxidation electrocatalyst: an online electrochemical mass spectrometry study J Electrochem Soc 157 2010 B697 B704
30. E. Gyenge, M. Atwan, and D. Northwood Electrocatalysis of borohydride oxidation on colloidal Pt and Pt-alloys (Pt-Ir, Pt-Ni, and Pt-Au) and application for direct borohydride fuel cell anodes J Electrochem Soc 153 2006 A150 A158
31. B.M. Concha, and M. Chatenet Direct oxidation of sodium borohydride on Pt, Ag and alloyed Pt-Ag electrodes in basic media. Part I: bulk electrodes Electrochim Acta 54 2009 6119 6129
32. B.M. Concha, and M. Chatenet Direct oxidation of sodium borohydride on Pt, Ag and alloyed Pt-Ag electrodes in basic media: Part II. Carbon-supported nanoparticles Electrochim Acta 54 2009 6130 6139
33. A.P. Pavlov, L.K. Grigorieva, S.P. Chizhik, and V.K. Stankov Nickel-zinc batteries with long cycle life J Power Source 62 1996 113 116 (Pubitemid 126364595)
34. R.M. Dell Batteries: fifty years of materials development Solid State Ion 134 2000 139 158 (Pubitemid 32033523)
35. Y. Shen, and K. Kordesch The mechanism of capacity fade of rechargeable alkaline manganese dioxide zinc cells J Power Source 87 2000 162 166 (Pubitemid 30585583)
36. A.P. Karpinski, B. Makovetski, S.J. Russell, J.R. Sevenyi, and D.C. Williams Silver-zinc: status of technology and applications J Power Source 80 1999 53 60
37. H. Celikkan, M. Sahin, M.L. Aksu, and T.N. Veziroglu The investigation of the electrooxidation of sodium borohydride on various metal electrodes in aqueous basic solutions Int J Hydrogen Energy 32 2007 588 593 (Pubitemid 46330634)