Facile synthesis of gold-nanoparticles-decorated polymer assemblies and core-shell gold nanoparticles using Pluronic block copolymers

Guocheng Gongcheng Xuebao/The Chinese Journal of Process Engineering

Volumn 11, Issue 4, 2011, Pages 711-715

  Shou, Qing Hui ^a,b   Guo, Chen ^a   Gao, Hong Shuai ^a   Zhou, Hua Cong ^a,b   Liu, Chun Zhao ^a   Liu, Hui Zhou ^a  

^a INSTITUTE OF PROCESS ENGINEERING   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Assembly; Core shell structure; Gold nanoparticles; Nanocomposite; Pluronic

Indexed keywords

EID: 80052875988     PISSN: 1009606X     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (24)

1. Ajayan P M, Tour J M. Materials Science-Nanotube Composites[J]. Nature, 2007, 447(7148): 1066-1068.
2. Balazs A C, Emrick T, Russell T P. Nanoparticle Polymer Composites: Where Two Small Worlds Meet [J]. Science, 2006, 314(5802): 1107-1110.
3. Zhang H, Han J S, Yang B. Structural Fabrication and Functional Modulation of Nanoparticle-Polymer Composites[J]. Adv. Funct. Mater., 2010, 20(10): 1533-1550.
4. Kang Y J, Taton T A. Core/Shell Gold Nanoparticles by Self-assembly and Crosslinking of Micellar, Block-copolymer Shells[J]. Angew. Chem. Int. Ed., 2005, 44(3): 409-412.
5. Zheng P W, Jiang X W, Zhang X, et al. Formation of Gold@Polymer Core-Shell Particles and Gold Particle Clusters on a Template of Thermoresponsive and ph-responsive Coordination Triblock Copolymer[J]. Langmuir, 2006, 22(22): 9393-9396.
6. Zhang Y, Wang L, Tian J, et al. Ag@Poly(m-phenylenediamine) Core-Shell Nanoparticles for Highly Selective, Multiplex Nucleic Acid Detection[J]. Langmuir, 2011, 27(6): 2170-2175.
7. Li D X, Li C F, Wang A H, et al. Hierarchical Gold/Copolymer Nanostructures as Hydrophobic Nanotanks for Drug Encapsulation[J]. J. Mater. Chem., 2010, 20(36): 7782-7787.
8. 2 Activation: An Unexpected Catalytic Activity of Polymer-supported Nanogold[J]. J. Am. Chem. Soc, 2005, 127(12): 4182-4183.
9. Haruta M, Ishida T. Gold Catalysts: Towards Sustainable Chemistry[J]. Angew. Chem. Int. Ed., 2007, 46(38): 7154-7156.
10. Ofir Y, Samanta B, Rotello V M. Polymer and Biopolymer Mediated Self-assembly of Gold Nanoparticles[J]. Chem. Soc. Rev., 2008, 37(9): 1814-1823.
11. Sidorov S N, Bronstein L M, Kabachii Y A, et al. Influence of Metalation on the Morphologies of Poly(ethylene oxide)-Block-poly(4-vinylpyridine) Block Copolymer Micelles[J]. Langmuir, 2004, 20(9): 3543-3550.
12. Meristoudi A, Pispas S, Vainos N. Self-assembly in Solutions of Block and Random Copolymers during Metal Nanoparticle Formation[J]. J. Polym. Sci., Part B: Polym. Phys., 2008, 46(14): 1515-1524.
13. Papp S, Korosi L, Gool B, et al. Formation of Gold Nanoparticles in Diblock Copolymer Micelles with Various Reducing Agents[J]. J. Therm. Anal. Calorim., 2010, 101(3): 865-872.
14. Hickey R J, Haynes A S, Kikkawa J M, et al. Controlling the Self-assembly Structure of Magnetic Nanoparticles and Amphiphilic Block-copolymers: From Micelles to Vesicles[J]. J. Am. Chem. Soc, 2011, 133(5): 1517-1525.
15. Rahme K, Oberdisse J, Schweins R, et al. Pluronics-stabilized Gold Nanoparticles: Investigation of the Structure of the Polymer-Particle Hybrid[J]. Chemphyschem., 2008, 9(15): 2230-2236.
16. Lam Y M, Grigorieff N, Goldbeck-Wood G. Direct Visualisation of Micelles of Pluronic Block Copolymers in Aqueous Solution by Cryo-TEM[J]. Phys. Chem. Chem. Phys., 1999, 1(14): 3331-3334.
17. Sakai T, Alexandridis P. Mechanism of Gold Metal Ion Reduction, Nanoparticle Growth and Size Control in Aqueous Amphiphilic Block Copolymer Solutions at Ambient Conditions[J]. J. Phys. Chem. B, 2005, 109(16): 7766-7777.
18. Goy-Lopez S, Taboada P, Cambon A, et al. Modulation of Size and Shape of Au Nanoparticles Using Amino-X-shaped Poly(ethylene oxide)-Poly(propylene oxide) Block Copolymers[J]. J. Phys. Chem. B, 2010, 114(1): 66-76.
19. Abdullin T I, Bondar O V, Shtyrlin Y G, et al. Pluronic Block Copolymer-mediated Interactions of Organic Compounds with Noble Metal Nanoparticles for SERS Analysis[J]. Langmuir, 2010, 26(7): 5153-5159.
20. Guo C, Wang J, Liu H Z, et al. Hydration and Conformation of Temperature-dependent Micellization of PEO-PPO-PEO Block Copolymers in Aqueous Solutions by FT-Raman[J]. Langmuir, 1999, 15(8): 2703-2708.
21. Chen S, Guo C, Hu G H, et al. Effect of Hydrophobicity inside PEO-PPO-PEO Block Copolymer Micelles on the Stabilization of Gold Nanoparticles: Experiments[J]. Langmuir, 2006, 22(23): 9704-9711.
22. Liu H L, Hou P, Zhang W X, et al. The Synthesis and Characterization of Polymer-coated FeAu Multifunctional Nanoparticles[J]. Nanotechnology, 2010, 21(33): 335602.
23. Zhang C X, Zhang J L, Han B X, et al. Synthesis of Icosahedral Gold Particles by a Simple and Mild Route[J]. Green Chem., 2008, 10(10): 1094-1098.
24. Yang B, Guo C, Chen S, et al. Effect of Acid on the Aggregation of Poly(ethylene oxide)-Poly(propylene xide)-Poly(ethylene oxide) Block Copolymers[J]. J. Phys. Chem. B, 2006, 110(46): 23068-23074.