Intrinsic kinetics for the synthesis of acetonitrile from ethanol and ammonia over Co-Ni/γ-Al2O3 catalyst

Chemical Engineering Research and Design

Volumn 89, Issue 10, 2011, Pages 2147-2152

  Zhang, Di ^a   Zhang, Yuecheng ^a   Wen, Yanlong ^a   Hou, Kaihu ^a   Zhao, Jiquan ^a  

^a HEBEI UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Acetonitrile; Co Ni Al2O3 catalyst; Fixed bed reactor; Intrinsic kinetics; Power law model

Indexed keywords

AMMONIA CONCENTRATIONS; CATALYST VOLUME; EXPERIMENTAL DATA; FEED VELOCITY; FIXED-BED REACTORS; INTRINSIC KINETICS; MATLAB- SOFTWARE; MODEL PARAMETERS; POWER LAW MODEL; REACTION KINETIC MODELS; REACTION ORDERS; REACTION TEMPERATURE; REACTOR PRESSURES;

ACETONITRILE; ACTIVATION ENERGY; ALUMINUM; AMMONIA; CATALYSTS; CHEMICAL REACTORS; ETHANOL; INDEXING (OF INFORMATION); KINETICS;

SYNTHESIS (CHEMICAL);

EID: 80052802946     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2011.01.029     Document Type: Article

References (31)

1. Badani M.V., et al. Acetonitrile synthesis from CO, H2, and NH3 over Fe/C and K, Fe/C. Stud. Surf. Sci. Catal. 1993, 75:1223-1234.
2. Bussche K.M.V., Froment G.F. A steady-state kinetic model for methanol synthesis and the water gas shift reaction on a commercial Cu/Zno/Al2O3 catalyst. J. Catal. 1996, 161:1-10.
3. Callahan, J.L., Stamm, J.A., 1963. Method for the manufacture of acetonitrile. US Patent 3106574.
4. Cao C.S., et al. Kinetic studies of methanol steam reforming over Pd/ZnO catalyst using a microchannel reactor. Appl. Catal. A 2004, 262:19-29.
5. Card R.J., Schmitt J.L. Gas-phase synthesis of nitrile. J. Org. Chem. 1981, 46:754-757.
6. Eshelman L.M., Delgass W.N. Acetonitrile synthesis over potassium-promoted, supported iron catalyst. Catal. Today 1994, 21:229-242.
7. Feng C., et al. Study on alumina-supported cobal-nickel oxide catalyst for synthesis of acetonitrile from ethanol. Catal. Lett. 2011, 141:168-177.
8. Fierce, W.L., et al., 1957. Preparation of acetonitrile. US Patent 2802020.
9. Fierce, W.L., et al., 1962. Preparation of nitriles by catalyzed reaction of alkynes with hydrogen cyanide or cyanogen. US Patent 3056826.
10. Fierce, W.L., Sandner, W.J., 1959. Preparation of acetonitrile. CA Patent 586008.
11. Hou X.M., et al. The study of synthesizing acetonitrile over SO42-/ZrO2-Al2O3. J. Jilin Normal Univ. (Nat. Sci. Ed.) 2009, 30:108-109.
12. Huang H.J. Practical Computer Simulation of Chemical Processes-Matlab's Application in Chemical Engineering 2004, Chemical Industry Press, Beijing. First ed.
13. Hummel A.A., et al. Acetonitrile synthesis from CO, H2, and NH3 over iron catalysts. J. Catal. 1993, 139:392-405.
14. Idem R.O., Bakhshi N.N. Kinetic modeling of the production of hydrogen from the methanol-stream reforming process over Mn-promoted coprecipitated Cu-Al catalyst. Chem. Eng. Sci. 1996, 51:3697-3780.
15. Krebaum, L.J., 1964. Preparation of acetonitrile. US Patent 3129241.
16. Kulkarni S.J., et al. Ammoxidation of ethanol to acetonitrile over molecular sievest. J. Chem. Soc., Chem. Commun. 1994, 3:273.
17. Kurina, L.N., et al., 2003. Acetonitrile synthesis method. RU Patent 2214396.
18. Li Y.J., Armor J.N. Ammoxidation of ethane to acetonitrile over metal-zeolite catalysts. J. Catal. 1998, 173:511-518.
19. Mies M.J.M., et al. High-throughput screening of Co-BEA and Co-ZSM-5 coatings in the ammoxidation of ethylene to acetonitrile in microstructured reactor. Chem. Eng. Sci. 2007, 62:5097-5101.
20. Mies M.J.M., et al. Method for the in situ preparation of a single layer of zeolite beta crystals on a molybdenum substrate for microreactor applications. J. Catal. 2007, 247:328-338.
21. Morikawa, K., Shiba, T., 1961. Improvements in or relating to the production of acetonitrile. GB Patent 870462.
22. Olivé, G., Olivé, S., 1979. Process for preparing acetonitrile. US Patent 4179462.
23. Potaraju, R., Vishnu, J.M., 1986. Process for the production of acetonitrile. EP Patent 0206632.
24. Reddy B.M., Manohar B. One step synthesis of acetonitrile from ethanol via ammoxidation over Sb-V-P-O/Al2O3 catalyst. J. Chem. Soc., Chem. Commun. 1993, 3:234-235.
25. Sandner, W.J., Fierce, W.L., 1961. Preparation of acetonitrile. CA Patent 615929.
26. Stamm, J.A., Callahan, J.L., 1965. Callahan. Method for the manufacture of acetonitrile. CA Patent 718 939 A.
27. Thomas B., et al. Dehydration of aldoximes over H-zeolites: a convenient and highly atom economic method for the preparation of nitriles. Chem. Eng. J. 2007, 133:59-68.
28. Weekman V.W. Laboratory reactors and their limitation. AIChE J. 1974, 20:833-840.
29. Zhang, H.T., et al., 2005. Ethanol ammoxidizing process to synthesize high-purity acetonitrile. CN Patent 1226281.
30. Zhang Y.N., et al. Amination of ethanol to acetonitrile over Ni-doped Co/γ-Al2O3 catalyst. Catal. Commun. 2009, 10:1454-1458.
31. Zhu B.C., et al. The engineering and chemical reactions. Laboratory Reactors 2001, 503-504. Chemical Industry Press, Beijng. Third ed. B.C. Zhu (Ed.).