Synthesis of methyl esters from palm (Elaeis guineensis) oil using cobalt doped MgO as solid oxide catalyst

Bioresource Technology

Volumn 102, Issue 20, 2011, Pages 9749-9754

  Ab Rahman, Nur Ashikin ^a   Olutoye, M A ^a   Hameed, B H ^a  

^a SCHOOL OF CHEMICAL ENGINEERING   (Malaysia)

Author keywords

Methyl ester; Palm oil; Solid oxide catalyst; Transesterification

Indexed keywords

ACTIVE SITE; CATALYST LOADINGS; ELAEIS GUINEENSIS; METAL HYDROXIDE; METHYL ESTERS; MOLAR RATIO; PALM OIL; REACTION MIXTURE; REACTION TEMPERATURE; REUSABLE CATALYSTS; SOLID OXIDE; SOLID OXIDE CATALYST;

CALCINATION; COBALT; ESTERIFICATION; ESTERS; LEACHING; METHANOL; PRECIPITATION (CHEMICAL); SYNTHESIS (CHEMICAL); TRANSESTERIFICATION; VEGETABLE OILS;

CATALYST ACTIVITY;

COBALT; ESTER; HYDROXIDE; MAGNESIUM OXIDE; METHANOL; PALM OIL;

CATALYST; COBALT; ESTER; EVERGREEN TREE; HYDROXIDE; INDUSTRIAL PRODUCTION; MAGNESIUM; REACTION KINETICS; VEGETABLE OIL;

ARTICLE; CATALYST; NONHUMAN; PRIORITY JOURNAL; TEMPERATURE;

CATALYSIS; COBALT; ESTERS; MAGNESIUM OXIDE; MICROSCOPY, ELECTRON, SCANNING; PLANT OILS; REGRESSION ANALYSIS;

ELAEIS GUINEENSIS;

EID: 80052778364     PISSN: 09608524     EISSN: 18732976     Source Type: Journal    
DOI: 10.1016/j.biortech.2011.07.023     Document Type: Article

References (21)

1. Albuquerque M.C.G., Jose S.G., Josefa M.M.R., Ramon M.T., Enrique R.C., Antonio J.L., Diana C.S.A., Pedro M.T. MgM (M = Al and Ca) oxides as basic catalysts in transesterification processes. Appl. Catal. A: Gen. 2008, 347:162-168.
2. Arizaga G.G.C., Satyanarayana K.G., Wypych F. Layered hydroxide salts: synthesis, properties and potential applications. Solid State Ion. 2007, 178:1143-1162.
3. Dizge N., Aydiner C., Imer D.Y., Bayramoglu M., Tanriseven A., Keskinler B. Biodiesel production from sunflower, soybean, and waste cooking oils by transesterification using lipase immobilized onto a novel microporous polymer. Bioresour. Technol. 2009, 100:1983-1991.
4. Granados M.L., Poves M.D.Z., Alonso D.M., Mariscal R., Galisteo F.C., Santamaria J., Fierro J.L.G. Biodiesel from sunflower oil by using activated calcium oxide. Appl. Catal. B: Environ. 2007, 73:317-326.
5. Hameed B.H., Goh C.S., Chin L.H. Process optimization for methyl ester production from waste cooking oil using activated carbon supported potassium fluoride. Fuel Process. Technol. 2009, 90:1532-1537.
6. Hameed B.H., Lai L.F., Chin L.H. Production of biodiesel from palm oil (Elaeis guineensis) using heterogeneous catalyst: an optimized process. Fuel Process. Technol. 2009, 90:606-610.
7. Issariyakul T., Kulkarni M.G., Meher L.C., Dalai A.K., Bakhshi N.N. Biodiesel production from mixtures of canola oil and used cooking oil. Chem. Eng. J. 2008, 140:77-85.
8. Kaya C., Hamamci C., Baysal A., Akba O., Erdogan S., Saydut A. Methyl ester of peanut (Arachis hypogea L.) seed oil as a potential feedstock for biodiesel production. Renew. Energ. 2009, 34:1257-1260.
9. Li E., Xu Z.P., Rudolph V. MgCoAl-LDH derived heterogeneous catalysts for the ethanol transesterification of canola oil to biodiesel. Appl. Catal. B: Environ. 2009, 88:42-49.
10. Li H., Xie W. Fatty acid methyl ester synthesis over Fe3+-vanadyl phosphate catalysts. J. Am. Oil Chem. Soc. 2008, 85:655-662.
11. Munari, F., Cavagnino, D., Cadoppi, A., 2007. Thermo Fisher Scientific, Milan, Italy, Application Note: 10212.
12. Ngamcharussrivichai C., Nunthasanti P., Tanachai S., Bunyakiat K. Biodiesel production through transesterification over natural calciums. Fuel Process. Technol. 2010, 91:1409-1415.
13. Olutoye M.A., Hameed B.H. KyMg1-xZn1+xO3 as a heterogeneous catalyst in the transesterification of palm oil to fatty acid methyl esters. Appl. Catal. A: Gen. 2009, 371:191-198.
14. Olutoye M.A., Hameed B.H. Transesterification of palm oil on KyMg1-xZn1+xO3 catalyst: effect of Mg-Zn interaction. Fuel Process. Technol. 2010, 91:653-659.
15. Olutoye M.A., Hameed B.H. Synthesis of fatty acid methyl ester from used cooking oil by solid reusable Mg1-xZn1+xO2 catalyst. Bioresour. Technol. 2011, 104:3819-3826.
16. Peng B.X., Shu Q., Wang J.F., Wang G.R., Wang D.Z., Han M.H. Biodiesel production from waste oil feedstocks by solid acid catalysis. Process Saf. Environ. 2008, 86:441-447.
17. Rao K.N., Sridhar A., Lee A.F., Stewart J.T., Nigel A.Y., Karen W. Zirconium phosphate supported tungsten oxide solid acid catalysts for the esterification of palmitic acid. Green Chem. 2006, 8:790-797.
18. Sahoo P.K., Das L.M. Process optimization for biodiesel production from jatropha, karanja and polanga oils. Fuel 2009, 88:1588-1594.
19. Sharma Y.C., Singh B., Upadhyay S.N. Advancements in development and characterization of biodiesel: a review. Fuel 2008, 87:2355-2373.
20. Sree R., Babu N.S., Prasad P.S., Lingaiah N. Transesterification of edible and non-edible oils basic solid Mg/Zr catalysts. Fuel Process. Technol. 2009, 90:152-157.
21. Wen Z., Yu X., Tu S.T., Yan J., Dahlquist E. Biodiesel production from waste cooking oil catalyzed by TiO2-MgO mixed oxides. Bioresour. Technol. 2010, 101:9570-9576.