Catalytic hydrolysis of borohydride for fuel cells

Chinese Journal of Chemical Engineering

Volumn 19, Issue 4, 2011, Pages 693-697

  Wang, Lianbang ^a   Zhan, Xingyue ^a   Yang, Zhenzhen ^a   Ma, Chun'An ^a  

^a ZHEJIANG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

borohydride; catalytic hydrolysis; fuel cell; Mg Ni composite

Indexed keywords

BOROHYDRIDES; CATALYTIC HYDROLYSIS; CO-DOPED; CO-DOPING; ELECTROCHEMICAL POWER GENERATION; HYDROGEN GENERATIONS; HYDROGEN SOURCES; HYDROLYSIS RATE; LOW COSTS; MECHANICALLY ALLOYING; MG-NI COMPOSITE;

CATALYST ACTIVITY; DIRECT BOROHYDRIDE FUEL CELLS (DBFC); GAS FUEL PURIFICATION; HYDROGEN; HYDROGEN PRODUCTION;

HYDROLYSIS;

EID: 80052747294     PISSN: 10049541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1004-9541(11)60043-8     Document Type: Article

References (17)

1. M.E. Indig, R.N. Snyder "Sodium borohydride, an interesting anodic fuel" J. Electrochem. Soc. 109 1962 1104 1106
2. S.C. Amendola, P. Onnerud, M. Kelly, P. Petillo, S.L. Sharp-Goldman, M. Binder "A novel high power density borohydride-air cell" J. Power Sources 84 1999 130 133 (Pubitemid 32082643)
3. S.M. Lee, J.H. Kim, H.H. Lee, P.S. Lee, J.Y. Lee "The characterization of an alkaline fuel cell that uses hydrogen storage alloys" J. Electrochem. Soc. 149 2002 A603 A606
4. Z.P. Li, B.H. Liu, K. Arai, S. Suda "A fuel cell development for using borohydrides as the fuel" J. Electrochem. Soc. 150 2003 A868 A872
5. El'od Gyenge "Electrooxidation of borohydride on platinum and gold electrodes: Implications for direct borohydride fuel cells" Electrochim. Acta 49 2004 965 978
6. S.C. Amendola, S.L. Sharp-Goldman, M. Saleem Janjua, N.C. Spencer, M.T. Kelly, P.J. Petillo, M. Binder "A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst" Int. J. Hydrogen Energy 25 2000 969 975
7. 4 solution using the high-performance Co-B catalyst" J. Power Sources 144 2005 129 134
8. Y. Kojima, K. Suzuki, K. Fukumoto, Y. Kawai, M. Kimbara, H. Nakaishi, S. Matsumoto "Development of 10 kW-scale hydrogen generator using chemical hydride" J. Power Sources 125 2004 22 26 (Pubitemid 41331275)
9. V.C.Y. Kong, F.R. Foulkes, D.W. Kirk, J.T. Hinatsu "Development of hydrogen storage for fuel cell generators. I: Hydrogen generation using hydrolysishydrides" Int. J. Hydrogen Energy 24 1999 665 675
10. H.I. Schlesinger, H.C. Brown, A.E. Finholt, J.R. Gilbreath, H.R. Hoekstra, E.K. Hyde "The preparation of sodium borohydride by the high temperature reaction of sodium hydride with borate esters" J. Am. Chem. Soc. 75 1953 215 219
11. S.C. Amendola, S.L. Sharp-Goldman, M. Saleem Janjua, M.T. Kelly, P.J. Petillo, M. Binder "An ultrasafe hydrogen generator: Aqueous alkaline borohydride solutions and Ru catalyst" J. Power Sources 85 2000 186 189 (Pubitemid 30556664)
12. A. Levy, J.B. Brown, C.J. Lyons "Catalyzed hydrolysis of sodium borohydride" Ind. Eng. Chem. 52 1960 211 214
13. C.M. Kaufman, B. Sen "Hydrogen generation by hydrolysis of sodium tetrahydroborate: Effects of acids and transition metals and their salts" J. Chem. Soc.; Dalton Trans. 1985 307 313
14. S. Suda, Y.M. Sun, B.H. Liu, Y. Zhou, S. Morimitsu, K. Arai, N. Tsukamoto, Y. Candra, Z.P. Li "Fluorinated metal hydrides for the catalytic hydrolysis of metal-hydrogen complexes" Metals Mater. Int. 7 2001 73 75 (Pubitemid 33574994)
15. L.B. Wang, C.A. Ma, X.B. Mao, J.F. Sheng, F.Z. Bai, F. Tang "Rare earth hydrogen storage alloy used in borohydride fuel cell" Electrochem. Commun. 7 2005 1477 1481 (Pubitemid 41660216)
16. L.B. Wang, C.A. Ma, X.B. Mao "LmNi(4.78)Mn(0.22) alloy modified with Si used as anodic materials in borohydride fuel cells" J. Alloy. Compd. 397 2005 313 316
17. 0.5 alloy doped with Au used as anodic materials in a borohydride fuel cell" J. Power Sources 184 2008 260 264