Production of biodiesel by esterification of natural fatty acids over modified organoclay catalysts

Fuel

Volumn 90, Issue 11, 2011, Pages 3382-3389

  Ghiaci, M ^a   Aghabarari, B ^a   Gil, A ^b  

^a ISFAHAN UNIVERSITY OF TECHNOLOGY   (Iran)

^b PUBLIC UNIVERSITY OF NAVARRE   (Spain)

Author keywords

Bentonite; Biodiesel; Ionic liquid; Natural fatty acids; Transesterification

Indexed keywords

ACIDIC IONIC LIQUIDS; HYDROGENSULFATE; METHYL ESTERS; MODIFIED BENTONITES; MOLAR RATIO; NATURAL FATTY ACIDS; OPTIMIZED REACTION CONDITIONS; REACTION TEMPERATURE; RECYCLABILITY;

BENTONITE; BIODIESEL; BUTANE; ESTERIFICATION; ESTERS; IONIC LIQUIDS; METHANOL; OLEIC ACID;

CATALYST ACTIVITY;

EID: 80052741069     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2011.04.008     Document Type: Article

References (30)

1. M. Balat, and H. Balat A critical review of bio-diesel as a vehicular fuel Energy Convers Manage 49 2008 2727 2741
2. A.C. Carmo Jr, L.K.C. de Souza, C.E.F. da Costa, E. Longo, J.R. Zamian, and G.N. da Rocha Filho Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41 Fuel 88 2009 461 468
3. D. Martín Alonso, M. López Granados, R. Mariscal, and A. Douhal Polarity of the acid chain of esters and transesterification activity of acid catalysts J Catal 262 2009 18 26
4. M. Zabeti, W.M.A. Wan Daud, and M.K. Aroua Activity of solid catalysts for biodiesel production: a review Fuel Process Technol 90 2009 770 777
5. B.M.E. Russbueldt, and W.F. Hoelderich New sulfonic acid ion-exchange resins for the preesterification of different oils and fats with high content of free fatty acids Appl Catal A Gen 362 2009 47 57
6. Juan. JCh, J. Zhang, and M.A. Yarmo Structure and reactivity of silica-supported zirconium sulfate for esterification of fatty acid under solvent-free condition Appl Catal A Gen 332 2007 209 215 (Pubitemid 47562734)
7. M. Di Serio, R. Tesser, L. Pengmei, and E. Santacesaria Heterogeneous catalysts for biodiesel production Energy Fuels 22 2008 207 217 (Pubitemid 351233455)
8. R. Jothiramalingam, and M.K. Wang Review of recent developments in solid acid, base, and enzyme catalysts (heterogeneous) for biodiesel production via transesterification Ind. Eng. Chem. Res. 48 2009 6162 6172
9. S. Semwal, A.K. Arora, R.P. Badoni, and D.K. Tuli Biodiesel production using heterogeneous catalysts Bioresour Technol 102 2011 2151 2161
10. L. Xu, X. Yang, X. Yu, and Y. Guo Preparation of mesoporous polyoxometalate-tantalum pentoxide composite catalyst for efficient esterification of fatty acid Catal Commun 9 2008 1607 1611
11. Juan. JCh, J. Zhang, and M.A. Yarmo Study of catalysts comprising zirconium sulfate supported on a mesoporous molecular sieve HMS for esterification of fatty acids under solvent-free condition Appl Catal A Gen 347 2008 133 141
12. L. Nuttapol, A. Nourredine, A. Luke, and A. Foster Mechanistic modeling of palmitic acid esterification via heterogeneous catalysis Ind. Eng. Chem. Res. 50 2011 1177 1186
13. C.S. Caetano, L. Guerreiro, I.M. Fonseca, A.M. Ramos, J. Vital, and J.E. Castanheiro Esterification of fatty acids to biodiesel over polymers with sulfonic acid groups Appl Catal A Gen 359 2009 41 46
14. J.A. Melero, L.F. Bautista, G. Morales, J. Iglesias, and R. Sánchez-Vázquez Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts Chem Eng J 161 2010 323 331
15. C.S. Caetano, I.M. Fonseca, A.M. Ramos, J. Vital, and J.E. Castanheiro Hydrolysis of sucrose using sulfonated poly(vinyl alcohol) as catalyst Catal Commun 9 2008 1996 1999
16. W.H. Awad, J.W. Gilman, M. Nyden, R.H. Harris Jr, T.E. Sutto, and J. Callahan Thermal degradation studies of alkyl-imidazolium salts and their application in nanocomposites Thermochim Acta 409 2004 3 11
17. N. Hyun, S.V. Malhotra, and M. Xanthos Modification of cationic nanoclays with ionic liquids Micropor Mesopor Mater 96 2006 29 35 (Pubitemid 44636325)
18. R. Ratti, S. Kaur, M. Vaultier, and V. Singh Preparation, characterization and catalytic activity of MMT-clay exchanged sulphonic acid functionalized ionic liquid for transesterification of β-ketoester2 Catal Commun 11 2010 503 507
19. M. Ghiaci, B. Aghabarari, S. Habibollahi, and A. Gil Highly efficient Bronsted acidic ionic liquid-based catalysts for biodiesel synthesis from vegetable oils Bioresour Technol 102 2011 1200 1204
20. L. Zhang, M. Xian, Y. He, L. Li, J. Yang, and S. Yu A Brønsted acidic ionic liquid as an efficient and environmentally benign catalyst for biodiesel synthesis from free fatty acids and alcohols Bioresour Technol 100 2009 4368 4373
21. Y. Zhao, J. Long, F. Deng, X. Liu, Z. Li, and C. Xia Catalytic amounts of Brønsted acidic ionic liquids promoted esterification: study of acidity-activity relationship Catal Commun 10 2009 732 736
22. K.J. Baranyai, G.B. Deacon, D.R. MacFarlane, J.M. Pringle, and J.L. Scott Degradation of ionic liquids at elevated temperatures Aust J Chem 57 2004 145 147
23. A. Berthod, S. Carda-Broch, and D.W. Armstrong Solvent properties of 1-butyl-3-methyl-imidazolium hexafluorophosphate ionic liquid Anal Bioanal Chem 375 2003 191 199 (Pubitemid 41201294)
24. R.E. Del Sesto, T.M. McCleskey, C. Macomber, K.C. Ott, A.T. Koppisch, and G.A. Baker Limited thermal stability of imidazolium and pyrrolidinium ionic liquids Thermochim Acta 491 2009 118 120
25. A.A. Atia Adsorption of chromate and molybdate by cetylpyridinium bentonite Appl Clay Sci 41 2008 73 84
26. N. Yilmaz, and S. Yapar Adsorption properties of tetradecyl- and hexadecyl trimethylammonium bentonites Appl Clay Sci 27 2004 223 228 (Pubitemid 39474087)
27. J.Y. Lee, and H.K. Lee Characterization of organobentonite used for polymer nanocomposites Mater Chem Phys 85 2004 410 415
28. J.-Y. Park, D.-K. Kim, and J.-S. Lee Esterification of free fatty acids using water-tolerable Amberlyst as a heterogeneous catalyst Bioresour Technol 101 2010 S62 S65
29. P.C.C. Faria, J.J.M. Órfao, and M.F.R. Pereira Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries Water Res 38 2004 2043 2052 (Pubitemid 38496203)
30. J. Clayden, N. Greeves, S. Warren, and P. Wothers Organic chemistry 2001 Oxford University Press Inc. New York