Probing the nature of the Co III ion in corrins: A comparison of the thermodynamics and kinetics of the ligand substitution reactions of aquacyanocobyrinic acid heptamethyl ester and stable yellow aquacyanocobyrinic acid heptamethyl ester

Inorganic Chemistry

Volumn 50, Issue 18, 2011, Pages 8719-8727

  Chemaly, Susan M ^a   Florczak, Melissa ^a   Dirr, Heinrich ^a   Marques, Helder M ^a  

^a UNIVERSITY OF THE WITWATERSRAND   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; CORRIN; CORRINOID; ESTER; LIGAND; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; COMPARATIVE STUDY; KINETICS; OXIDATION REDUCTION REACTION; THERMODYNAMICS;

COBALT; CORRINOIDS; ESTERS; KINETICS; LIGANDS; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; THERMODYNAMICS;

EID: 80052714635     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic200288b     Document Type: Article

References (40)

1. Chemaly, S. M., Brown, K. L., Fernandes, M. A., Munro, O. Q., Grimmer, C., and Marques, H. M. Inorg. Chem. 2011, in press.
2. Friedrich, W. Z. Naturforsch. B 1966, 21, 595-596
3. Pratt, J. M. The Inorganic Chemistry of Vitamin B12; Academic Press: London, 1972.
4. Friedrich, W.; Bieganowski, R. Z. Naturforsch. B 1967, 22, 741-747
5. Friedrich, W.; Ohlms, H.; Sandeck, W.; Bieganowski, R. Z. Naturforsch. B 1967, 22, 839-850
6. Martell, A. E.; Smith, R. M.; Motekaites, R. J. NIST Criticially Selected Stability Constants of Metal Complexes, version 8.0; NIST: Gaithersburg, MD, 2004.
7. Marques, H. M.; Bradley, J. C.; Brown, K. L.; Brooks, H. Inorg. Chim. Acta 1993, 209, 161-169
8. Broderick, K. E.; Singh, V.; Zhuang, S.; Kambo, A.; Chen, J. C.; Sharma, V. S.; Pilz, R. B.; Boss, G. R. J. Biol. Chem. 2005, 280, 8678-8685
9. Betterton, E. A. Ph.D. Thesis, The University of Witwatersrand, Johannesburg, South Africa, 1982.
10. Baldwin, D. A.; Betterton, E. A.; Pratt, J. M. J. Chem. Soc., Dalton Trans. 1983, 217-223
11. Hamza, M. S. A. Personal communication.
12. Allinger, N. L.; Yuh, Y. H.; Lii, J. H. J. Am. Chem. Soc. 1989, 111, 8551-8556
13. HyperChem, 7.05; Hypercube Ltd.: Gainesville, FL.
14. Marques, H. M.; Brown, K. L. THEOCHEM 1995, 340, 97-124
15. Marques, H. M.; Brown, K. L. Coord. Chem. Rev. 2002, 225, 123-158
16. Stewart, J. J. P. J. Comput. Chem. 1989, 10, 209-220
17. Bodor, N.; Gabanyi, Z.; Wong, C. J. Am. Chem. Soc. 1989, 111, 3783
18. Gavezotti, A. J. Am. Chem. Soc. 1983, 10, 5220
19. Ford, S. H.; Nichols, A.; Gallery, J. M. J.Chromatogr. A 1991, 536, 185-191
20. Reenstra, W. W.; Jencks, W. P. J. Am. Chem. Soc. 1979, 101, 5780-5791
21. Johnson, G. D.; Bowen, R. E. J. Am. Chem. Soc. 1965, 87, 1655
22. SigmaPlot, 11.0; Systat Software, Inc.: San Jose, CA, 2008.
23. Marques, H. M.; Munro, O. Q.; Crawcour, M. L. Inorg. Chim. Acta 1992, 196, 221-229
24. Firth, R. A.; Hill, H. A. O.; Mann, B. E.; Pratt, J. M.; Thorp, R. G.; Williams, R. J. P. J. Chem. Soc. A 1968, 2419-2428
25. Zhou, K.; Zelder, F. Eur. J. Inorg. Chem. 2011, 53-57
26. Butler, P. A.; Murtaza, S.; Kräutler, B. Monatsh. Chem. 2006, 137, 1579-1589
27. Randaccio, L.; Furlan, M.; Geremia, S.; Šlouf, M. Inorg. Chem. 1988, 37, 5390-5393
28. Perry, C. B.; Fernandes, M. A.; Brown, K. L.; Zou, X.; Valente, E. J.; Marques, H. M. Eur. J. Inorg. Chem. 2003, 2095-2107
29. Garau, G.; Geremia, S.; Marzilli, L. G.; Nardin, G.; Randaccio, L.; Tauzher, G. Acta Crystallogr., Sect. B 2003, 51-59
30. Randaccio, L.; Geremia, S.; Nardin, G.; Šlouf, M.; Srnova, I. Inorg. Chem. 1999, 38, 4087-4092
31. Randaccio, L.; Geremia, S.; Stener, M.; Toffoli, D.; Zangrando, E. Eur. J. Inorg. Chem. 2002, 93-103
32. Hamza, M. S. A. J. Inorg. Biochem. 1998, 69, 269-274
33. Bernasconi, C. F. Relaxation Kinetics; Academic Press: New York, 1976.
34. Baldwin, D. A.; Betterton, E. A.; Pratt, J. M. S. Afr. J. Chem. 1982, 35, 173-175
35. Marques, H. M.; Bradley, J. C.; Brown, K. L.; Brooks, H. J. Chem. Soc., Dalton Trans. 1993, 3475-3478
36. Männel-Croisé, C.; Probst, B.; Zelder, F. Anal. Chem. 2009, 81, 9493-9498
37. Meier, M.; van Eldik, R. Inorg. Chem. 1993, 32, 2635-2639
38. Knapton, L.; Marques, H. M. Dalton Trans. 2005, 889-895
39. Marques, H. M.; Bradley, J. C.; Campbell, L. A. J. Chem. Soc., Dalton Trans. 1992, 2019-2027
40. Douglas, B. E.; McDaniel, D. H.; Alexander, J. J. Inorganic Chemisty, 2nd ed.; John Wiley & Sons, Inc.: New York, 1980.