Hydroxyl radical yields from reactions of terpene mixtures with ozone

Indoor Air

Volumn 21, Issue 5, 2011, Pages 400-409

  Forester, C D ^a   Wells, J R ^a  

^a NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH   (United States)

Author keywords

Commercial cleaning products; Hydroxyl radical yields; Ozone; Solid phase microextraction fibers; terpineol

Indexed keywords

CLEANING; ESSENTIAL OILS; EXTRACTION; GAS CHROMATOGRAPHY; IONIZATION OF GASES; MONOTERPENES;

CLEANING PRODUCTS; COMMERCIAL CLEANING PRODUCT; HYDROXYL RADICAL YIELD; HYDROXYL RADICALS; INDIVIDUAL COMPONENTS; OIL CLEANING; SOLID-PHASE MICROEXTRACTION FIBERS; TWO-COMPONENT; WATER VAPOUR; Α- TERPINEOL;

OZONE;

EID: 80052632690     PISSN: 09056947     EISSN: 16000668     Source Type: Journal    
DOI: 10.1111/j.1600-0668.2011.00718.x     Document Type: Article

References (36)

1. 3 with a series of terpenes, Atmos. Environ., 36, 4347-4355.
2. Atkinson, R. (2003) Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes, Atmos. Chem. Phys. Discuss., 3, 4183-4358.
3. 3 with a series of alkenes under atmospheric conditions, Environ. Sci. Technol., 27, 1357-1363.
4. 3 with a series of monoterpenes and related compounds at 296-k +/-2-k, Int. J. Chem. Kinet., 22, 871-887.
5. 3 with a series of terpenes, J. Geophys. Res. Atmos., 97, 6065-6073.
6. Atkinson, R., Baulch, D.L., Cox, R.A., Hampson, R.F., Kerr, J.A., Rossi, M.J., Troe, J. and Evaluation, I.S.G.K.D. (1999) Evaluated kinetic and photochemical data for atmospheric chemistry, organic species: supplement vii, J. Phys. Chem. Ref. Data, 28, 191-393.
7. Baxley, J.S. and Wells, J.R. (1998) The hydroxyl radical reaction rate constant and atmospheric transformation products of 2-butanol and 2-pentanol, Int. J. Chem. Kinet., 30, 745-752.
8. Breitmaier, E. (2006) Terpenes: Flavors, Fragrances, Pharmaca, Pheromones, Weinheim, Germany, Wiley-VCH.
9. 3 with alkenes and monoterpenes, J. Geophys. Res. Atmos., 101, 28649-28653.
10. Criegee, R. (1975) Mechanism of ozonolysis, Agnew. Chem. Int. Ed, 14, 745.
11. De Rosa, C.T., El-Masri, H.A., Pohl, H., Cibulas, W. and Mumtaz, M.M. (2004) Implications of chemical mixtures in public health practice, J. Toxicol. Environ. Health, Part B: Crit. Rev., 7, 339-350.
12. Destaillats, H., Lunden, M.M., Singer, B.C., Coleman, B.K., Hodgson, A.T., Weschler, C.J. and Nazaroff, W.W. (2006) Indoor secondary pollutants from household product emissions in the presence of ozone: a bench-scale chamber study, Environ. Sci. Technol., 40, 4421-4428.
13. Fan, Z.H., Lioy, P., Weschler, C., Fiedler, N., Kipen, H. and Zhang, J.F. (2003) Ozone-initiated reactions with mixtures of volatile organic compounds under simulated indoor conditions, Environ. Sci. Technol., 37, 1811-1821.
14. Fick, J., Pommer, L., Andersson, B. and Nilsson, C. (2002) A study of the gas-phase ozonolysis of terpenes: the impact of radicals formed during the reaction, Atmos. Environ., 36, 3299-3308.
15. Forester, C.D., Ham, J.E. and Wells, J.R. (2007) Geraniol (2, 6-dimethyl-2, 6-octadien-8-ol) reactions with ozone and OH radical: rate constants and gas-phase products, Atmos. Environ., 41, 1188-1199.
16. FPPP (1998) Florida pollution prevention program pollution prevention fact sheet industrial cleaning #6 terpene cleaners Fppp 1998, April 26, 2011.
17. Guenther, A., Hewitt, C.N., Erickson, D., Fall, R., Geron, C., Graedel, T., Harley, P., Klinger, L., Lerdau, M., Mckay, W.A., Pierce, T., Scholes, B., Steinbrecher, R., Tallamraju, R., Taylor, J. and Zimmerman, P. (1995) A global-model of natural volatile organic-compound emissions, J. Geophys. Res. Atmos., 100, 8873-8892.
18. Jarvis, J., Seed, M.J., Elton, R.A., Sawyer, L. and Agius, R.M. (2005) Relationship between chemical structure and the occupational asthma hazard of low molecular weight organic compounds, Occup. Environ. Med., 62, 243-250.
19. Johnson, D. and Marston, G. (2008) The gas-phase ozonolysis of unsaturated volatile organic compounds in the troposphere, Chem. Soc. Rev., 37, 699-716.
20. Johnson, D., Lewin, A.G. and Marston, G. (2001) The effect of Criegee-intermediate scavengers on the OH yield from the reaction of ozone with 2-methylbut-2-ene, J. Phys. Chem. A, 105, 2933-2935.
21. Kroll, J.H., Clarke, J.S., Donahue, N.M., Anderson, J.G. and Demerjian, K.L. (2001a) Mechanism of hox formation in the gas-phase ozone-alkene reaction. 1. Direct, pressure-dependent measurements of prompt OH yields, J. Phys. Chem. A, 105, 1554-1560.
22. Kroll, J.H., Sahay, S.R., Anderson, J.G., Demerjian, K.L. and Donahue, N.M. (2001b) Mechanism of hox formation in the gas-phase ozone-alkene reaction. 2. Prompt versus thermal dissociation of carbonyl oxides to form OH, J. Phys. Chem. A, 105, 4446-4457.
23. Marketwire (2010) U.S. Market for green household cleaning products enters forefront of consumer consciousness with shift toward more eco-friendly and sustainable lifestyles, April 26, 2011.
24. Paulson, S.E., Chung, M., Sen, A.D. and Orzechowska, G. (1998) Measurement of OH radical formation from the reaction of ozone with several biogenic alkenes, J. Geophys. Res. Atmos., 103, 25533-25539.
25. Paulson, S.E., Chung, M.Y. and Hasson, A.S. (1999) OH radical formation from the gas-phase reaction of ozone with terminal alkenes and the relationship between structure and mechanism, J. Phys. Chem. A, 103, 8125-8138.
26. Pryor, W.A. and Uppu, R.M. (1993) A kinetic-model for the competitive reactions of ozone with amino-acid-residues in proteins in reverse micelles, J. Biol. Chem., 268, 3120-3126.
27. RAM (2009) Research and markets; Environmentally friendly cleaning products in the united states Ram 2009 April 26, 2011.
28. Rastogi, S.C., Heydorn, S., Johansen, J.D. and Basketter, D.A. (2001) Fragrance chemicals in domestic and occupational products, Contact Dermatitis, 45, 221-225.
29. Rickard, A.R., Johnson, D., Mcgill, C.D. and Marston, G. (1999) OH yields in the gas-phase reactions of ozone with alkenes, J. Phys. Chem. A, 103, 7656-7664.
30. Siese, M., Becker, K.H., Brockmann, K.J., Geiger, H., Hofzumahaus, A., Holland, F., Mihelcic, D. and Wirtz, K. (2001) Direct measurement of OH radicals from ozonolysis of selected alkenes: a euphore simulation chamber study, Environ. Sci. Technol., 35, 4660-4667.
31. Singer, B.C., Coleman, B.K., Destaillats, H., Hodgson, A.T., Lunden, M.M., Weschler, C.J. and Nazaroff, W.W. (2006a) Indoor secondary pollutants from cleaning product and air freshener use in the presence of ozone, Atmos. Environ., 40, 6696-6710.
32. Singer, B.C., Destaillats, H., Hodgson, A.T. and Nazaroff, W.W. (2006b) Cleaning products and air fresheners: emissions and resulting concentrations of glycol ethers and terpenoids, Indoor Air, 16, 179-191.
33. Vohringer-Martinez, E., Tellbach, E., Liessmann, M. and Abel, B. (2010) Role of water complexes in the reaction of propionaldehyde with OH radicals, J. Phys. Chem. A, 114, 9720-9724.
34. Wells, J.R. (2005) Gas-phase chemistry of alpha-terpineol with ozone and OH radical: rate constants and products, Environ. Sci. Technol., 39, 6937-6943.
35. Weschler, C.J. and Shields, H.C. (1996) Production of the hydroxyl radical in indoor air, Environ. Sci. Technol., 30, 3250-3258.
36. Weschler, C.J. and Shields, H.C. (1997) Measurements of the hydroxyl radical in a manipulated but realistic indoor environment, Environ. Sci. Technol., 31, 3719-3722.