In situ synthesis of SAPO-34 grown onto fully calcined kaolin microspheres and its catalytic properties for the MTO reaction

Industrial and Engineering Chemistry Research

Volumn 50, Issue 17, 2011, Pages 9989-9997

  Wang, Pengfei ^a,b   Lv, Ailing ^b   Hu, Jie ^b   Xu, Jing ^b   Lu, Guanzhong ^a  

^a RESEARCH INSTITUTE OF INDUSTRIAL CATALYSIS   (China)

^b Shanghai Research Institute of Chemical Industry   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC PROPERTIES; CHEMICAL COMPOSITIONS; HYDROTHERMAL METHODS; IN-SITU; IN-SITU SYNTHESIS; LIGHT OLEFINS; LOW TEMPERATURES; METAKAOLINS; METHANOL CONVERSION; METHANOL TO OLEFIN; NAOH CONCENTRATION; NAOH PRETREATMENT; NAOH SOLUTIONS; PHYSICOCHEMICAL PROPERTY; REACTION CATALYZED; SAPO-34; TETRAETHYLAMMONIUM; TRIETHYLAMINES; XRD;

ADSORPTION; AMMONIUM COMPOUNDS; CALCINATION; CATALYST DEACTIVATION; CATALYST SELECTIVITY; KAOLIN; METHANOL; MICROSPHERES; OLEFINS;

SYNTHESIS (CHEMICAL);

EID: 80052383731     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie201060u     Document Type: Article

References (34)

1. Chen, J. Q.; Bozzano, A.; Glover, B.; Fuglerud, T.; Kvisle, S. Recent Advancements in Ethylene and Propylene Production Using the UOP/Hydro MTO Process Catal. Today 2005, 106, 103
2. Bjørgen, M.; Svelle, S.; Joensen, F.; Nerlov, J.; Kolboe, S.; Bonino, F.; Palumbo, L.; Bordigac, S.; Olsbye, U. Conversion of Methanol to Hydrocarbons over Zeolite H-ZSM-5: On the Origin of the Olefinic Species J. Catal. 2007, 249, 195
3. Chen, D.; Grønvold, A.; Moljord, K.; Holmen, A. Methanol Conversion to Light Olefins over SAPO-34: Reaction Network and Deactivation Kinetics Ind. Eng. Chem. Res. 2007, 46, 4116
4. Chen, X. S.; Liu, Y. Economic Analysis and Engineering Design Principle of Producing Low Carbon Olefin by Converting Natural Gas to Methanol or Dimethyl Ether Pet. Refin. Eng. 2003, 33, 43
5. Fougerit, J. M.; Gnep, N. S.; Guisnet, M. Selective Transformation of Methanol into Light Olefins over a Mordenite Catalyst: Reaction Scheme and Mechanism Microporous Mesoporous Mater. 1999, 29, 79
6. Campelo, J. M.; Lafont, F.; Marinas, J. M.; Ojeda, M. Studies of Catalyst Deactivation in Methanol Conversion with High, Medium and Small Pore Silicoaluminophosphates Appl. Catal. A: Gen. 2000, 192, 85
7. Wu, X. C.; Abraha, M. G.; Anthony, R. G. Methanol Conversion on SAPO-34: Reaction Condition for Fixed-Bed Reactor Appl. Catal. A: Gen. 2004, 260, 63
8. Lok, B. M.; Messina, C. A.; Patton, R. L.; Gajek, R. T.; Cannan, T. R.; Flanigen, E. M. Silicoaluminophosphate Molecular Sieves: Another New Class of Microporous Crystalline Inorganic Solids J. Am. Chem. Soc. 1984, 106, 6092
9. Lee, Y. J.; Baek, S. C.; Jun, K. W. Methanol Conversion on SAPO-34 Catalysts Prepared by Mixed Template Method Appl. Catal. A: Gen. 2007, 329, 130
10. Wilson, S.; Barger, P. The Characteristics of SAPO-34 which Influence the Conversion of Methanol to Light Olefins Microporous Mesoporous Mater. 1999, 29, 117
11. Liu, G. Y.; Tian, P.; Zhang, Y.; Li, J. Z.; Xu, L.; Meng, S. H.; Liu, Z. M. Synthesis of SAPO-34 Templated by Diethylamine: Crystallization Process and Si Distribution in the Crystals Microporous Mesoporous Mater. 2008, 114, 416
12. Cui, Z. M.; Liu, Q.; Song, W. G.; Wan, L. J. Insights into the Mechanism of Methanol-to-Olefin Conversion at Zeolites with Systematically Selected Framework Structures Angew. Chem., Int. Ed. 2006, 45, 6512
13. Arstad, B.; Kolboe, S. The Reactivity of Molecules Trapped Within the SAPO-34 Cavities in the Methanol-to-Hydrocarbons Reaction J. Am. Chem. Soc. 2001, 123, 8137
14. Leonardo, T.; Alexandre, C. L.; Alexandre, B. G.; Monica, A. P. Methanol Conversion over Acid Solid Catalysts Catal. Today 2008, 133-135, 406
15. 3 Sphere Supports as the Catalyst for the Fluidized Bed Conversion of Dimethyl Ether to Olefins Appl. Catal. A: Gen. 2008, 341, 112
16. Qi, G. Z.; Xie, Z. K.; Yang, W. M.; Zhong, S. Q.; Liu, H. X.; Zhang, C. F.; Chen, Q. L. Behaviors of Coke Deposition on SAPO-34 Catalyst during Methanol Conversion to Light Olefins Fuel Process. Technol. 2007, 88, 437
17. Alwahabi, S. M.; Froment, G. F. Single Event Kinetic Modeling of the Methanol-to-Olefins Process on SAPO-34 Ind. Eng. Chem. Res. 2004, 43, 5098
18. Liu, H. H.; Ma, J. T.; Gao, X. H. Synthesis, Characterization and Evaluation of a Novel Resid FCC Catalyst Based on in Situ Synthesis on Kaolin Microspheres Catal. Lett. 2006, 110, 229
19. Feng, H.; Chen, Y. H.; Li, C. Y.; Shan, H. H. In-Situ Synthesis of ZSM-5 on Silica Gel and Studies on its Catalytic Activity J. Fuel Chem. Technol. 2008, 36, 144
20. Patcas, F. C. The Methanol-to-Olefins Conversion over Zeolite-Coated Ceramic Foams J. Catal. 2005, 231, 194
21. Liu, H. H.; Zhao, H. Q.; Gao, X. H.; Ma, J. T. A; Novel, F. C. C. Catalyst Synthesized via in Situ Overgrowth of Nay Zeolite on Kaolin Microspheres for Maximizing Propylene Yield Catal. Today 2007, 125, 163
22. Tan, Q. F.; Bao, X. J.; Song, T. C.; Fan, Y.; Shi, G.; Shen, B. J.; Liu, C. H.; Gao, X. H. Synthesis, Characterization, and Catalytic Properties of Hydrothermally Stable Macro-Meso-Micro-Porous Composite Materials Synthesized via in Situ Assembly of Preformed Zeolite Y Nanoclusters on Kaolin J. Catal. 2007, 251, 69
23. Feng, H.; Li, C. Y.; Shan, H. H. In-Situ Synthesis and Catalytic Activity of ZSM-5 Zeolite Appl. Clay Sci. 2009, 42, 439
24. Zhu, J.; Cui, Y.; Nawaz, Z.; Wang, Y.; Wei, F. In Situ Synthesis of SAPO-34 Zeolites in Kaolin Microspheres for a Fluidized Methanol or Dimethyl Ether to Olefins Process Chin. J.Chem. Eng. 2010, 18, 979
25. Sanchez, R. M. T.; Basaldella, E. I.; Marco, J. F. The Effect of Thermal and Mechanical Treatments on Kaolinite: Characterization by XPS and IEP Measurements J. Colloid Interface Sci. 1999, 215, 339
26. Wittberg, T. N.; Wang, P. S. XPS Study of the Dehydration of Clay and Kaolin Powders Surf. Interface Anal. 1999, 27, 936
27. Liu, G. Y.; Tian, P.; Li, J. Z.; Zhang, D. Z.; Zhou, F.; Liu, Z. M. Synthesis, Characterization and Catalytic Properties of SAPO-34 Synthesized Using Diethylamine as a Template Microporous Mesoporous Mater. 2008, 111, 143
28. Parlitz, B.; Schreier, E.; Zubowa, H. L.; Eckelt, R.; Lieschke, E.; Fricke, R. Isomerization of n -Heptane over Pd-Loaded Silico-Alumino-Phosphate Molecular Sieve J. Catal. 1995, 155, 1
29. 3-TPD Study J. Phys. Chem. C 2008, 112, 7193
30. Niekerk, M. J. V.; Fletcher, J. C. Q.; O'Connor, C. T. Effect of Catalyst Modification on the Conversion of Methanol to Light Olefins over SAPO-34 Appl. Catal. A: Gen. 1996, 138, 135
31. Keil, F. J. Methanol-to-Hydrocarbons: Process Technology Microporous Mesoporous Mater. 1999, 29, 49
32. Chen, Y. J.; Zhou, H. Q.; Zhu, J.; Zhang, Q.; Wang, Y.; Wang, D. Z.; Wei, F. Direct Synthesis of a Fluidizable SAPO-34 Catalyst for a Fluidized Dimethyl Ether-to-Olefins Process Catal. Lett. 2008, 124, 297
33. Wei, Y. X.; Zhang, D. Z.; Xu, L.; Chang, F. X.; He, Y. L.; Meng, S. H.; Su, B. L.; Liu, Z. M. Synthesis, Characterization and Catalytic Performance of Metal-Incorporated SAPO-34 for Chloromethane Transformation to Light Olefins Catal. Today 2008, 131, 262
34. Liu, H. X.; Xie, Z. K.; Zhang, C. F.; Chen, Q. L. Characterization and Thermal Decomposition Modes of SAPO-34 Molecular Sieves Synthesized with Different Templates Chin. J. Chem. Phys. 2003, 6, 521