Transesterification kinetics of palm olein oil using supercritical methanol

Journal of Supercritical Fluids

Volumn 58, Issue 3, 2011, Pages 365-370

  Choi, Cheong Song ^a   Kim, Jin Woo ^a   Jeong, Cheol Jin ^a   Kim, Huiyong ^a   Yoo, Ki Pung ^a  

^a Sogang University   (South Korea)

Author keywords

Continuous transesterification; Entropy of activation; Kinetics; Palm olein oil; Supercritical methanol

Indexed keywords

ACTIVATION VOLUME; CONTINUOUS TRANSESTERIFICATION; ENTROPY OF ACTIVATION; FATTY ACID METHYL ESTER; HOMOGENEOUS PHASE; INDIVIDUAL COMPONENTS; METHYL ESTERS; MOLAR RATIO; PALM OLEIN; REACTION TEMPERATURE; RESIDENCE TIME; SUPERCRITICAL METHANOL; TRANSESTERIFICATION REACTION;

ACTIVATION ENERGY; ENTROPY; ESTERIFICATION; ESTERS; FATTY ACIDS; METHANOL; PYROLYSIS; VEGETABLE OILS;

TRANSESTERIFICATION;

EID: 80052267477     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2011.06.015     Document Type: Article

References (18)

1. N. Martini, and S. Schell Plant oil as fuels: present state of future developments Proceedings of the Symposium 1997 Springer Potsdam, Germany 6
2. A. Demirbas Biodeisel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterfication methods Progress in Energy and Combustion Science 31 2005 466 487
3. A.P. Vyas, J.L. Verma, and N. Subrahmanyam A review on FAME production processes Fuel 89 2010 1 9
4. R. Sawangkeaw, K. Bunyakiat, and S. Ngamprasertsith A review of laboratory-scale research on lipid conversion to biodiesel with supercritical methanol (2001-2009) J. Supercritical Fluids 55 2010 1 13
5. M. Diasakou, A. Louloudi, and N. Papayannakos Kinetics of the non-catalytic transesterification of soybean oil Fuel 77 1998 1297 1302 (Pubitemid 128400511)
6. D. Kusdiana, and S. Saka Kinetics of transesterification in rapeseed oil to biodiesel fuel as treated in supercritical methanol Fuel 80 2001 693 698
7. H. He, S. Sun, T. Wang, and S. Zhu Transesterification kinetics of soybean oil for production of biodiesel in super critical methanol J. American Oil Chemists Society 84 2007 399 404 (Pubitemid 46931873)
8. H. Imahara, E. Minami, S. Hari, and S. Saka Thermal stability of biodiesel in supercritical methanol Fuel 87 2008 1 6 (Pubitemid 350087929)
9. M.N. Varma, and G. Madras Synthesis of biodiesel from castor oil and linseed oil in supercritical fluids Industrial and Engineering Chemistry Research 46 2007 1 6
10. AOCS, Official Methods and Recommended Practices of the AOCS 2006, 5th ed., Champaign, Illinois, 2006, p. 97.
11. K. Bunyakiat, S. Mankmee, R. Sawangkeaw, and S. Ngamprasertsith Continuous production of biodiesel via transesterification from vegetable oils in supercritical methanol Energy & Fuels 20 2006 812 817
12. A. Demirbas Biodiesel from sunflower oil in supercritical methanol with calcium oxide Energy Conversion and Management 48 2007 937 941 (Pubitemid 46123729)
13. K.J. Ladler Chemical Kinetics 3rd ed. 1987 McGraw-Hill
14. W.B. Wan Nik, F.N. Ani, and H.H. Masjuki Thermal stability evaluation of palm oil as energy transport media Energy Conversion and Management 46 2005 2198 2215
15. W. Cao, H. Han, and J. Zhang Preparation of biodiesel from soybean using supercritical methanol and co-solvent Fuel 84 2005 347 351
16. P. Hegel, G. Mabe, S. Pereda, and E.A. Brignole Phase transition in a biodiesel reactor using supercritical methanol Industrial and Engineering Chemistry Research 46 2007 6360 6365 (Pubitemid 47477349)
17. D. Kusdiana, and S. Saka Two-step preparation for catalyst-free biodiesel fuel production Applied Biochemistry and Biotechnology 115 2004 781 791
18. H. He, T. Wang, and S. Zhu Continuous production of biodiesel fuel from vegetable oil using supercritical methanol process Fuel 86 2007 442 447 (Pubitemid 44666831)