Predicting the glass transition temperature of bioactive glasses from their molecular chemical composition

Acta Biomaterialia

Volumn 7, Issue 10, 2011, Pages 3601-3605

  Hill, Robert G ^a   Brauer, Delia S ^a  

^a QUEEN MARY UNIVERSITY OF LONDON   (United Kingdom)

Author keywords

Bioactive glass; Glass property modelling; Glass transition temperature; Thermal analysis; Thermal properties

Indexed keywords

BIOACTIVE GLASS; GLASS TRANSITION; PHASE SEPARATION; TEMPERATURE;

CHEMICAL COMPOSITIONS; GLASS PROPERTIES; GLASS PROPERTY MODELING; GLASS STRUCTURE; GLASS TRANSITION TEMPERATURE TG; ITERATIVE LEAST-SQUARE FITTING; MOLAR COMPOSITIONS; PROPERTY MODELS; STRUCTURAL COMPONENT; STRUCTURAL EFFECT;

THERMOANALYSIS;

CALCIUM OXIDE; FLUORIDE; GLASS; SILICON DIOXIDE;

ARTICLE; GLASS TRANSITION TEMPERATURE; MELTING POINT; MODEL; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PHYSICAL PHASE; PREDICTION; PRIORITY JOURNAL; STRUCTURE ANALYSIS; THERMAL ANALYSIS; TRANSITION TEMPERATURE;

EID: 80052259387     PISSN: 17427061     EISSN: 18787568     Source Type: Journal    
DOI: 10.1016/j.actbio.2011.06.023     Document Type: Article

References (29)

1. L.L. Hench, R.J. Splinter, W.C. Allen, and T.K. Greenlee Bonding mechanisms at the interface of ceramic prosthetic materials J Biomed Mater Res 5 1971 117 141
2. L.L. Hench The story of Bioglass® J Mater Sci Mater Med 17 2006 967 978
3. Y.C. Fredholm, N. Karpukhina, R.V. Law, and R.G. Hill Strontium containing bioactive glasses: glass structure and physical properties J Non-Cryst Solids 356 2010 2546 2551
4. E. Gentleman, Y.C. Fredholm, G. Jell, N. Lotfibakhshaiesh, M.D. O'Donnell, and R.G. Hill The effects of strontium-substituted bioactive glasses on osteoblasts and osteoclasts in vitro Biomaterials 31 2010 3244 3252
5. 2-ZnO glasses J Phys Chem B 106 2002 9753 9760 (Pubitemid 35390045)
6. V. Aina, G. Malavasi, A.F. Pla, L. Munaron, and C. Morterra Zinc-containing bioactive glasses: surface reactivity and behaviour towards endothelial cells Acta Biomater 5 2009 1211 1222
7. M.M. Azevedo, G. Jell, M.D. O'Donnell, R.V. Law, R.G. Hill, and M.M. Stevens Synthesis and characterization of hypoxia-mimicking bioactive glasses for skeletal regeneration J Mater Chem 20 2010 8854 8864
8. D.S. Brauer, N. Karpukhina, M.D. O'Donnell, R.V. Law, and R.G. Hill Fluoride-containing bioactive glasses: effect of glass design and structure on degradation, pH and apatite formation in simulated body fluid Acta Biomater 6 2010 3275 3282
9. G. Lusvardi, G. Malavasi, M. Cortada, L. Menabue, M.C. Menziani, and A. Pedone Elucidation of the structural role of fluorine in potentially bioactive glasses by experimental and computational investigation J Phys Chem B 112 2008 12730 12739
10. S.J. Watts, M.D. O'Donnell, R.V. Law, and R.G. Hill Influence of magnesia on the structure and properties of bioactive glasses J Non-Cryst Solids 356 2010 517 524
11. J.M. Gomez-Vega, E. Saiz, A.P. Tomsia, T. Oku, K. Suganuma, and G.W. Marshall Novel bioactive functionally graded coatings on Ti6Al4V Adv Mater 12 2000 894 898
12. N. Lotfibakhshaiesh, D.S. Brauer, and R.G. Hill Bioactive glass engineered coatings for Ti6Al4V alloys: influence of strontium substitution for calcium on sintering behaviour J Non-Cryst Solids 356 2010 2583 2590
13. M.R. Towler, C.M. Crowley, D. Murphy, and A.M.C. O'Callaghan A preliminary study of an aluminum-free glass polyalkenoate cement J Mater Sci Lett 21 2002 1123 1126 (Pubitemid 34950914)
14. B.J. Tai, Z. Bian, H. Jiang, D.C. Greenspan, J. Zhong, and A.E. Clark Anti-gingivitis effect of a dentifrice containing bioactive glass (NovaMin®) particulate J Clin Periodontol 33 2006 86 91 (Pubitemid 43424833)
15. M.D. O'Donnell Predicting bioactive glass properties from the molecular chemical composition: Glass transition temperature Acta Biomater 7 2011 2264 2269
16. 3 system J Mater Sci Mater Med 3 1992 326 328
17. A. Tilocca, and A.N. Cormack Structural effects of phosphorus inclusion in bioactive silicate glasses J Phys Chem B 111 2007 14256 14264
18. Elgayar I. The influence of alkali metal content and network connectivity on bioactive glasses. Ph.D. Thesis. London: Imperial College; 2004.
19. I. Elgayar, A.E. Aliev, A.R. Boccaccini, and R.G. Hill Structural analysis of bioactive glasses J Non-Cryst Solids 351 2005 173 183
20. 5 content in two series of soda lime phosphosilicate glasses on structure and properties - Part I: NMR J Non-Cryst Solids 354 2008 3554 3560
21. M.W.G. Lockyer, D. Holland, and R. Dupree NMR investigation of the structure of some bioactive and related glasses J Non-Cryst Solids 188 1995 207 219
22. A. Pedone, T. Charpentier, G. Malavasi, and M.C. Menziani New insights into the atomic structure of 45S5 bioglass by means of solid-state NMR spectroscopy and accurate first-principles simulations Chem Mater 22 2010 5644 5652
23. D.S. Brauer, N. Karpukhina, R.V. Law, and R.G. Hill Structure of fluoride-containing bioactive glasses J Mater Chem 19 2009 5629 5636
24. 2 system J Non-Cryst Solids 325 2003 193 205
25. D.S. Brauer, N. Karpukhina, D. Seah, R.V. Law, and R.G. Hill Fluoride-containing bioactive glasses Adv Mater Res 39-40 2008 299 304
26. L. Linati, G. Lusvardi, G. Malavasi, L. Menabue, M.C. Menziani, and P. Mustarelli Qualitative and quantitative structure-property relationship analysis of multicomponent potential bioglasses J Phys Chem B 109 2005 4989 4998 (Pubitemid 40414761)
27. G. Lusvardi, G. Malavasi, F. Tarsitano, L. Menabue, M.C. Menziani, and A. Pedone Quantitative structure-property relationships of potentially bioactive fluoro phospho-silicate glasses J Phys Chem B 113 2009 10331 10338
28. Watts SJ. Composition-structure-property relationships in bioactive glasses. Ph.D. Thesis. London: Imperial College; 2010.
29. Fredholm YC. Development and characterisation of strontium-containing bioactive glasses and aluminium-free glass polyalkenoate cements. Ph.D. Thesis. London: Imperial College; 2009.