Kinetic and safety parameters analysis for 1,1,-di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane in isothermal and non-isothermal conditions

Journal of Hazardous Materials

Volumn 192, Issue 3, 2011, Pages 1427-1436

  Tseng, Jo Ming ^a   Lin, Chun Ping ^b   Huang, Sheng Tien ^a   Hsu, Johnson ^c  

^a CENTRAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Taiwan)

^b ASIA UNIVERSITY   (Taiwan)

^c TA INSTRUMENTS   (United States)

Author keywords

1,1, Di (tert butylperoxy) 3,3,5 trimethylcyclohexane (TMCH) 88mass ; Differential scanning calorimetry; Kinetic and safety parameters; Runaway reactions; Thermal analysis

Indexed keywords

1,1,-DI-(TERT-BUTYLPEROXY)-3,3,5-TRIMETHYLCYCLOHEXANE (TMCH) 88MASS%; CHEMICAL ENGINEERING DEPARTMENT; EXPLOSION ACCIDENTS; FREQUENCY FACTORS; MANUFACTURING PROCESS; NON-ISOTHERMAL CONDITION; ORGANIC PEROXIDE; REACTION HEAT; REACTION ORDERS; RUNAWAY REACTION; SAFETY PARAMETERS; SELF-ACCELERATING DECOMPOSITION TEMPERATURES; TIME TO MAXIMUM RATE; UNSTABLE STRUCTURES;

ACCIDENTS; ACTIVATION ENERGY; DIFFERENTIAL SCANNING CALORIMETRY; KINETICS; OCCUPATIONAL RISKS; SAFETY FACTOR; THERMOANALYSIS;

EXPLOSIONS;

1,1 DI(TERT BUTYLPEROXY) 3,3,5 TRIMETHYLCYCLOHEXANE; CYCLOHEXANE DERIVATIVE; UNCLASSIFIED DRUG;

ACTIVATION ENERGY; CALORIMETRY; CHEMICAL INDUSTRY; CHLORINATED HYDROCARBON; DECOMPOSITION; DIFFERENTIAL THERMAL ANALYSIS; HAZARDOUS WASTE; HEAT TRANSFER; INDUSTRIAL TECHNOLOGY; ISOTHERM; MANUFACTURING; PEROXY RADICAL; POLYMERIZATION; SAFETY; TEMPERATURE PROFILE;

ACTIVATION ENERGY; ANALYTICAL PARAMETERS; ARTICLE; DECOMPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; FREQUENCY FACTOR; ISOTHERM; KINETICS; ONSET TEMPERATURE; PEAK OF TEMPERATURE; REACTION HEAT; REACTION ORDER; SAFETY; SAMPLE MASS; SELF ACCELERATING DECOMPOSITION TEMPERATURE; TEMPERATURE; TEMPERATURE OF NO RETURN; THERMAL ANALYSIS; TIME TO MAXIMUM RATE;

CALORIMETRY, DIFFERENTIAL SCANNING; CHEMISTRY; CHEMISTRY TECHNIQUES, ANALYTICAL; CYCLOHEXANES; ENVIRONMENTAL REMEDIATION; HAZARDOUS SUBSTANCES; KINETICS; MODELS, CHEMICAL; PEROXIDES; TEMPERATURE; THERMODYNAMICS; TIME FACTORS;

EID: 80052023134     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2011.06.059     Document Type: Article

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