Modeling a slurry CSTR with Co/P-Al2O3 catalyst for Fischer-Tropsch synthesis

Fuel Processing Technology

Volumn 92, Issue 12, 2011, Pages 2264-2271

  Kwack, Seung Ho ^a   Park, Myung June ^a   Bae, Jong Wook ^b   Park, Seon Ju ^c   Ha, Kyoung Su ^c   Jun, Ki Won ^c  

^a Ajou University   (South Korea)

^b Sungkyunkwan University   (South Korea)

^c Korea Research Institute of Chemical Technology   (South Korea)

Author keywords

Cobalt based catalyst; Fischer Tropsch synthesis; Hydrocarbon distribution; Kinetics model; Parameter estimation; Slurry CSTR

Indexed keywords

CO CONVERSION; COBALT-BASED CATALYSTS; DEVELOPED MODEL; ESTIMATED PARAMETER; EXPERIMENTAL DATA; HYDROCARBON DISTRIBUTION; HYDROCARBON PRODUCT; KINETIC MODELS; KINETICS MODEL; OPERATING CONDITION; PRODUCT DISTRIBUTIONS; REACTION MECHANISM;

CATALYSTS; COBALT; HYDROCARBONS; KINETICS; MATHEMATICAL MODELS; PARAMETER ESTIMATION;

FISCHER-TROPSCH SYNTHESIS;

EID: 80051919169     PISSN: 03783820     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuproc.2011.07.019     Document Type: Article

References (53)

1. E. Iglesia Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts Appl. Catal. A: General 161 1997 59 78 (Pubitemid 127379094)
2. M.E. Dry The Fischer-Tropsch process: 1950-2000 Catal. Today 71 2002 227 241 (Pubitemid 34141274)
3. B.H. Davis Fischer-Tropsch synthesis: overview of reactor development and future potentialities Top. Catal. 32 2005 143 168 (Pubitemid 40623606)
4. A.Y. Khodakov, W. Chu, and P. Fongarland Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels Chem. Rev. 107 2007 1692 1744 (Pubitemid 46876278)
5. T. Wang, J. Wang, and Y. Jin Slurry reactors for gas-to-liquid processes: a review Ind. Eng. Chem. Res. 46 2007 5824 5847 (Pubitemid 47407634)
6. J.W.A. De Swart, R. Krishna, and S.T. Sie Proc. 4th Int'l. Nat. Gas Conv. Sym., South Africa 1995
7. B. Jager Proceedings of the Fourth International Natural Gas Conversion Symposium, Kruger Park, South Africa 1995 19 23 November
8. R. Krishna, and S.T. Sie Design and scale-up of the Fischer-Tropsch bubble column slurry reactor Fuel Process. Technol. 39 2000 73 105
9. V.R. Ahón, E.F. Costa Jr., J.E.P. Monteagudo, C.E. Fontes, E.C. Biscaia Jr., and P.L.C. Lage A comprehensive mathematical model for the Fischer-Tropsch synthesis in well-mixed slurry reactors Chem. Eng. Sci. 60 2005 677 694 (Pubitemid 39606054)
10. K.-J. Woo, S.-H. Kang, S.-M. Kim, J.W. Bae, and K.-W. Jun Performance of a slurry bubble column reactor for Fischer-Tropsch synthesis: determination of optimum condition Fuel Process. Technol. 91 2010 434 439
11. W.-D. Deckwer, R. Kokuun, E. Sanders, and S. Ledakowicz Kinetic studies of Fischer-Tropsch synthesis on suspended iron/potassium catalyst-rate inhibition by carbon dioxide and water Ind. Eng. Chem. Process. Des. Dev. 25 1986 643 649 (Pubitemid 16587791)
12. W.H. Zimmerman, and D.B. Bukur Reaction kinetics over iron catalysts used for the Fischer-Tropsch synthesis Can. J. Chem. Eng. 68 1990 292 301
13. I.C. Yates, and C.N. Satterfield Intrinsic kinetics of the Fischer-Tropsch synthesis on a cobalt catalyst Energ. Fuels 5 1991 168 173
14. S.-M. Kim, Y.-J. Lee, J.W. Bae, H.S. Potdar, and K.-W. Jun Synthesis and characterization of a highly active alumina catalyst for methanol dehydration to dimethyl ether Appl. Catal. A: Gen. 348 2008 113 120
15. 3 catalyst: effect of phosphorous content Catal. Commun. 10 2009 1358 1362
16. S.-J. Park, J.W. Bae, Y.-J. Lee, K.-S. Ha, and K.-W. Jun Deactivation behaviors of Pt or Ru promoted Co/P-Al2O3 catalysts during slurry-phase Fischer-Tropsch synthesis Catal. Commun. 12 2011 539 543
17. V. Ponec, and W.A. van Barneveld The role of chemisorption of Fischer-Tropsch synthesis Ind. Eng. Chem. Prod. Res. Dev. 18 1979 268 271
18. C.K. Rofer-DePoorter A comprehensive mechanism for the Fischer-Tropsch synthesis Chem. Rev. 81 1981 447 474
19. K.H. Ernst, E. Schwarz, and K. Christmann The interaction of hydrogen with a cobalt(1010) surface J. Chem. Phys. 101 1994 5388 5401
20. 14 J. Am. Chem. Soc. 70 1948 3632 3643
21. 4 - x with hydrogen: relation to the Fischer-Tropsch synthesis of hydrocarbons J. Catal. 88 1984 382 387
22. E. van Steen, and H. Schulz Polymerisation kinetics of the Fischer-Tropsch CO hydrogenation using iron and cobalt based catalysts Appl. Catal. A: Gen. 186 1999 309 320 (Pubitemid 129532968)
23. X.-Q. Gong, R. Raval, and P. Hu J. Chem. Phys. 122 2005 024711
24. A.T. Bell Catalytic synthesis of hydrocarbons over Group VIII metals: a discussion of the reaction mechanism Catal. Rev. Sci. Eng. 23 1980 203 232
25. J.-P. Hovi, J. Lahtinen, Z.S. Liu, and R.M. Nieminen Monte Carlo study of CO hydrogenation on cobalt model catalysts J. Chem. Phys. 102 1995 7674 7682
26. C.S. Kellner, and A.T. Bell The kinetics and mechanism of carbon monoxide hydrogenation over alumina-supported ruthenium J. Catal. 70 1981 418 432
27. S. Krishnamoorthy, M. Tu, M.P. Ojeda, D. Pinna, and E. Iglesia An investigation of the effects of water on rate and selectivity for the Fischer-Tropsch synthesis on cobalt-based catalysts J. Catal. 211 2002 422 433
28. R.W. Joyner The mechanism of chain growth in the Fischer-Tropsch hydrocarbon synthesis Catal. Lett. 1 1988 307 310
29. H. Schulz, K. Beck, and E. Erich Kinetics of Fischer-Tropsch selectivity Fuel Proc. Technol. 18 1988 293 304
30. H. Schulz, E. van Steen, and M. Claeys Selective Hydrogenation and Dehydrogenation 1993 DGMK Kassel, Germany
31. G. Henrici-Olive, and S. Olive The Chemistry of the Catalytic Hydrogenation of Carbon Monoxide 1984 Springer Berlin
32. Y.T. Eidus The mechanism of the Fischer-Tropsch reaction and the initiated hydropolymerisation of alkenes, from radiochemical and kinetic data Rus. Chem. Rev. 36 1967 338 351
33. C.L. Kibby, R.B. Pannell, and T.P. Kobylinski Hydrogenation of olefins in the presence of carbon monoxide on supported cobalt catalysts ACS Division of Petroleum Preprints 29 1984 1113 1119 (Pubitemid 15442467)
34. H.S. Fogler Elements of Chemical Reaction Engineering 1999 Prentice-Hall New Jersey
35. M. Boudart Two-step catalytic reactions AICHE J. 18 1972 465 478
36. R. Krishna, and C. Maretto Scale up of a bubble column slurry reactor for Fischer-Tropsch synthesis Stud. Surf. Sci. Catal. 119 1998 197 202 (Pubitemid 128779630)
37. C. Maretto, and R. Krishna Modelling of a bubble column slurry reactor for Fischer-Tropsch synthesis Catal. Today 52 1999 279 289 (Pubitemid 129588005)
38. E.N. Fuller, P.D. Schettler, and J.C. Giddings New method for prediction of binary gas-phase diffusion coefficients Ind. Eng. Chem. 58 1966 18 27
39. R.S. Albal, Y.T. Shah, N.L. Carr, and A.T. Bell Mass transfer coefficients and solubilities for hydrogen and carbon monoxide under Fischer-Tropsch conditions Chem. Eng. Sci. 39 1984 905 907
40. R.A. Dictor, and A.T. Bell Fischer-Tropsch synthesis over reduced and unreduced iron oxide catalyst J. Catal. 97 1986 121 136
41. 2 und Wasserdampf in flässigenKohlenwasserstoffen Z. Phys. Chem. 5 1955 114 121
42. G.P. van der Laan, and A.A.C.M. Beenackers Catal. Rev. Sci. Eng. 41 1999 255 318
43. 2 Fischer-Tropsch catalyst with the estimation of kinetic parameters and hydrocarbon distribution Fuel 90 2011 1383 1394
44. M.E. Dry Catalysis-Science and Technology 1981 Springer-Verlag New York
45. T.J. Donnelly, and C.N. Satterfield Product distributions of the Fischer-Tropsch synthesis on precipitated iron catalysts Appl. Catal. 52 1989 93 114
46. Y. Liu, B.-T. Teng, X.-H. Guo, Y. Li, J. Chang, L. Tian, X. Hao, Y. Wang, H.-W. Xiang, Y.-Y. Xu, and Y.-W. Li Effect of reaction conditions on the catalytic performance of Fe-Mn catalyst for Fischer-Tropsch synthesis J. Mol. Catal. A: Chem. 272 2007 182 190 (Pubitemid 46809604)
47. 3 catalyst in a slurry reactor Chem. Eng. Sci. 62 2007 5353 5356 (Pubitemid 47268343)
48. P.J. van Berge, and R.C. Everson Cobalt as an alternative Fischer-Tropsch catalyst to iron for the production of middle distillates Stud. Surf. Sci. Catal. 107 1997 207 212 (Pubitemid 127816554)
49. H. Schulz, M. Claeys, and S. Harns Effect of water partial pressure on steady state Fischer-Tropsch activity and selectivity of a promoted cobalt catalyst Stud. Surf. Sci. Catal. 107 1997 193 200 (Pubitemid 127816552)
50. R.B. Anderson Catalysts for the Fischer-Tropsch Synthesis 1956 Van Nostrand Reinhold New York
51. M.A. Vannice The catalytic synthesis of hydrocarbons from carbon monoxide and hydrogen Catal. Rev. Sci. Eng. 14 1976 153 191
52. G. Huff Jr., and C.N. Satterfield Intrinsic kinetics of the Fischer-Tropsch synthesis on a reduced fused-magnetite catalyst Ind. Eng. Chem. Prod. Res. Dev. 23 1984 696 705 (Pubitemid 14643581)
53. S. Lögdberg, M. Boutonnet, J.C. Walmsley, S. Järås, A. Holmen, and E.A. Blekkan Appl Catal A: Gen 393 2011 109 121