Heterogeneity within order in crystals of a porous metal-organic framework

Journal of the American Chemical Society

Volumn 133, Issue 31, 2011, Pages 11920-11923

  Choi, Kyung Min ^a   Jeon, Hyung Joon ^a   Kang, Jeung Ku ^a   Yaghi, Omar M ^a,b  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLINE NATURE; MACRO-POROSITY; MACROPORES; METAL ORGANIC FRAMEWORK; MICROPOROUS; NATURAL SYSTEMS; NEW FORMS; SYNTHETIC CRYSTALS;

CRYSTALLINE MATERIALS; CRYSTALS; JAVA PROGRAMMING LANGUAGE; POROUS MATERIALS;

CRYSTAL STRUCTURE;

METAL ORGANIC FRAMEWORK; METAL ORGANIC FRAMEWORK 5; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; POROSITY; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

CRYSTALLIZATION; ORGANOMETALLIC COMPOUNDS; PARTICLE SIZE; POROSITY; POWDER DIFFRACTION; SURFACE PROPERTIES;

EID: 79961145904     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja204818q     Document Type: Article

References (20)

1. Ishizu, K. Prog. Polym. Sci. 1998, 23, 1383
2. Rieter, W. J.; Taylor, K. M. L.; Lin, W. J. Am. Chem. Soc. 2008, 129, 9852
3. Koh, K.; Wong-Foy, A. G.; Matzger, A. J. Chem. Commun. 2009, 41, 6162
4. Joo, S. H.; Park, J. Y.; Tsung, C. K.; Yamada, Y.; Yang, P.; Somorjai, G. A. Nat. Mater. 2009, 8, 126
5. Xu, Z.; Hou, Y.; Sun, S. J. Am. Chem. Soc. 2007, 129, 8698
6. Choi, K. M.; Augustine, S.; Choi, J. H.; Lee, J. H.; Shin, W. H.; Yang, S. H.; Lee, J. Y.; Kang, J, K. Angew. Chem., Int. Ed. 2008, 47, 9904
7. Han, Y.; Zhang, D.; Chung, L. L.; Sun, J.; Zhao, L.; Zou, X.; Ying, J. Y. Nature Chem. 2009, 1, 123
8. Wan, Y.; Zhao, D. Y. Chem. Rev. 2007, 107, 2821
9. Inagaki, S.; Guan, S.; Ohsuna, T.; Terasaki, O. Nature 2002, 416, 304
10. Liang, C.; Li, Z.; Dai, S. Angew. Chem., Int. Ed. 2008, 47, 3696
11. Su, D. S.; Chen, X.; Weinberg, G.; Kelin-Hofmann, A.; Timpe, O.; Hamid, S. B.; Schlogl, R. Angew. Chem., Int. Ed. 2005, 44, 5488
12. Yang, R. T. Adsorbents: Fundamentals and Applications; Wiley-Interscience: New York, 2003.
13. Li, H.; Eddaoudi, M.; OKeeffe, M.; Yaghi, O. M. Nature 1999, 402, 276
14. Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; OKeeffe, M.; Yaghi, O. M. Science 2002, 295, 469
15. See the SI.
16. Baerlocher, C.; Meier, W. M.; Olson, D. H. Atlas of Zeolite Framework Types, 5 th ed.; Elsevier: Amsterdam, 2001.
17. For spng-MOF-5, a large amount of DBAs results in large-sized macropores (>80 nm) for most of pores except micropores (Figure 2). However, macropores are not observed by conventional isotherm measurements, because the pore filling would occur at pressures too close to the vapor pressure
18. Walton, K. S.; Millward, A. R.; Dubbeldam, D.; Frost, H.; Low, L. L.; Yaghi, O. M.; Snurr, R. Q. J. Am. Chem. Soc. 2008, 130, 406
19. Kubota, Y.; Takata, M.; Kobayashi, T. C.; Kitagawa, S. Coord. Chem. Rev. 2007, 251, 2510
20. Muroyama, N.; Yoshimura, A.; Kubota, Y.; Miyasaka, K.; Ohsuna, T.; Ryoo, R.; Ravikovitch, P.; Neimark, A. V.; Takata, M.; Terasaki, O. J. Phys. Chem. C 2008, 112, 10803