The production of nabh4 from its elements by mechano-chemical reaction and usage in hydrogen recycle

Energy Sources, Part A: Recovery, Utilization and Environmental Effects

Volumn 33, Issue 20, 2011, Pages 1912-1920

  Cakanyildirim C ^a   Guru M ^a  

^a GAZI UNIVERSITY   (Turkey)

Author keywords

Dehydrogenation; hydrogen carrier; hydrogen storage; NaBH4; solid phase reaction

Indexed keywords

ARGON ATMOSPHERES; HIGH TEMPERATURE; HYDROGEN CARRIER; HYDROGEN CONTENTS; MECHANOCHEMICAL REACTIONS; MECHANOCHEMICALS; NABH4; SODIUM BOROHYDRIDES; SOLID PHASE REACTION; WORKING TIME; XRD;

ARGON; BALL MILLING; BORON; BORON COMPOUNDS; CHEMICAL REACTORS; FACE RECOGNITION; HYDROGEN STORAGE; SODIUM; STOICHIOMETRY;

HYDROGEN;

EID: 79961057859     PISSN: 15567036     EISSN: 15567230     Source Type: Journal    
DOI: 10.1080/15567030903503175     Document Type: Article

References (15)

1. Akyüz, Y, Gürü, M., and Tekeli, S. 2007. Synthesis of MgB2 from anhydrous B2O3 by ball milling method and determination of superconductivity properties. Key Eng. Mater. 336-338:723-725. (Pubitemid 46425199)
2. Çakanyldrm, Ç., and Gürü, M. 2008a. Processing of lithium borohydride from its elements by ball milling method. Renew. Energy 33:2388-2392.
3. Çakanyldrm, Ç., and Gürü, M. 2008b. Hydrogen cycle with sodium borohydride. Int. J. Hydrogen Energy 33:4634-4639.
4. Çakanyldrm, Ç., and Gürü, M. 2009. Production of NaBH4 and hydrogen release with catalyst. Renew. Energ. 34:2362-2365.
5. Demirci, U. B., Akdim, O., and Miele, P. 2009. Ten-year efforts and a no-go recommendation for sodium borohydride for on-board automotive hydrogen storage. Int. J. Hydrogen Energy 34:2638-2645.
6. Hsueh, C. L., Liu, C. H., Chen, B. H., Chen, C. Y., Kuo, Y. C., Hwang, K. J., and Ku, J. R. 2009. Regeneration of spent-NaBH4 back to NaBH4 by using high-energy ball milling. Int. J. Hydrogen Energy 34:1717-1725.
7. Kaya, S., Gürü, M., and Ar, I. Synthesis of magnesium borohydride from its elements and usage in hydrogen recycle. Energy Sources, Part A, in press.
8. Kojima, Y., and Haga, T. 2003. Recycling of sodium metaborate to sodium borohydride. Int. J. Hydrogen Energy 28:989-993.
9. Li, Z. P., Liu, B. H., Morigasaki, N., and Suda, S. 2003a. Preparation of potassium borohydride by a mechano-chemical reaction of saline hydrides with dehydrated borate through ball milling. J. Alloys & Compd. 354:243-247.
10. Li, Z. P., Morigazaki, N., Liu, B. H., and Suda, S. 2003b. Preparation of sodium borohydride by the reaction of MgH2 with dehydrated borax through ball milling at room temperature. J. Alloys & Compd. 349:232-236.
11. Liu, B. H., Li, Z. P., Morigasaka, N., and Suda, S. 2008. Kinetic characteristics of sodium borohydride formation when sodium meta-borate reacts with magnesium. Int. J. Hydroen. Energ. 33:1323-1328.
12. Park, E. H., Jeong, S. U., Jung, U. H., Kim, S. H., Lee, J., Nam, S. W., Lim, T. H., Park, Y. J., and Yu, Y. H. 2007. Recycling of sodium metaborate to borax. Int. J. Hydrogen Energy 32:2982-2987. (Pubitemid 47374962)
13. Suda, S., Morigazaki, N., Iwase, Y., and Li, Z. P. 2005. Production of sodium borohydride by using dynamic behaviors of protite at the extreme surface of magnesium particles. J. Alloys & Compd. 404-406:643-647. (Pubitemid 41688694)
14. Uslu, T. 2009. Potential use of boron for energy production and storage. Energy Sources, Part A 31:610-618.
15. Varin, R. A., Chiu, Ch., and Wronski, Z. S. 2008. Mechano-chemical activation synthesis (MCAS) of disordered Mg(BH4)2 using NaBH4. J. Alloys & Comp. 462:201-208.