The effect of impurities on the performance of bioethanol-used internal reforming molten carbonate fuel cell

International Journal of Hydrogen Energy

Volumn 36, Issue 16, 2011, Pages 10346-10354

  Devianto, Hary ^a   Han, Jonghee ^b   Yoon, Sung Pil ^b   Nam, Suk Woo ^b   Lim, Tae Hoon ^b   Oh, In Hwan ^b   Hong, Seong Ahn ^b   Lee, Ho In ^a  

^a Seoul National University   (South Korea)

^b Korea Institute of Science and Technology   (South Korea)

Author keywords

Bioethanol; Coking; Impurities; MCFC; Steam reforming

Indexed keywords

CELL VOLTAGES; COKE FORMATION; DIETHYLAMINES; DIRECT INTERNAL REFORMING; EFFECTS OF IMPURITIES; INTERNAL REFORMING; MOLE RATIO; REACTION PATHWAYS; SINGLE CELLS;

ACETIC ACID; CATALYST ACTIVITY; COKE; ETHANOL; IMPURITIES; METHANOL; MOLTEN CARBONATE FUEL CELLS (MCFC); ORGANIC COMPOUNDS; PH; PROPANOL; STEAM ENGINEERING; STEAM REFORMING;

BIOETHANOL;

EID: 79960924177     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.09.070     Document Type: Conference Paper

References (36)

1. C. Wyman Handbook on bioethanol production and utilization 1996 CRC Press New York
2. M. Benito, J.L. Sanz, R. Isabel, R. Padilla, R. Arjona, and L. Daza Bio-ethanol steam reforming: insights on the mechanism for hydrogen production J Power Sources 2005 15111 15117
3. F. Frusteri, and S. Freni Bio-ethanol, a suitable fuel to produce hydrogen for a molten carbonate fuel cell J Power Sources 173 1 2007 200 209 (Pubitemid 47498844)
4. M. Ni, D.Y.C. Leung, and M.K.H. Leung A review on reforming bio-ethanol for hydrogen production Int J Hydrogen Energy 32 15 2007 3238 3247 (Pubitemid 47562217)
5. 3 catalyst Chem Eng J 98 1-2 2004 61 68 (Pubitemid 38345848)
6. M. Youn, J. Seo, K. Cho, J. Jung, H. Kim, and K. La Effect of support on hydrogen production by auto-thermal reforming of ethanol over supported nickel catalysts Korean J Chem Eng 25 2 2008 236 238
7. A.N. Fatsikostas, and X.E. Verykios Reaction network of steam reforming of ethanol over Ni-based catalysts J Catal 225 2 2004 439 452
8. V. Fierro, O. Akdim, H. Provendier, and C. Mirodatos Ethanol oxidative steam reforming over Ni-based catalysts J Power Sources 145 2 2005 659 666
9. S. Freni, S. Cavallaro, N. Mondello, L. Spadaro, and F. Frusteri Production of hydrogen for MC fuel cell by steam reforming of ethanol over MgO supported Ni and Co catalysts Catal Commun 4 6 2003 259 268 (Pubitemid 41087769)
10. 2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts Catal Commun 5 10 2004 611 615
11. J.W.C. Liberatori, R.U. Ribeiro, D. Zanchet, F.B. Noronha, and J.M.C. Bueno Steam reforming of ethanol on supported nickel catalysts Appl Catal A: Gen 327 2 2007 197 204 (Pubitemid 47031613)
12. C. Wang, T. Wang, L. Ma, Y. Gao, and C. Wu Partial oxidation reforming of biomass fuel gas over nickel-based monolithic catalyst with naphthalene as model compound Korean J Chem Eng 25 4 2008 738 743
13. A.J. Appleby, and F.R. Foulkes Fuel cell handbook 1989 Van Nostrand Reinhold Co. Minnesota
14. L.G. Austin Handbook of fuel cell technology 1968 Prentice Hall New Jersey
15. G. Hoogers Fuel cell technology handbook 2003 CRC Press New York
16. J. Larminie, A. Dicks, and M.S. McDonald Fuel cell systems explained 2004 John Wiley & Sons Pub. New York
17. G. Grassi Modern bioenergy in the European Union Renew Energy 16 1-4 1999 985 990
18. A. Le Valant, F. Can, N. Bion, D. Duprez, and F. Epron Hydrogen production from raw bioethanol steam reforming: optimization of catalyst composition with improved stability against various impurities Int J Hydrogen Energy 35 10 2010 5015 5020
19. A. Vizcaíno, A. Carrero, and J. Calles Hydrogen production by ethanol steam reforming over Cu-Ni supported catalysts Int J Hydrogen Energy 32 10-11 2007 1450 1461 (Pubitemid 46874751)
20. Yoon SP, Han J, Nam SW, Lim T-H, Oh I-H, Devianto H, et al. "MCFC anode for direct internal reforming of ethanol, manufacturing process thereof, and method for direct internal reforming in MCFC containing the anode", Korea Patent 10-0803669-0000; 2008.
21. 3Al(5 wt.%)-Al(3 wt.%) as an anode electrode for molten carbonate fuel cell. Part I: creep and sintering resistance J Alloy Compd 390 1-2 2005 155 160 (Pubitemid 40206185)
22. H. Devianto, Z. Li, S.P. Yoon, J. Han, S.W. Nam, T.-H. Lim, and et al The effect of Al addition on the prevention of Ni sintering in bio-ethanol steam reforming for molten carbonate fuel cells Int J Hydrogen Energy 35 7 2010 2591 2596
23. H. Devianto, Z. Li, S.P. Yoon, J. Han, S.W. Nam, T.-H. Lim, and et al The effect of water on direct ethanol molten carbonate fuel cell Catal Today 146 1-2 2009 2 8
24. H. Devianto, Z. Li, S.P. Yoon, J. Han, S.W. Nam, and T.-H. Lim The effect of electrolyte wettability on reforming catalyst in direct ethanol MCFC Curr Appl Phys 10 2 2010 S26 S28
25. F.J. Mariño, M. Boveri, G. Baronetti, and M. Laborde Hydrogen production via catalytic gasification of ethanol. A mechanism proposal over copper-nickel catalysts Int J Hydrogen Energy 29 1 2004 67 71
26. V. Mas, R. Kipreos, N. Amadeo, and M. Laborde Thermodynamic analysis of ethanol/water system with the stoichiometric method Int J Hydrogen Energy 31 1 2006 21 28
27. J.G. Seo, M.H. Youn, H.-I. Lee, J.J. Kim, E. Yang, and J.S. Chung Hydrogen production by steam reforming of liquefied natural gas (LNG) over mesoporous nickel-alumina xerogel catalysts: effect of nickel content Chem Eng J 141 1-3 2008 298 304
28. N. Takezawa, and N. Iwasa Steam reforming and dehydrogenation of methanol: difference in the catalytic functions of copper and group VIII metals Catal Today 36 1 1997 45 56 (Pubitemid 127381347)
29. T. Mizuno, Y. Matsumura, T. Nakajima, and S. Mishima Effect of support on catalytic properties of Rh catalysts for steam reforming of 2-propanol Int J Hydrogen Energy 28 12 2003 1393 1399
30. 3 React Kinet Catal Lett 78 2 2003 315 324
31. Y. Park, S. Baek, and S. Ihm Effect of reaction conditions and catalytic properties on methanol conversion over SAPO-34 J Ind Eng Chem 7 3 2001 167 172 (Pubitemid 33067607)
32. B. Zhang, X. Tang, Y. Li, W. Cai, Y. Xu, and W. Shen Steam reforming of bio-ethanol for the production of hydrogen over ceria-supported Co, Ir and Ni catalysts Catal Commun 7 6 2006 367 372
33. B. Nohair, C. Especel, G. Lafaye, P. Marécot, L. Hoang, and J. Barbier Palladium supported catalysts for the selective hydrogenation of sunflower oil J Mol Catal A Chem 229 1-2 2005 117 126
34. J. Jain, and C. Pillai Catalytic dehydration of alcohols over alumina: mechanism of ether formation J Catal 9 4 1967 322 330
35. J. Boitiaux, J. Cosyns, and E. Robert Additive effects in the selective hydrogenation of unsaturated hydrocarbons on platinum and rhodium catalysts. II: influence of various compounds containing phosphorus, oxygen, sulphur and chlorine on the catalytic performance of platinum catalyst Appl Catal 49 2 1989 235 246
36. S. Hong, S. Oh, D. Park, and G. Kim The methane reforming with carbon dioxide on Ni-catalyst activated by a DC-pulsed corona discharge J Ind Eng Chem 7 6 2001 410 416 (Pubitemid 33811265)