Accelerated anode failure of a high temperature planar SOFC operated with reduced moisture and increased PH3 concentrations in coal syngas

International Journal of Hydrogen Energy

Volumn 36, Issue 16, 2011, Pages 9945-9955

  De Silva, K Channa R ^a   Kaseman, Brian J ^a   Bayless, David J ^a  

^a OHIO UNIVERSITY   (United States)

Author keywords

Anode poisoning; PH3 contaminated syngas; Solid oxide fuel cells (SOFCs)

Indexed keywords

BI-LAYER; CATALYST LAYERS; CELL POWER; COUPON TESTS; HIGH TEMPERATURE; NICKEL PHOSPHIDE; SOLID OXIDE; SYN-GAS;

ANODES; DEGRADATION; ELECTROLYTES; NICKEL COMPOUNDS; PHOSPHORUS; SOLID OXIDE FUEL CELLS (SOFC);

SYNTHESIS GAS;

EID: 79960907121     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.04.169     Document Type: Article

References (18)

1. J.P. Trembly, R.S. Gemmen, and D.J. Bayless The effect of IGFC warm gas cleanup system conditions on the gas-solid partitioning and form of trace species in coal syngas and their interactions with SOFC anodes J Power Sources 163 2007 986 996 (Pubitemid 44959633)
2. 3 poisoning on a Ni-YSZ anode-supported solid oxide fuel cell under various operating conditions J Power Sources 196 2011 116 125
3. K. Haga, Y. Shiratori, Y. Nojiri, K. Ito, and K. Sasaki Phosphorus poisoning of Ni-cermet anodes in solid oxide fuel cells J Electrochem Soc 157 11 2010 B1693 B1700
4. O.A. Marina, C.A. Coyle, E.C. Thomsen, D.J. Edwards, G.W. Coffey, and L.R. Pederson Degradation mechanisms of SOFC anodes in coal gas containing phosphorus Solid State Ionics 181 2010 430 440
5. M. Zhi, X. Chen, H. Finklea, C. Ismail, and N.Q. Wu Electrochemical and microstructural analysis of nickel-yttria stabilized zirconia electrode operated in phosphorus-containing syngas J Power Sources 183 2008 485 490
6. 3-containing coal syngas Fuel Cells 10 1 2010 174 180
7. A. Martinez, K. Gerdes, R. Gemmen, and J. Poston Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas J Power Sources 195 2010 5206 5212
8. K.C.R. De Silva, B.J. Kaseman, and D.J. Bayless Silver (Ag) as anode and cathode current collectors in high temperature planar solid oxide fuel cells Int J Hydrogen Energy 36 2011 779 786
9. 2S poisoning on electrode behavior of Ni/YSZ and Ni/GDC anodes of solid oxide fuel cells Int J Hydrogen Energy 35 2010 12359 12368
10. 3 concentration J Power Sources 171 2007 818 825 (Pubitemid 47368989)
11. L. Holzer, B. Iwanschitz, Th. Hocker, B. Munch, M. Prestat, and D. Wiedenmann Mircostructure degradation of cermet anodes for solid oxide fuel cells: quantification of nickel grain growth in dry and humid atmospheres J Power Sources 196 2011 1279 1294
12. G.B. Jung, K.F. Lo, and S.H. Chan Effect of pretreatments on the anode structure of solid oxide fuel cells J Solid State Electrochem 11 2007 1435 1440
13. S. Primdahl, and M. Mogensen Gas conversion impedance, a test geometry effect in characterization of solid oxide fuel cell anodes J Electrochem Soc 145 1998 2431 2438 (Pubitemid 128602479)
14. M. Mori, Z. Wang, and T. Itoh Sintering mechanisms of cobalt-doped ceria and zirconia electrolytes in intermediate temperature solid oxide fuel cells J Fuel Cell Sci Technol 2011 8, 011007-1-6
15. 2 (or GDC) with Co for solid oxide fuel cell anodes Int J Hydrogen Energy 35 2010 11499 11504
16. C.J. Fu, Q.L. Liu, S.H. Chan, X.M. Ge, and G. Pasciak Effects of transition metal oxides on the densification of thin-film GDC electrolyte and on the performance of intermediate-temperature SOFC Int J Hydrogen Energy 35 2010 11200 11207
17. W. Liu, X. Sun, L.R. Pederson, O.A. Marina, and M.A. Khaleel Effect of nickel-phosphorus interactions on structural integrity of anode-supported solid oxide fuel cells J Power Sources 195 2010 7140 7145
18. C.E. Myers, and T.J. Conti Vaporization behavior, phase equilibria and thermodynamic stabilities of nickel phosphides J Electrochem Soc 132 2 1985 454 457